File name: Pandora26s1_CambridgeMA_20240708_L2Fit_fout2c10d20240425p1-8.txt File generation date: 20241217T232204.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v10d20240425.txt Level 1 file used: Pandora26s1_CambridgeMA_20240708_L1_smca1c10d20240425p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20240708 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0963 305.2371 305.3779 305.5186 305.6594 305.8002 305.9409 306.0816 306.2224 306.3631 306.5038 306.6445 306.7851 306.9258 307.0664 307.2071 307.3477 307.4883 307.6289 307.7695 307.9101 308.0507 308.1912 308.3318 308.4723 308.6129 308.7534 308.8939 309.0344 309.1748 309.3153 309.4558 309.5962 309.7366 309.8771 310.0175 310.1579 310.2982 310.4386 310.5790 310.7193 310.8597 311.0000 311.1403 311.2806 311.4209 311.5612 311.7015 311.8417 311.9820 312.1222 312.2624 312.4026 312.5428 312.6830 312.8232 312.9634 313.1035 313.2437 313.3838 313.5239 313.6640 313.8041 313.9442 314.0843 314.2243 314.3644 314.5044 314.6444 314.7844 314.9244 315.0644 315.2044 315.3444 315.4843 315.6243 315.7642 315.9041 316.0440 316.1839 316.3238 316.4637 316.6035 316.7434 316.8832 317.0230 317.1628 317.3026 317.4424 317.5822 317.7220 317.8617 318.0015 318.1412 318.2809 318.4206 318.5603 318.7000 318.8397 318.9793 319.1190 319.2586 319.3982 319.5378 319.6774 319.8170 319.9566 320.0962 320.2357 320.3753 320.5148 320.6543 320.7938 320.9333 321.0728 321.2123 321.3517 321.4912 321.6306 321.7700 321.9094 322.0488 322.1882 322.3276 322.4669 322.6063 322.7456 322.8849 323.0243 323.1636 323.3028 323.4421 323.5814 323.7206 323.8599 323.9991 324.1383 324.2775 324.4167 324.5559 324.6951 324.8342 324.9734 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240708T100547.6Z 8955.420689 58 1 34.32 2 82.72 66.23 104.66 45.61 0.00 1 0.00 1 0 25 7.685e-01 5.253e-02 2.466e-01 1.473e-02 8.630017e-01 9.036448e-03 9.361577e-03 -6.000000e+00 4.853396e-01 232.99 -2.00 3.54 -2.00 321.91 0.00e+00 -8.444080e-03 4.633490e-03 5.653388e-03 -6.000000e+00 3.130279e-02 287.76 -2.00 20.00 -2.00 321.31 0.00e+00 7.271 0.007 302.00 328.00 3 2.1272e+00 3.4740e-02 9.4799e-02 -6.0000e+00 1.2365e+00 1.5355e+00 4.1741e-02 7.1571e-02 -6.0000e+00 1.3521e+00 -2.0669e+00 2.3531e-02 2.2718e-02 -6.0000e+00 7.9130e-01 8.2527e-01 1.1880e-02 1.1804e-02 -6.0000e+00 3.3290e-01 1.7032e-05 1.8417e-03 4.5889e-04 8.8715e-05 -6.0000e+00 2.6560e-02 8.8953e-03 -1.3961e-04 12 9 9 12 1 1 99.67 26.93 0.49 0.00890 0.02273 15 3 1 5 0 2144.590 35.50 20.00 26.93 32.34 3.0 1022.40 900000 365824 900000 900000 900000 -60220 56223 239915 900000 900000 900000 900000 38883 900000 138325 58761 900000 900000 900000 900000 900000 -2083 900000 98643 900000 54804 -4264 900000 17447 86538 151930 900000 96500 117278 22969 79111 139046 900000 900000 121548 53497 191606 900000 900000 20836 900000 143036 181639 2239 184377 9245 900000 900000 900000 85540 188572 -41963 119425 123008 209786 47341 40734 -4140 47903 45933 30740 23536 82276 11636 218795 10104 16640 32050 -13317 -35908 11622 -16043 24647 -6181 53598 9784 -8631 9045 -13218 4505 5031 -5934 11880 17718 21494 -6101 6492 -6455 9036 -13929 -5725 6694 3096 772 -5519 -4294 -7166 8663 -6985 -8105 8947 -7674 -10638 3244 2282 -5598 -2287 1127 2528 1957 -2636 3591 1957 -2895 37 3953 -5512 5051 8332 3477 6844 4025 -3996 -2296 2162 1462 -398 -884 1173 2376 1023 -3004 -86 548 -3359 1830 -2389 1220 900000 5227 900000 900000 900000 -12202 3578 3428 900000 900000 900000 900000 3384 900000 5210 5037 900000 