File name: Pandora26s1_CambridgeMA_20240710_L2Fit_fout2c10d20240425p1-8.txt File generation date: 20241217T232545.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v10d20240425.txt Level 1 file used: Pandora26s1_CambridgeMA_20240710_L1_smca1c10d20240425p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20240710 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0963 305.2371 305.3779 305.5186 305.6594 305.8002 305.9409 306.0816 306.2224 306.3631 306.5038 306.6445 306.7851 306.9258 307.0664 307.2071 307.3477 307.4883 307.6289 307.7695 307.9101 308.0507 308.1912 308.3318 308.4723 308.6129 308.7534 308.8939 309.0344 309.1748 309.3153 309.4558 309.5962 309.7366 309.8771 310.0175 310.1579 310.2982 310.4386 310.5790 310.7193 310.8597 311.0000 311.1403 311.2806 311.4209 311.5612 311.7015 311.8417 311.9820 312.1222 312.2624 312.4026 312.5428 312.6830 312.8232 312.9634 313.1035 313.2437 313.3838 313.5239 313.6640 313.8041 313.9442 314.0843 314.2243 314.3644 314.5044 314.6444 314.7844 314.9244 315.0644 315.2044 315.3444 315.4843 315.6243 315.7642 315.9041 316.0440 316.1839 316.3238 316.4637 316.6035 316.7434 316.8832 317.0230 317.1628 317.3026 317.4424 317.5822 317.7220 317.8617 318.0015 318.1412 318.2809 318.4206 318.5603 318.7000 318.8397 318.9793 319.1190 319.2586 319.3982 319.5378 319.6774 319.8170 319.9566 320.0962 320.2357 320.3753 320.5148 320.6543 320.7938 320.9333 321.0728 321.2123 321.3517 321.4912 321.6306 321.7700 321.9094 322.0488 322.1882 322.3276 322.4669 322.6063 322.7456 322.8849 323.0243 323.1636 323.3028 323.4421 323.5814 323.7206 323.8599 323.9991 324.1383 324.2775 324.4167 324.5559 324.6951 324.8342 324.9734 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240710T123156.1Z 8957.522177 132 1 2.21 2 56.74 89.35 104.22 63.53 0.00 1 0.00 1 0 17 9.100e-03 6.037e-03 3.651e-03 2.106e-03 2.409737e-01 1.130380e-03 2.882949e-03 -6.000000e+00 5.545459e-03 233.00 -2.00 3.54 -2.00 315.75 0.00e+00 3.191405e-04 1.151189e-04 6.345788e-05 -6.000000e+00 2.486097e-04 287.95 -2.00 20.00 -2.00 314.99 0.00e+00 1.817 0.000 302.00 328.00 3 2.7648e+00 2.9462e-03 2.2174e-02 -6.0000e+00 1.3911e-02 1.6304e-03 3.2731e-03 1.2659e-02 -6.0000e+00 1.5031e-02 -2.4480e-03 1.8650e-03 6.0909e-03 -6.0000e+00 8.9469e-03 -1.2528e-03 8.1996e-04 1.6449e-03 -6.0000e+00 3.7013e-03 4.1459e-03 1.4955e-04 6.6295e-05 2.3418e-05 -6.0000e+00 2.8478e-04 4.6558e-03 -3.1885e-05 12 1 1 12 1 1 98.26 27.36 0.35 0.00466 0.00578 9 26 1 5 0 220.380 36.00 20.01 27.36 35.91 2.8 1039.16 -1357 -2253 -991 -1754 -2418 -3136 -2709 -478 1785 -448 -1110 156 723 365 203 -450 568 1118 1885 1830 1851 1077 1683 398 14 891 -1094 -240 236 1124 1007 488 165 -2055 -2505 -800 -1021 -514 -154 -1098 -1166 -972 -493 -814 -687 -443 -226 -358 -445 -306 822 537 899 729 616 1150 593 830 496 1085 1000 1380 991 1024 -168 -451 331 -475 1178 1008 2 79 242 357 -300 -224 -697 -873 -422 -882 -1379 -1130 -1307 -1505 -530 -301 -146 397 72 315 196 -115 -415 610 168 75 212 493 -198 -501 -480 -820 -193 17 -449 -859 -563 -478 102 823 702 408 186 377 -3 208 516 510 58 -7 -390 -365 354 -48 516 846 73 946 750 58 50 -535 -254 -147 -2 -143 -158 210 71 -232 -19 -366 -394 -334 -593 -256 -426 -547 -704 -646 -123 487 -120 -303 44 228 122 76 -170 222 452 782 781 800 472 710 179 7 423 -518 -107 106 499 444 231 83 -994 -1247 -399 -533 -296 -99 -732 -841 -698 -361 -601 -506 -323 -161 -260 -319 -223 597 415 700 594 496 939 492 682 405 888 854 1210 899 962 -156 -406 291 -420 1061 969 2 79 241 351 -285 -201 -599 -733 -373 -808 -1361 -1172 -1398 -1652 -597 -349 -177 491 89 369 227 -126 -440 634 179 85 251 612 -249 -635 -589 -973 -221 20 -559 -1101 -732 -633 141 1164 1005 583 263 507 -4 262 653 657 78 -9 -550 -508 489 -66 684 1066 93 1206 984 79 69 -764 -360 -211 -2 -221 -246 331 112 -358 -29 -544 -596 SS 20240710T124954.3Z 8957.534656 140 1 7.04 2 53.43 92.42 101.35 66.81 0.00 1 0.00 1 0 17 7.365e-03 5.484e-03 7.030e-04 4.514e-04 2.222955e-01 2.428673e-04 2.666686e-03 -6.000000e+00 4.488295e-03 233.00 -2.00 3.54 -2.00 315.36 0.00e+00 2.372146e-04 2.276998e-05 3.067191e-05 -6.000000e+00 2.012137e-04 287.95 -2.00 20.00 -2.00 314.62 0.00e+00 1.674 0.000 302.00 328.00 3 1.1494e+00 6.3018e-04 2.0432e-02 -6.0000e+00 1.1259e-02 -7.0678e-03 6.9930e-04 1.1673e-02 -6.0000e+00 1.2166e-02 -1.4725e-03 3.9811e-04 5.6222e-03 -6.0000e+00 7.2413e-03 -2.4561e-03 1.7185e-04 1.5213e-03 -6.0000e+00 2.9958e-03 2.4885e-02 1.3752e-04 1.4204e-05 2.2425e-05 -6.0000e+00 2.3049e-04 4.2049e-03 -4.2682e-05 12 1 1 12 1 1 98.96 27.42 0.31 0.00420 0.00524 181 147 1 5 0 38.650 35.75 20.01 27.42 38.22 2.7 1050.31 -747 -1542 -1670 -2818 -1726 -290 -137 738 7 -1014 -1070 -160 63 49 251 -215 85 848 888 1175 946 795 1334 858 605 487 -211 -73 661 1013 1531 995 807 -1129 -1953 -1067 -1194 -432 -302 -929 -1206 -807 -560 -820 -393 -327 -705 -458 -375 328 807 714 718 848 344 832 630 333 524 866 1063 1305 1002 849 -63 -367 189 -87 1043 658 -224 74 -111 95 -15 -201 -315 -543 -243 -555 -1092 -1267 -1760 -1397 -676 -416 -120 7 192 156 236 389 92 513 565 243 225 351 -131 -537 -515 -647 -265 93 -431 -954 -453 -428 -9 361 319 149 137 193 36 347 485 255 213 13 -231 -5 276 159 520 617 260 958 760 264 138 -223 -113 46 115 -32 -147 70 -125 -224 -175 -532 -530 -212 -467 -501 -850 -476 -78 -39 230 2 -336 -358 -55 23 19 101 -93 38 372 403 545 445 377 646 417 307 252 -107 -37 314 477 752 499 425 -605 -1019 -562 -664 -266 -201 -653 -883 -613 -434 -640 -305 -251 -530 -334 -279 246 610 552 585 695 291 714 529 279 448 744 919 1167 930 816 -59 -334 166 -76 942 640 -223 76 -113 95 -14 -181 -277 -466 -212 -522 -1080 -1328 -1866 -1521 -761 -485 -143 8 232 184 271 419 98 535 605 271 263 434 -165 -677 -627 -756 -309 110 -534 -1194 -591 -571 -13 505 452 210 189 259 46 430 604 327 284 18 -319 -7 373 210 667 771 323 1200 982 347 189 -306 -159 66 171 -48 -225 107 -191 -341 -263 -780 -788 SS 20240710T125543.8Z 8957.538701 143 1 54.38 2 52.35 93.44 100.41 67.85 0.00 1 0.00 1 0 17 7.745e-03 5.528e-03 8.422e-04 5.170e-04 2.175153e-01 2.779240e-04 2.597743e-03 -6.000000e+00 4.720959e-03 233.00 -2.00 3.54 -2.00 315.50 0.00e+00 3.114771e-04 2.690219e-05 3.745253e-05 -6.000000e+00 2.116091e-04 287.95 -2.00 20.00 -2.00 314.76 0.00e+00 1.633 0.000 302.00 328.00 3 3.4576e+00 7.2307e-04 1.9946e-02 -6.0000e+00 1.1843e-02 4.5444e-03 8.0331e-04 1.1404e-02 -6.0000e+00 1.2796e-02 -2.0476e-03 4.5671e-04 5.4880e-03 -6.0000e+00 7.6164e-03 -2.3746e-03 1.9834e-04 1.4903e-03 -6.0000e+00 3.1515e-03 2.5820e-03 2.3440e-04 1.6330e-05 2.1497e-05 -6.0000e+00 2.4241e-04 3.7470e-03 -2.1436e-05 10 0 0 10 0 0 99.99 27.49 0.24 0.00375 0.00551 198 21 1 5 0 274.590 36.00 20.00 27.49 38.77 2.6 1050.42 -936 -1762 -1851 -2577 -1532 -2015 -284 395 712 -392 -929 102 -185 -241 -134 -582 -93 1124 1233 1358 1198 468 1906 575 788 202 -641 179 224 749 1415 1152 541 -1337 -2384 -1264 -1131 -315 -327 -740 -1117 -816 -377 -557 -311 -401 -800 -302 -518 240 619 957 1080 860 630 777 299 373 634 881 1002 1308 1060 935 88 -524 84 -129 725 895 -121 104 -91 81 -167 -351 -232 -674 -293 -408 -1079 -1327 -1685 -1366 -669 -486 -108 75 241 275 191 299 28 468 328 139 288 371 -134 -508 -496 -723 -242 104 -468 -902 -510 -487 59 430 365 180 82 196 140 126 528 268 271 43 -154 -27 368 216 498 688 196 821 633 278 99 -185 -161 24 156 23 -149 127 -146 -239 -156 -545 -556 -247 -495 -515 -673 -395 -513 -76 106 206 -118 -284 32 -65 -89 -54 -238 -39 485 548 619 553 218 900 270 385 101 -315 88 104 345 677 552 273 -686 -1193 -636 -628 -190 -208 -534 -828 -628 -281 -418 -232 -311 -609 -223 -376 175 472 733 869 723 520 652 254 315 528 739 874 1164 1009 882 82 -474 75 -114 649 848 -120 106 -93 82 -157 -311 -197 -586 -255 -377 -1068 -1377 -1793 -1534 -768 -572 -133 91 290 327 218 323 30 480 356 159 338 455 -170 -635 -604 -856 -278 124 -580 -1145 -653 -652 80 611 520 255 115 262 180 160 671 346 361 59 -214 -37 507 285 644 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