File name: Pandora26s1_CambridgeMA_20240619_L2Fit_fout2c10d20240425p1-8.txt File generation date: 20241217T230634.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v10d20240425.txt Level 1 file used: Pandora26s1_CambridgeMA_20240619_L1_smca1c10d20240425p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20240619 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0963 305.2371 305.3779 305.5186 305.6594 305.8002 305.9409 306.0816 306.2224 306.3631 306.5038 306.6445 306.7851 306.9258 307.0664 307.2071 307.3477 307.4883 307.6289 307.7695 307.9101 308.0507 308.1912 308.3318 308.4723 308.6129 308.7534 308.8939 309.0344 309.1748 309.3153 309.4558 309.5962 309.7366 309.8771 310.0175 310.1579 310.2982 310.4386 310.5790 310.7193 310.8597 311.0000 311.1403 311.2806 311.4209 311.5612 311.7015 311.8417 311.9820 312.1222 312.2624 312.4026 312.5428 312.6830 312.8232 312.9634 313.1035 313.2437 313.3838 313.5239 313.6640 313.8041 313.9442 314.0843 314.2243 314.3644 314.5044 314.6444 314.7844 314.9244 315.0644 315.2044 315.3444 315.4843 315.6243 315.7642 315.9041 316.0440 316.1839 316.3238 316.4637 316.6035 316.7434 316.8832 317.0230 317.1628 317.3026 317.4424 317.5822 317.7220 317.8617 318.0015 318.1412 318.2809 318.4206 318.5603 318.7000 318.8397 318.9793 319.1190 319.2586 319.3982 319.5378 319.6774 319.8170 319.9566 320.0962 320.2357 320.3753 320.5148 320.6543 320.7938 320.9333 321.0728 321.2123 321.3517 321.4912 321.6306 321.7700 321.9094 322.0488 322.1882 322.3276 322.4669 322.6063 322.7456 322.8849 323.0243 323.1636 323.3028 323.4421 323.5814 323.7206 323.8599 323.9991 324.1383 324.2775 324.4167 324.5559 324.6951 324.8342 324.9734 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240619T102448.0Z 8936.433889 147 1 26.60 2 78.14 69.00 127.50 271.50 0.00 1 0.00 1 0 25 4.463e-01 2.702e-02 1.726e-01 7.052e-03 6.406669e-01 4.005999e-03 7.441970e-03 -6.000000e+00 2.754502e-01 232.94 -2.00 3.54 -2.00 320.92 0.00e+00 4.627800e-03 1.772653e-03 2.722323e-03 -6.000000e+00 1.376765e-02 286.00 -2.00 20.00 -2.00 320.26 0.00e+00 4.712 0.002 302.00 328.00 3 3.7072e+00 1.3266e-02 5.9285e-02 -6.0000e+00 6.9614e-01 2.7428e-01 1.7052e-02 3.7125e-02 -6.0000e+00 7.5646e-01 -3.9174e-01 1.4824e-02 1.9213e-02 -6.0000e+00 4.4752e-01 1.5852e-01 7.1265e-03 5.9502e-03 -6.0000e+00 1.8449e-01 5.8187e-05 -8.4515e-04 2.2084e-04 1.0594e-04 -6.0000e+00 1.4229e-02 7.3482e-03 -4.7814e-05 12 9 9 12 33 1 59.19 26.65 0.14 0.00735 0.00100 11 3 1 5 0 2216.060 35.50 20.00 26.65 29.65 3.0 1012.62 -135712 900000 -147420 900000 -147881 -198428 -163467 -85325 900000 -137885 900000 207 900000 50978 900000 -12291 900000 90075 