900000 900000 900000 900000 -244 900000 4356 900000 3559 -449 900000 1224 3147 3157 900000 3885 3656 1700 3617 3774 900000 900000 5731 5197 4654 900000 900000 2381 900000 4496 3893 298 4215 1321 900000 900000 900000 7088 5658 -12410 6654 6151 4196 4870 4830 -846 6228 6169 4743 3968 8228 2627 6877 2699 4160 6502 -3862 -11594 2109 -3736 4085 -1607 9036 2963 -3539 3373 -6553 1982 2307 -3128 5262 7215 7984 -2807 2541 -2933 3860 -8657 -3845 4610 2485 669 -4999 -3565 -5560 5433 -5249 -6542 6468 -7050 -11079 3328 2449 -7219 -3024 1458 3162 2389 -3338 4393 2557 -4152 52 5206 -7660 6101 10368 4407 8204 5050 -5434 -3525 3606 2715 -813 -1947 2717 5794 2408 -7486 -209 1284 -8404 4041 -5179 2522 SS 20240708T101741.5Z 8955.428952 61 1 54.32 2 80.69 68.11 103.15 47.91 0.00 1 0.00 1 0 17 5.275e-01 1.402e-02 1.127e-01 2.038e-03 7.434633e-01 1.150278e-03 8.633607e-03 -6.000000e+00 3.234183e-01 232.99 -2.00 3.54 -2.00 321.13 0.00e+00 1.416958e-03 5.773517e-04 4.947778e-03 -6.000000e+00 1.598545e-02 287.76 -2.00 20.00 -2.00 320.50 0.00e+00 5.873 0.004 302.00 328.00 3 1.2334e+00 4.0218e-03 7.4856e-02 -6.0000e+00 8.1669e-01 1.4393e-01 5.5063e-03 5.1310e-02 -6.0000e+00 8.8515e-01 -2.3215e-01 5.2551e-03 2.3252e-02 -6.0000e+00 5.2214e-01 8.7004e-02 2.4630e-03 5.5857e-03 -6.0000e+00 2.1585e-01 2.2286e-04 7.5631e-04 5.9266e-05 1.1469e-04 -6.0000e+00 1.6555e-02 4.7861e-03 7.9641e-05 12 8 8 10 0 0 22.90 26.97 0.48 0.00479 0.01047 166 17 1 5 0 327.160 35.50 20.00 26.97 32.64 2.9 1022.97 -151539 -198915 -123018 -121652 -136011 -306389 -192051 -128400 900000 900000 -101956 900000 -147183 -78167 -96628 -92267 62628 101994 900000 70628 9674 -80528 900000 -50711 -5191 -47818 -77357 -10843 -64425 -20504 -23301 2916 -61922 -9778 -28660 -24732 -11358 19400 4729 -223 905 693 6332 4676 -5265 10559 5015 9333 -938 7133 -1555 13656 31095 11446 9410 11831 -5980 4848 5204 8763 7815 4420 3958 5489 4453 3704 3412 6469 2017 7787 322 2574 3263 -217 -737 -404 -3597 -235 -2529 1247 -1044 -1666 -1478 -3404 -1605 -141 -123 789 1873 1214 -752 -558 -1222 -697 -2093 -1739 218 -232 -85 -881 -846 -2150 -123 -1187 -1270 -573 -1137 -1065 438 845 192 -57 99 342 213 -278 948 386 171 141 380 194 980 644 429 874 208 239 302 461 112 -221 -112 -149 240 41 -242 251 -6 -372 5 -746 -166 -821 -1975 -600 -571 -712 -9072 -2011 -893 900000 900000 -749 900000 -2631 -900 -1670 -1814 299 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6.2368e-02 -6.0000e+00 5.6874e-01 4.6994e-02 2.4922e-03 3.7888e-02 -6.0000e+00 6.1451e-01 -1.0676e-01 2.2214e-03 1.8213e-02 -6.0000e+00 3.6574e-01 3.8206e-02 1.0978e-03 4.7589e-03 -6.0000e+00 1.5132e-01 6.0920e-04 3.3674e-04 3.3533e-05 7.6339e-05 -6.0000e+00 1.1640e-02 4.7451e-03 4.0469e-05 11 8 0 10 0 0 3.08 26.95 0.32 0.00475 0.00728 294 31 1 5 0 184.990 35.50 20.00 26.95 32.87 2.9 1024.48 -136614 -128587 -104824 -117057 -128565 -191115 -131446 -138908 -50357 -73472 -68539 -17324 -81641 -48853 -62110 -47209 -34845 -1990 32925 -280 -11725 -39094 31990 -19298 -15072 -18981 -37825 -11491 -29267 -17051 -17591 -6128 -25109 -10048 -13842 -14017 -9329 -1679 -2692 -3635 -2739 1025 2711 -5 787 2180 1033 1356 -18 2047 628 5031 8188 3476 3381 4464 -1053 1956 2954 3930 2778 3463 3263 3321 2645 1645 1466 2868 2031 2810 69 1100 1433 284 -296 -1779 -1979 -666 -1221 -83 -1219 -1673 -1756 -2163 -1062 -274 -184 358 721 761 -202 193 -604 -137 -1207 -777 310 175 -291 -751 -672 -1295 -772 -418 -828 -1018 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