File name: Pandora26s1_CambridgeMA_20240726_L2Fit_fout2c10d20240425p1-8.txt File generation date: 20241217T234003.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v10d20240425.txt Level 1 file used: Pandora26s1_CambridgeMA_20240726_L1_smca1c10d20240425p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20240726 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0963 305.2371 305.3779 305.5186 305.6594 305.8002 305.9409 306.0816 306.2224 306.3631 306.5038 306.6445 306.7851 306.9258 307.0664 307.2071 307.3477 307.4883 307.6289 307.7695 307.9101 308.0507 308.1912 308.3318 308.4723 308.6129 308.7534 308.8939 309.0344 309.1748 309.3153 309.4558 309.5962 309.7366 309.8771 310.0175 310.1579 310.2982 310.4386 310.5790 310.7193 310.8597 311.0000 311.1403 311.2806 311.4209 311.5612 311.7015 311.8417 311.9820 312.1222 312.2624 312.4026 312.5428 312.6830 312.8232 312.9634 313.1035 313.2437 313.3838 313.5239 313.6640 313.8041 313.9442 314.0843 314.2243 314.3644 314.5044 314.6444 314.7844 314.9244 315.0644 315.2044 315.3444 315.4843 315.6243 315.7642 315.9041 316.0440 316.1839 316.3238 316.4637 316.6035 316.7434 316.8832 317.0230 317.1628 317.3026 317.4424 317.5822 317.7220 317.8617 318.0015 318.1412 318.2809 318.4206 318.5603 318.7000 318.8397 318.9793 319.1190 319.2586 319.3982 319.5378 319.6774 319.8170 319.9566 320.0962 320.2357 320.3753 320.5148 320.6543 320.7938 320.9333 321.0728 321.2123 321.3517 321.4912 321.6306 321.7700 321.9094 322.0488 322.1882 322.3276 322.4669 322.6063 322.7456 322.8849 323.0243 323.1636 323.3028 323.4421 323.5814 323.7206 323.8599 323.9991 324.1383 324.2775 324.4167 324.5559 324.6951 324.8342 324.9734 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240726T102249.3Z 8973.432515 189 1 54.13 2 82.14 71.04 41.67 208.92 0.00 1 0.00 1 0 17 5.687e-01 2.769e-02 1.960e-01 4.345e-03 8.854541e-01 2.537440e-03 9.958956e-03 -6.000000e+00 3.548518e-01 232.59 -2.00 3.54 -2.00 321.80 0.00e+00 8.519104e-03 1.480249e-03 3.045046e-03 -6.000000e+00 1.871290e-02 288.61 -2.00 20.00 -2.00 321.23 0.00e+00 6.810 0.006 302.00 328.00 3 1.2532e+00 9.9513e-03 8.3411e-02 -6.0000e+00 9.0080e-01 9.1215e-01 1.3355e-02 4.8583e-02 -6.0000e+00 9.8490e-01 -1.2044e+00 1.1359e-02 2.6520e-02 -6.0000e+00 5.7859e-01 4.8571e-01 5.2240e-03 1.1728e-02 -6.0000e+00 2.3570e-01 6.5632e-05 3.5756e-05 1.2190e-04 2.1664e-04 -6.0000e+00 1.8152e-02 7.6251e-03 1.1582e-06 12 8 8 10 0 0 7.82 26.13 0.43 0.00763 0.00789 71 7 1 5 0 762.280 35.00 20.00 26.13 25.63 3.5 987.09 -23093 -154632 201476 900000 -101847 -170754 -141339 54109 286063 900000 900000 900000 -17931 -58719 23179 900000 900000 900000 900000 