900000 900000 197611 -59687 900000 97059 -15280 -17994 981 -57615 -17503 -26109 -41353 16227 -664 -208 -5591 8558 46589 28264 33562 -1452 8779 19368 58145 5075 -16032 61347 22460 6405 -6233 31545 -2576 43581 72979 52849 1605 23633 -14826 26376 -5222 7043 -1414 11426 647 6612 28373 6041 -2515 4588 430 -1731 5635 3392 -1177 2822 -3665 996 -8141 -2806 -2375 7353 -7728 -5867 -2718 -4745 -391 -2541 -1912 3595 3547 5006 -2457 4145 -3546 -3967 -2987 1363 2949 -2119 -926 -2384 585 -2952 -3017 3325 -3252 -818 -2233 -2290 -1612 2469 603 335 755 106 -227 357 1182 906 724 996 -1397 -2105 1510 1189 2758 3152 -1172 183 1496 126 1040 -79 -1348 -545 665 760 -1386 616 589 -628 -783 -550 -498 -3049 900000 -4232 900000 -3783 -8296 -5100 -1331 900000 -4130 900000 2 900000 490 900000 -312 900000 989 900000 900000 1356 -3237 900000 1199 -608 -753 34 -3480 -721 -1290 -2782 713 -38 -12 -342 464 1919 1649 2212 -156 940 1981 4191 634 -2509 4506 2482 857 -993 3703 -468 5504 7464 7074 376 4575 -4264 4961 -1319 1576 -362 2839 200 2102 7459 1957 -887 1581 171 -718 2345 1484 -527 1251 -1582 374 -3202 -1086 -1033 3397 -4359 -3653 -1783 -3387 -285 -2007 -1568 2845 2778 3698 -1832 2729 -2470 -2916 -2438 1228 3009 -2339 -1071 -2763 615 -2943 -3103 3270 -3324 -864 -2544 -2814 -2164 3530 882 511 1141 155 -344 524 1747 1407 1095 1544 -2196 -3226 2335 1775 3893 4282 -1647 268 2416 212 1883 -154 -2602 -1108 1420 1693 -3227 1421 1341 -1387 -1638 -1091 -973 SS 20240619T103024.9Z 8936.437788 150 1 53.97 2 77.17 69.87 128.50 272.43 0.00 1 0.00 1 0 17 3.438e-01 1.287e-02 1.097e-01 2.127e-03 6.023071e-01 1.166690e-03 6.805323e-03 -6.000000e+00 2.105120e-01 232.94 -2.00 3.54 -2.00 320.38 0.00e+00 -1.182682e-03 4.476755e-04 1.499451e-03 -6.000000e+00 9.829975e-03 286.00 -2.00 20.00 -2.00 319.68 0.00e+00 4.381 0.002 302.00 328.00 3 2.8906e+00 3.6070e-03 5.4804e-02 -6.0000e+00 5.3027e-01 2.2124e-02 4.5159e-03 3.3834e-02 -6.0000e+00 5.7437e-01 -1.1280e-01 3.9660e-03 1.5976e-02 -6.0000e+00 3.4028e-01 4.3405e-02 1.9694e-03 4.3884e-03 -6.0000e+00 1.4099e-01 2.0448e-04 2.8115e-04 6.4938e-05 5.4242e-05 -6.0000e+00 1.0813e-02 6.3521e-03 1.3010e-05 12 8 8 10 0 0 84.35 26.67 0.43 0.00635 0.00846 78 8 1 5 0 691.890 35.50 20.00 26.67 29.81 3.0 1013.35 -122702 900000 900000 87578 -158785 -179416 -137587 -94012 900000 -118553 71113 -28841 69016 -48658 -20064 -27030 7039 -1016 900000 95903 1242 -31503 56576 15300 -13031 -3601 -14890 -28145 -9858 -34082 -14987 4744 -33459 -7557 -17312 26335 893 4187 1964 -1327 -10610 5161 14405 3647 -4061 12202 4146 846 -3323 2289 -4800 10195 16796 10260 2252 6024 -7022 4785 -1443 2163 -36 2670 -593 4296 5843 