File name: Pandora26s1_CambridgeMA_20240720_L2Fit_fout2c10d20240425p1-8.txt File generation date: 20241217T233648.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v10d20240425.txt Level 1 file used: Pandora26s1_CambridgeMA_20240720_L1_smca1c10d20240425p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20240720 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0963 305.2371 305.3779 305.5186 305.6594 305.8002 305.9409 306.0816 306.2224 306.3631 306.5038 306.6445 306.7851 306.9258 307.0664 307.2071 307.3477 307.4883 307.6289 307.7695 307.9101 308.0507 308.1912 308.3318 308.4723 308.6129 308.7534 308.8939 309.0344 309.1748 309.3153 309.4558 309.5962 309.7366 309.8771 310.0175 310.1579 310.2982 310.4386 310.5790 310.7193 310.8597 311.0000 311.1403 311.2806 311.4209 311.5612 311.7015 311.8417 311.9820 312.1222 312.2624 312.4026 312.5428 312.6830 312.8232 312.9634 313.1035 313.2437 313.3838 313.5239 313.6640 313.8041 313.9442 314.0843 314.2243 314.3644 314.5044 314.6444 314.7844 314.9244 315.0644 315.2044 315.3444 315.4843 315.6243 315.7642 315.9041 316.0440 316.1839 316.3238 316.4637 316.6035 316.7434 316.8832 317.0230 317.1628 317.3026 317.4424 317.5822 317.7220 317.8617 318.0015 318.1412 318.2809 318.4206 318.5603 318.7000 318.8397 318.9793 319.1190 319.2586 319.3982 319.5378 319.6774 319.8170 319.9566 320.0962 320.2357 320.3753 320.5148 320.6543 320.7938 320.9333 321.0728 321.2123 321.3517 321.4912 321.6306 321.7700 321.9094 322.0488 322.1882 322.3276 322.4669 322.6063 322.7456 322.8849 323.0243 323.1636 323.3028 323.4421 323.5814 323.7206 323.8599 323.9991 324.1383 324.2775 324.4167 324.5559 324.6951 324.8342 324.9734 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240720T101703.3Z 8967.428510 161 1 54.55 2 82.27 69.21 112.56 251.81 0.00 1 0.00 1 0 17 5.727e-01 2.789e-02 1.802e-01 4.060e-03 9.112293e-01 2.411026e-03 1.066787e-02 -6.000000e+00 3.600067e-01 232.81 -2.00 3.54 -2.00 321.89 0.00e+00 6.668750e-03 1.444247e-03 7.439690e-03 -6.000000e+00 2.003038e-02 288.48 -2.00 20.00 -2.00 321.34 0.00e+00 6.912 0.006 302.00 328.00 3 1.0442e+00 9.6019e-03 9.1356e-02 -6.0000e+00 9.2230e-01 9.2723e-01 1.3025e-02 6.3706e-02 -6.0000e+00 1.0101e+00 -1.2184e+00 1.1340e-02 3.0939e-02 -6.0000e+00 5.8591e-01 4.8263e-01 5.1791e-03 8.5033e-03 -6.0000e+00 2.3835e-01 7.1927e-05 -3.6164e-04 1.1378e-04 2.3737e-04 -6.0000e+00 1.8332e-02 8.7801e-03 -2.7600e-06 12 8 8 10 0 0 61.76 26.36 0.44 0.00878 0.00606 90 9 1 5 0 606.080 35.25 20.00 26.36 27.86 3.3 997.76 21792 -149135 900000 -6695 -67149 -221088 -152603 900000 900000 900000 900000 900000 -64492 -18325 -66403 900000 900000 900000 900000 