900000 149883 -100956 900000 30326 -75699 -2725 -13021 -5724 -74862 35725 14377 900000 -65630 21113 -3209 900000 16760 100409 73666 25136 -32109 21833 57721 81117 41856 119483 51245 115444 31648 6456 -20458 176049 143712 81456 31591 45937 -19832 34035 55005 43756 9589 17257 12700 16746 50607 -1595 23548 18051 10345 17893 17300 16353 25798 12666 -10102 6587 8455 3798 2547 13271 -1438 -6386 205 -4587 -2787 -508 -1018 3450 6769 5072 374 -2145 -8481 -4959 -5197 -2793 -1209 -524 -351 -1257 -2099 -3802 999 -2755 -2247 -315 -4495 -3140 82 -203 -3017 -962 32 -256 16 -1460 525 -346 -49 1147 1250 99 2920 3072 967 3225 466 545 1544 1036 2073 254 -243 123 980 -247 -268 647 -267 -445 -545 -1610 -1437 -240 -6418 852 900000 -1957 -6103 -3748 229 1209 900000 900000 900000 -234 -1467 312 900000 900000 900000 900000 900000 749 -5975 900000 538 -3549 -67 -341 -136 -3671 665 401 900000 -5299 723 -134 900000 624 1868 2087 1307 -3203 1329 2513 2812 2159 2879 2513 3123 2114 606 -2794 3721 4557 5131 3406 4370 -3622 3511 4418 3885 1257 2335 2046 2874 6482 -347 4092 3548 2458 4410 4586 4431 6097 3132 -2814 1415 1744 886 705 3961 -584 -2820 93 -2320 -1470 -276 -575 1889 3528 2567 187 -1056 -4504 -2783 -3398 -2115 -1060 -477 -341 -1222 -2089 -3474 810 -2336 -2003 -293 -4675 -3248 93 -264 -4162 -1386 46 -365 24 -2188 791 -510 -75 1759 1862 143 4257 4318 1343 4271 640 819 2439 1879 3846 520 -536 290 2277 -605 -668 1606 -654 -1032 -1260 -3528 -3087 SS 20240726T104145.8Z 8973.445669 194 1 54.35 2 78.80 74.06 43.41 215.27 0.00 1 0.00 1 0 17 4.054e-01 9.263e-03 2.809e-02 9.737e-04 6.948147e-01 5.298724e-04 7.909822e-03 -6.000000e+00 2.466656e-01 232.59 -2.00 3.54 -2.00 320.38 0.00e+00 1.802089e-03 2.074014e-04 1.917451e-03 -6.000000e+00 1.110723e-02 288.61 -2.00 20.00 -2.00 319.65 0.00e+00 4.967 0.002 302.00 328.00 3 7.8335e-01 1.6436e-03 6.2338e-02 -6.0000e+00 6.1797e-01 1.1420e-01 2.0814e-03 3.8283e-02 -6.0000e+00 6.6792e-01 -1.3251e-01 1.8475e-03 1.9176e-02 -6.0000e+00 3.9787e-01 4.5697e-02 9.1680e-04 5.5263e-03 -6.0000e+00 1.6480e-01 8.2235e-04 2.9322e-04 2.7541e-05 7.9622e-05 -6.0000e+00 1.2687e-02 6.9855e-03 4.4005e-06 11 8 0 10 0 0 -6.55 26.16 0.32 0.00699 0.00919 347 36 1 5 0 156.610 35.00 20.00 26.16 26.54 3.4 990.76 -178050 -161758 -133693 -98941 -160645 -169785 -152953 -121230 -87883 -94010 -74221 -22921 -72116 -66788 -49365 -25504 -20158 -5620 -17870 8218 -17088 -50442 3990 -20544 -37473 -15382 -28473 -31151 -24835 -15256 -16467 405 -25251 -10032 -10950 -4566 -9099 -1778 -3723 -819 -5730 -723 1753 1569 1312 2368 806 3805 1559 119 -630 6429 6165 5240 2851 3179 -222 2465 3364 2622 2714 2997 3251 2437 