365 -121 1985 -453 4077 108 115 3844 758 -1039 -219 -3165 -2132 -1882 1004 -2349 -2246 -1405 -2148 -856 -940 -340 977 1385 1370 -1108 1014 -919 -650 -649 265 1501 -414 -195 -1253 -974 -1839 388 357 -1011 -1165 -1176 -852 -47 1119 -296 27 448 -79 111 233 1035 376 18 -103 409 -411 515 466 1014 1397 -176 836 -176 396 282 -140 -519 -67 276 222 -384 137 25 -219 -358 -215 -338 -1687 900000 900000 181 -3380 -4833 -2994 -1520 900000 -2997 295 -377 415 -1170 -437 -728 150 -26 900000 1033 36 -1293 1032 463 -567 -149 -691 -1458 -429 -2055 -863 260 -2982 -539 -1352 1386 69 377 219 -179 -1750 776 2054 590 -718 1861 698 152 -652 459 -1040 2318 3912 2505 631 1698 -2306 1389 -438 635 -11 902 -231 1727 2369 154 -51 867 -226 2007 60 66 2084 400 -557 -106 -1513 -1043 -946 571 -1592 -1709 -1064 -1753 -738 -862 -324 938 1310 1240 -963 814 -736 -544 -607 261 1671 -490 -243 -1551 -1125 -2108 414 391 -1195 -1362 -1460 -1133 -64 1655 -452 43 696 -125 168 342 1530 585 27 -164 645 -635 810 705 1466 1944 -246 1225 -288 673 490 -259 -1015 -132 573 481 -816 293 53 -469 -731 -417 -687 SS 20240619T103655.2Z 8936.442305 153 1 54.37 2 76.04 70.87 129.66 273.52 0.00 1 0.00 1 0 17 2.174e-01 8.030e-03 4.690e-02 1.378e-03 5.590241e-01 7.386925e-04 6.373397e-03 -6.000000e+00 1.324301e-01 232.94 -2.00 3.54 -2.00 319.91 0.00e+00 5.372083e-04 2.447711e-04 1.118562e-03 -6.000000e+00 5.889857e-03 286.00 -2.00 20.00 -2.00 319.18 0.00e+00 4.050 0.001 302.00 328.00 3 2.4858e+00 2.1848e-03 5.0428e-02 -6.0000e+00 3.3238e-01 7.3477e-03 2.6354e-03 3.0354e-02 -6.0000e+00 3.5929e-01 -6.8616e-02 2.1840e-03 1.4822e-02 -6.0000e+00 2.1361e-01 1.9993e-02 1.1116e-03 4.0666e-03 -6.0000e+00 8.8200e-02 4.3477e-04 3.1608e-04 4.1722e-05 5.3571e-05 -6.0000e+00 6.8016e-03 5.9070e-03 1.7904e-05 11 8 0 10 0 0 52.85 26.68 0.30 0.00591 0.00828 144 15 1 5 0 377.510 35.25 20.01 26.68 29.97 3.0 1014.51 -121009 83296 10113 -18247 -83801 -100100 -90763 -54082 46172 -67454 -24865 -17573 -4029 -36863 -17530 -17257 -1880 240 47537 11471 472 -14315 19237 3336 -5783 -2684 -8676 -14279 -18744 -16471 -7750 190 -13731 -2853 -6763 2996 -1385 2713 -2209 -2731 -1533 3379 3946 -212 -1770 2995 2668 -635 -2104 1993 -124 2180 5172 4269 506 1998 -2218 1497 -576 1628 -101 1438 735 2407 2655 432 -91 941 649 2303 625 597 1488 126 -481 -1185 -2087 -1497 -1279 52 -1668 -1627 -1544 -1765 -464 -231 232 754 1007 593 -155 582 63 -393 -171 391 691 145 -510 -842 -760 -1008 -280 -133 -895 -1118 -928 -580 -95 656 -13 72 320 122 -111 148 676 225 316 79 150 -106 587 542 419 716 -16 931 110 147 87 -255 -242 -307 253 98 -163 194 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