900000 900000 -73178 900000 110108 -13747 -39833 -40929 128953 -79102 120725 62701 226015 -63506 41119 17286 900000 111960 112637 45635 46415 -28920 51396 69994 70324 69418 99917 51940 115259 18256 7584 -38321 124863 242055 69035 43797 63264 -22721 24030 54955 42486 20410 24220 16734 21561 26463 4325 16627 27891 13236 25330 13855 17335 21783 14483 -783 7402 8248 5063 4891 8046 3876 -2296 3363 -3867 716 1217 -1045 4164 6179 2711 -678 -3246 -8089 -6101 -7360 -1803 -1594 -3136 924 -2165 -3226 -3884 161 -5029 -3043 -557 -3817 -3393 -1010 -475 -1573 -1335 -1047 -1254 261 -1014 1031 480 723 1442 1936 1167 2883 3359 1242 2043 -127 1403 968 800 1714 -21 8 315 1099 -197 -542 -44 177 -164 -1055 -1412 -1181 117 -4765 900000 -46 -747 -10794 -3780 900000 900000 900000 900000 900000 -1158 -263 -1883 900000 900000 900000 900000 900000 900000 -2863 900000 783 -342 -1274 -1277 713 -3623 858 966 892 -4514 1039 532 900000 1459 1690 1568 1796 -2581 2151 2487 2499 2494 2683 2318 2867 1283 650 -5796 4092 2676 4607 3926 4771 -4037 2590 4166 3590 2249 2860 2425 3312 4065 839 2935 4725 2911 5531 3633 4449 5126 3363 -190 1505 1628 1116 1267 2427 1436 -938 1422 -1877 352 627 -571 2187 3127 1357 -331 -1564 -4152 -3369 -4793 -1320 -1372 -2870 871 -2087 -2926 -3487 129 -4266 -2673 -507 -3534 -3444 -1136 -609 -2111 -1912 -1524 -1801 358 -1394 1422 699 1097 2195 2850 1652 4176 4678 1710 2725 -174 2085 1539 1462 3215 -43 18 702 2589 -491 -1379 -111 439 -386 -2324 -3133 -2566 SS 20240720T102925.9Z 8967.437105 164 1 54.41 2 80.12 71.17 114.63 253.55 0.00 1 0.00 1 0 17 5.834e-01 1.353e-02 9.483e-02 1.589e-03 7.666322e-01 8.785131e-04 8.935777e-03 -6.000000e+00 3.552006e-01 232.81 -2.00 3.54 -2.00 320.97 0.00e+00 3.484712e-03 4.179415e-04 4.220124e-03 -6.000000e+00 1.597536e-02 288.48 -2.00 20.00 -2.00 320.31 0.00e+00 5.568 0.003 302.00 328.00 3 1.0102e+00 2.9590e-03 7.1440e-02 -6.0000e+00 8.9042e-01 1.7983e-01 3.9841e-03 4.7465e-02 -6.0000e+00 9.6228e-01 -2.4729e-01 3.7648e-03 2.3737e-02 -6.0000e+00 5.7305e-01 9.4442e-02 1.7908e-03 6.5094e-03 -6.0000e+00 2.3720e-01 3.4746e-04 2.5442e-04 4.4009e-05 1.2643e-04 -6.0000e+00 1.8259e-02 7.7390e-03 4.0213e-06 12 8 8 10 0 0 10.42 26.39 0.34 0.00774 0.00965 219 23 1 5 0 248.400 35.25 19.99 26.39 28.06 3.3 997.97 -225539 -260181 -134171 -118364 -234672 -267835 -219121 -148621 -84564 -52609 -15845 -116336 -126742 -106216 -102698 55411 -4818 -1116 65425 113445 30713 -79495 79747 -27162 -50857 -52065 -53357 -27777 -59154 -11469 -15129 4060 -54734 -19001 -30523 7880 -5738 3190 4311 475 -14562 719 6954 3053 2079 12930 1927 12614 -1997 -2791 -11318 13999 20682 10335 6430 8560 -6184 4565 6890 4529 4277 5957 3348 6195 5775 1540 2693 4459 4163 4768 2073 2397 3864 1225 -26 704 415 -615 -769 81 -898 -1469 -1487 -2332 -1273 -840 -450 881 992 861 245 -675 -2016 -1276 -1999 -747 -508 -282 -195 -901 -1128 -1352 -758 -958 -1141 -917 -1217 -1118 200 466 -61 120 -164 -8 -7 -25 679 535 563 419 448 409 1060 776 400 715 -37 860 901 265 232 -68 -39 -75 60 37 -208 168 -165 -156 -194 -543 -579 -2764 -5168 -794 -584 -3571 -5811 -3211 -1336 -446 -220 -52 -1262 -1984 -1761 -2069 275 -50 -12 406 457 290 -2328 507 -547 -1395 -1509 -1579 -637 -1953 -270 -450 120 -3291 -836 -1504 276 -261 160 260 35 -1390 63 605 284 200 1152 200 1241 -245 -381 -1900 2048 3128 1885 1296 1763 -1368 988 1429 965 968 1350 886 1766 1728 484 857 1495 1576 2027 980 1063 1794 545 -11 262 151 -241 -349 40 -520 -970 -992 -1680 -970 -674 -375 737 819 681 184 -487 -1472 -995 -1796 -720 -529 -331 -243 -1117 -1305 -1425 -799 -1029 -1213 -1031 -1466 -1373 270 665 -96 188 -259 -12 -11 -39 1047 865 900 682 716 664 1646 1165 581 1067 -55 1303 1459 487 444 -133 -82 -158 135 84 -477 388 -375 -355 -414 -1155 -1216 SS 20240720T103702.7Z 8967.442393 168 1 54.48 2 78.79 72.38 115.91 254.63 0.00 1 0.00 1 0 17 4.821e-01 1.549e-02 1.863e-01 2.321e-03 6.929331e-01 1.287382e-03 7.879590e-03 -6.000000e+00 2.943252e-01 232.81 -2.00 3.54 -2.00 320.79 0.00e+00 1.488591e-03 5.719869e-04 2.643043e-03 -6.000000e+00 1.412596e-02 288.48 -2.00 20.00 -2.00 320.10 0.00e+00 4.962 0.002 302.00 328.00 3 2.3041e+00 4.2410e-03 6.2951e-02 -6.0000e+00 7.4154e-01 1.7273e-01 5.5338e-03 4.0099e-02 -6.0000e+00 8.0336e-01 -2.2728e-01 5.0209e-03 1.9699e-02 -6.0000e+00 4.7488e-01 8.5723e-02 2.4286e-03 5.3148e-03 -6.0000e+00 1.9631e-01 1.8004e-04 2.2288e-04 6.7603e-05 8.7270e-05 -6.0000e+00 1.5129e-02 8.3321e-03 -3.5459e-05 12 8 8 10 0 0 99.49 26.40 0.39 0.00833 0.01001 114 12 1 5 0 477.810 35.25 20.00 26.40 28.16 3.3 998.69 -154786 -225450 102455 -3842 -174476 -236674 -125234 -19220 900000 900000 52748 147439 -88304 -15758 -88796 31520 24878 50862 108869 900000 50157 -80768 197928 -15821 -32974 -40102 -31457 14429 -62556 1260 11678 29351 -47978 -2347 -7515 36663 11799 19537 5408 5277 -14061 4604 10198 12956 4743 10087 10147 16378 -1081 -494 -16351 22025 26577 13380 4416 11701 -11368 1634 10827 4735 3130 4713 2529 4071 5048 -3065 169 3567 1514 4369 1732 1787 3524 1618 -785 -805 394 -1581 -105 -42 -612 -2434 -1362 -2913 -1620 -1271 -447 1164 1681 1439 -303 -809 -2195 -1298 -1986 -276 321 -312 948 -1006 -1212 -1479 -356 -1219 -897 -418 -1396 -1227 210 599 -434 39 -149 -51 154 -137 486 700 479 317 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