File name: Pandora26s1_CambridgeMA_20240627_L2Fit_fout2c7d20230915p1-8.txt File generation date: 20241010T180738.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v7d20230915.txt Level 1 file used: Pandora26s1_CambridgeMA_20240627_L1_smca1c7d20230915p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20240627 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 5 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.1176 305.2583 305.3991 305.5398 305.6805 305.8212 305.9619 306.1026 306.2432 306.3839 306.5245 306.6651 306.8057 306.9464 307.0869 307.2275 307.3681 307.5087 307.6492 307.7897 307.9303 308.0708 308.2113 308.3518 308.4923 308.6327 308.7732 308.9136 309.0541 309.1945 309.3349 309.4753 309.6157 309.7561 309.8964 310.0368 310.1771 310.3175 310.4578 310.5981 310.7384 310.8787 311.0189 311.1592 311.2995 311.4397 311.5799 311.7201 311.8604 312.0005 312.1407 312.2809 312.4211 312.5612 312.7013 312.8415 312.9816 313.1217 313.2618 313.4019 313.5419 313.6820 313.8220 313.9621 314.1021 314.2421 314.3821 314.5221 314.6621 314.8020 314.9420 315.0819 315.2219 315.3618 315.5017 315.6416 315.7815 315.9213 316.0612 316.2010 316.3409 316.4807 316.6205 316.7603 316.9001 317.0399 317.1797 317.3194 317.4592 317.5989 317.7386 317.8783 318.0180 318.1577 318.2974 318.4371 318.5767 318.7164 318.8560 318.9956 319.1352 319.2748 319.4144 319.5540 319.6935 319.8331 319.9726 320.1122 320.2517 320.3912 320.5307 320.6702 320.8096 320.9491 321.0885 321.2280 321.3674 321.5068 321.6462 321.7856 321.9250 322.0643 322.2037 322.3430 322.4823 322.6217 322.7610 322.9003 323.0395 323.1788 323.3181 323.4573 323.5965 323.7358 323.8750 324.0142 324.1534 324.2926 324.4317 324.5709 324.7100 324.8491 324.9883 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240627T115819.8Z 8944.498841 243 1 1.26 2 61.81 83.22 59.47 222.01 0.00 1 0.00 1 0 17 2.055e-02 8.140e-03 1.835e-02 6.697e-03 3.214239e-01 3.576326e-03 3.800595e-03 -6.000000e+00 1.252137e-02 232.96 -2.00 3.54 -2.00 316.94 0.00e+00 8.463273e-05 4.766106e-04 8.858579e-05 -6.000000e+00 5.586050e-04 286.75 -2.00 20.00 -2.00 316.13 0.00e+00 2.107 0.000 302.00 328.00 3 3.3045e+00 9.4687e-03 2.7121e-02 -6.0000e+00 3.1420e-02 2.5054e-02 1.0588e-02 1.6872e-02 -6.0000e+00 3.3956e-02 -1.6635e-02 6.1737e-03 8.1340e-03 -6.0000e+00 2.0197e-02 5.0149e-03 2.8987e-03 2.1898e-03 -6.0000e+00 8.3503e-03 1.5790e-03 -9.1019e-05 2.0995e-04 2.8542e-05 -6.0000e+00 6.4302e-04 -1.1536e-02 0.0000e+00 12 9 1 12 1 1 999.00 26.40 0.17 -0.01154 -0.01222 1 9 1 5 0 625.060 35.25 20.00 26.40 28.14 3.1 1003.28 -1169 1091 -6891 -5265 -12134 -4303 -1264 -2330 -2834 -6910 -1448 1234 -6122 -948 