3416 634 2235 1680 2361 1485 1367 1322 1401 784 -465 -1311 8 -1232 -687 -397 -1529 -2089 -1966 -2048 -1192 -481 -280 220 447 411 125 85 -631 -625 -569 -495 -48 195 -224 -762 -615 -979 -406 -183 -676 -1046 -593 -551 125 458 121 111 296 170 149 288 601 284 196 141 -68 150 456 493 431 640 112 835 562 76 216 -165 -136 -64 48 -92 -148 225 -129 -247 -132 -391 -331 -2773 -2442 -1600 -817 -2380 -2838 -2396 -1577 -918 -1143 -825 -183 -1198 -1344 -1036 -499 -425 -114 -441 165 -454 -1935 95 -685 -1598 -551 -1171 -1307 -1014 -637 -832 20 -1858 -662 -728 -297 -705 -154 -401 -100 -825 -106 263 242 207 380 136 651 265 23 -134 1424 1507 1402 829 962 -71 762 1012 797 871 978 1194 991 1426 271 954 767 1108 793 791 787 814 430 -235 -663 4 -632 -369 -251 -1053 -1635 -1563 -1744 -1076 -428 -260 206 413 363 111 72 -530 -557 -537 -509 -53 244 -282 -951 -754 -1098 -453 -208 -771 -1267 -761 -724 172 665 192 176 467 271 228 428 905 449 310 228 -109 241 706 734 648 929 163 1287 928 135 399 -312 -261 -131 101 -202 -318 486 -275 -524 -274 -772 -646 SS 20240726T104813.9Z 8973.450160 197 1 54.33 2 77.65 75.08 44.07 217.34 0.00 1 0.00 1 0 17 2.907e-01 7.771e-03 1.543e-02 7.130e-04 6.392207e-01 3.849541e-04 7.280031e-03 -6.000000e+00 1.768593e-01 232.59 -2.00 3.54 -2.00 319.97 0.00e+00 1.837832e-03 1.309685e-04 1.289851e-03 -6.000000e+00 7.964657e-03 288.61 -2.00 20.00 -2.00 319.21 0.00e+00 4.539 0.002 302.00 328.00 3 6.7294e-01 1.1439e-03 5.6822e-02 -6.0000e+00 4.4308e-01 7.9873e-02 1.3946e-03 3.4337e-02 -6.0000e+00 4.7891e-01 -8.6755e-02 1.1734e-03 1.7099e-02 -6.0000e+00 2.8527e-01 2.7099e-02 5.9692e-04 5.1032e-03 -6.0000e+00 1.1816e-01 1.4589e-03 2.3842e-04 2.0586e-05 6.5841e-05 -6.0000e+00 9.0976e-03 6.9855e-03 -1.1915e-05 11 8 0 10 0 0 8.25 26.18 0.29 0.00699 0.00878 491 52 1 5 0 110.640 35.00 20.00 26.18 26.69 3.4 991.78 -126323 -119936 -93266 -85101 -110877 -115249 -108466 -84789 -72311 -63383 -58954 -49267 -55240 -42041 -27614 -14219 -16058 -1688 -7226 -677 -9711 -25144 795 -10251 -20903 -11702 -18164 -14384 -16448 -7300 -10309 -2399 -13841 -5916 -8234 -2825 -6575 -1076 -682 -1007 -2471 53 1223 843 668 1905 409 2426 62 680 323 3874 3756 3166 2158 2443 307 1493 1726 2343 2119 2787 2856 2314 2319 746 1433 794 1465 1012 398 326 491 339 -691 -898 -455 -1121 -1147 -689 -1341 -1551 -1993 -1656 -948 -438 -129 152 567 316 169 244 -276 -115 -251 -310 136 288 -322 -657 -666 -907 -257 -120 -857 -1014 -572 -562 64 277 190 125 198 189 170 432 621 391 193 -98 -164 211 513 334 476 586 235 887 533 76 66 -193 -130 -110 103 -92 -73 150 -118 -204 -95 -425 -330 -2029 -2051 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