2587 275 1043 2516 5095 5416 -2962 -9 4186 -450 759 -1595 -2956 -2359 -2650 361 2283 -1497 1657 -2086 -1744 -253 -4392 588 -64 530 -1003 127 993 528 -1291 1051 161 -1028 -105 1675 655 1632 1856 138 1423 -69 1010 1951 1035 1392 764 1318 1174 278 -60 -703 -1464 -1002 -1466 1431 -506 824 -640 963 -890 -741 -292 -422 -500 247 -1102 -554 -1066 -1486 -230 -743 659 -320 -868 663 -301 807 -106 -690 1003 316 91 7 -715 -933 -192 -265 589 -10 -282 -698 -1650 -427 537 359 34 -159 -145 -42 993 1257 431 51 1111 -512 -613 -13 -257 879 1344 770 763 950 162 336 532 -176 -508 -103 94 -58 -27 -441 -533 -267 207 -640 -188 -140 137 -941 -666 -1534 -501 -154 -320 -426 -1128 -230 206 -1250 -195 582 69 276 689 1417 1550 -864 -3 1194 -142 250 -550 -1016 -768 -835 112 749 -556 635 -776 -678 -92 -1852 259 -34 296 -582 76 607 327 -815 645 98 -628 -63 1027 431 1077 1299 98 1031 -52 761 1447 765 1032 595 1043 1004 239 -51 -596 -1196 -822 -1246 1313 -487 808 -630 889 -810 -640 -233 -332 -422 221 -1069 -561 -1112 -1650 -258 -859 788 -395 -1066 766 -339 860 -111 -732 1074 363 112 9 -936 -1199 -239 -318 703 -12 -347 -913 -2208 -573 757 523 50 -238 -215 -60 1361 1644 571 69 1572 -746 -904 -18 -374 1209 1813 1035 994 1265 223 479 769 -265 -765 -161 150 -94 -44 -751 -905 -439 336 -1013 -293 SS 20240627T121145.6Z 8944.508167 252 1 54.28 2 59.35 85.34 61.08 225.26 0.00 1 0.00 1 0 17 4.561e-02 1.220e-02 7.807e-03 2.225e-03 3.027339e-01 1.179627e-03 3.548806e-03 -6.000000e+00 2.780210e-02 232.96 -2.00 3.54 -2.00 317.49 0.00e+00 -1.207836e-03 1.809546e-04 2.070405e-04 -6.000000e+00 1.240207e-03 286.75 -2.00 20.00 -2.00 316.66 0.00e+00 1.953 0.000 302.00 328.00 3 5.3776e+00 3.1594e-03 2.5335e-02 -6.0000e+00 6.9764e-02 4.8277e-02 3.5518e-03 1.6028e-02 -6.0000e+00 7.5392e-02 -2.1924e-02 2.1287e-03 7.6508e-03 -6.0000e+00 4.4843e-02 7.3661e-03 1.0296e-03 2.2561e-03 -6.0000e+00 1.8542e-02 2.3576e-04 3.9421e-04 7.0904e-05 2.7702e-05 -6.0000e+00 1.4276e-03 -1.2083e-02 0.0000e+00 12 8 8 10 0 0 99.99 26.43 -0.33 -0.01208 -0.00912 39 4 1 5 0 1391.680 35.25 20.00 26.43 28.03 3.1 1003.17 -4232 1298 975 -6259 -5751 -32147 -6836 3260 10851 -15910 10038 6784 -2606 1463 -4660 -2623 5070 8987 18133 7212 270 -7630 11136 -1419 1861 -4347 -2986 -3773 -3446 -3348 -3151 3599 -3410 -2422 -6929 7530 -1265 -684 1986 -847 -3028 -381 1690 1451 -2162 1871 356 -1288 -4070 -111 -711 3969 4983 2893 344 3111 -2288 2677 2242 1326 1395 1292 -1364 982 1650 -1541 -1941 371 61 3832 -776 -23 1118 -15 -467 -1030 -1540 -440 -1454 -92 -2553 -2530 -1630 -1539 -1144 -366 -269 125 709 1193 -565 990 -289 -1219 605 488 682 435 561 -976 -874 -818 -218 814 -1029 -162 -854 -598 322 1199 -28 -104 555 674 -369 -100 385 138 325 5 677 -1025 59 553 1023 1140 -13 763 -331 204 725 -459 -979 -181 71 103 -406 397 532 -559 -109 -479 -302 -402 124 93 -602 -513 -3726 -666 321 1081 -2158 1076 802 -381 234 -890 -532 1001 1783 3408 1557 64 -1964 2470 -379 506 -1288 -853 -1029 -897 -878 -879 1015 -1092 -771 -2241 2157 -441 -254 848 -424 -1679 -215 955 825 -1270 1047 198 -718 -2322 -62 -427 2434 2941 1830 231 2079 -1632 1803 1496 897 982 977 -1138 833 1365 -1237 -1491 280 50 3361 -708 -21 1021 -14 -413 -829 -1151 -320 -1140 -80 -2335 -2533 -1727 -1602 -1267 -428 -329 156 867 1385 -618 1054 -293 -1244 646 535 829 579 721 -1244 -1118 -973 -250 958 -1318 -217 -1128 -827 468 1833 -43 -158 859 973 -499 -138 534 188 469 8 1032 -1563 87 771 1444 1533 -17 1019 -445 291 1079 -713 -1571 -283 116 176 -718 707 943 -974 -182 -774 -482 SS 20240627T125752.2Z 8944.540188 271 1 12.41 2 50.84 93.04 67.31 235.57 0.00 1 0.00 1 0 17 7.865e-03 5.637e-03 4.146e-04 2.613e-04 2.379840e-01 1.405579e-04 2.847262e-03 -6.000000e+00 4.793016e-03 232.96 -2.00 3.54 -2.00 315.44 0.00e+00 3.020793e-04 1.335100e-05 3.326706e-05 -6.000000e+00 2.138429e-04 286.75 -2.00 20.00 -2.00 314.72 0.00e+00 1.580 0.000 302.00 328.00 3 5.2749e-01 3.6513e-04 2.0215e-02 -6.0000e+00 1.2027e-02 3.0059e-03 4.0540e-04 1.2454e-02 -6.0000e+00 1.2998e-02 -1.0394e-03 2.3061e-04 6.0082e-03 -6.0000e+00 7.7311e-03 -2.5397e-03 9.9818e-05 1.6293e-03 -6.0000e+00 3.1962e-03 4.8824e-02 1.1563e-04 8.2323e-06 2.3688e-05 -6.0000e+00 2.4616e-04 -1.1175e-02 0.0000e+00 12 1 1 12 1 1 98.62 26.58 0.30 -0.01117 -0.01031 482 222 1 5 0 25.680 35.25 20.01 26.58 30.88 2.9 1016.20 -778 -1958 -2228 -3046 -2135 -779 -245 389 78 -1331 -1426 -320 225 19 406 -96 124 1052 815 1210 862 922 1398 819 632 284 -501 -394 572 1159 1654 1019 684 -1380 -2050 -813 -780 -122 -20 -692 -1114 -696 -533 -733 -208 -309 -637 -321 -259 398 946 773 803 861 503 771 658 289 608 814 1079 1389 1125 894 -151 -521 6 -191 908 610 -305 20 -163 49 -175 -342 -276 -590 -264 -615 -1133 -1343 -1835 -1392 -731 -577 -218 -33 108 86 234 400 182 589 498 226 231 345 -188 -492 -454 -572 -239 85 -455 -934 -426 -454 -4 354 318 213 197 245 188 406 593 289 225 -8 -249 27 286 274 586 636 381 1016 713 188 97 -203 -126 -5 31 -78 -193 44 -154 -239 -147 -506 -565 -217 -585 -661 -849 -582 -207 -69 113 25 -413 -448 -105 77 8 166 -40 54 470 359 546 395 425 660 389 314 144 -250 -195 267 537 803 508 359 -739 -1069 -427 -433 -72 -13 -491 -827 -518 -405 -561 -158 -233 -471 -239 -190 295 708 596 652 706 425 642 554 243 519 699 934 1246 1051 842 -140 -479 6 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