File name: Pandora26s1_CambridgeMA_20240809_L2Fit_fout2c7d20230915p1-8.txt File generation date: 20241010T190406.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v7d20230915.txt Level 1 file used: Pandora26s1_CambridgeMA_20240809_L1_smca1c7d20230915p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20240809 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 5 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.1176 305.2583 305.3991 305.5398 305.6805 305.8212 305.9619 306.1026 306.2432 306.3839 306.5245 306.6651 306.8057 306.9464 307.0869 307.2275 307.3681 307.5087 307.6492 307.7897 307.9303 308.0708 308.2113 308.3518 308.4923 308.6327 308.7732 308.9136 309.0541 309.1945 309.3349 309.4753 309.6157 309.7561 309.8964 310.0368 310.1771 310.3175 310.4578 310.5981 310.7384 310.8787 311.0189 311.1592 311.2995 311.4397 311.5799 311.7201 311.8604 312.0005 312.1407 312.2809 312.4211 312.5612 312.7013 312.8415 312.9816 313.1217 313.2618 313.4019 313.5419 313.6820 313.8220 313.9621 314.1021 314.2421 314.3821 314.5221 314.6621 314.8020 314.9420 315.0819 315.2219 315.3618 315.5017 315.6416 315.7815 315.9213 316.0612 316.2010 316.3409 316.4807 316.6205 316.7603 316.9001 317.0399 317.1797 317.3194 317.4592 317.5989 317.7386 317.8783 318.0180 318.1577 318.2974 318.4371 318.5767 318.7164 318.8560 318.9956 319.1352 319.2748 319.4144 319.5540 319.6935 319.8331 319.9726 320.1122 320.2517 320.3912 320.5307 320.6702 320.8096 320.9491 321.0885 321.2280 321.3674 321.5068 321.6462 321.7856 321.9250 322.0643 322.2037 322.3430 322.4823 322.6217 322.7610 322.9003 323.0395 323.1788 323.3181 323.4573 323.5965 323.7358 323.8750 324.0142 324.1534 324.2926 324.4317 324.5709 324.7100 324.8491 324.9883 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240809T153423.8Z 8987.648886 216 1 1.90 2 31.32 143.17 82.32 106.87 0.00 1 0.00 1 0 17 7.756e-03 6.467e-03 4.632e-03 3.615e-03 1.592137e-01 1.961693e-03 1.940788e-03 -6.000000e+00 4.711500e-03 232.07 -2.00 3.54 -2.00 314.27 0.00e+00 2.374455e-04 1.513767e-04 2.766592e-05 -6.000000e+00 2.128121e-04 288.91 -2.00 20.00 -2.00 313.65 0.00e+00 1.170 0.000 302.00 328.00 3 3.9995e+00 5.0361e-03 1.4389e-02 -6.0000e+00 1.1787e-02 4.0509e-02 5.5664e-03 8.3557e-03 -6.0000e+00 1.2743e-02 -3.5869e-03 3.1812e-03 4.0437e-03 -6.0000e+00 7.5952e-03 -3.8505e-03 1.3361e-03 1.0996e-03 -6.0000e+00 3.1527e-03 2.6185e-03 2.3407e-04 1.1345e-04 1.7749e-05 -6.0000e+00 2.4272e-04 -1.0779e-02 0.0000e+00 12 9 1 12 1 1 999.00 27.02 0.22 -0.01078 -0.00902 2 9 1 5 0 630.440 35.75 20.00 27.02 36.38 3.1 1036.17 976 -1283 -1663 -1759 -2253 -357 1310 706 1030 -974 -56 228 -412 385 -895 -439 -911 601 300 436 878 291 1385 -85 618 -37 -450 -369 840 1084 1669 1843 480 -2011 -1903 390 59 -24 -120 -764 -1204 -897 -320 -190 -569 194 -823 678 -442 642 666 232 1158 1142 492 603 504 -144 147 770 882 1530 874 1130 317 -1098 -230 205 957 207 -340 -135 -195 112 50 -249 148 -913 -494 -1273 -1201 -1515 -1562 -1301 -888 28 253 -563 198 -12 -36 277 -334 365 590 -299 440 522 228 -560 -492 -1115 -229 154 -567 -1186 -278 -248 304 394 236 232 210 990 24 222 876 -4 307 -227 -163 -152 416 848 306 872 714 419 597 383 114 59 -241 162 122 -87 -179 373 -285 -671 -266 -870 -414 417 -547 -741 -723 -914 -139 530 294 458 -450 -26 107 -198 203 -489 -252 -508 338 173 256 517 172 827 -53 378 -23 -287 -221 495 624 983 1073 293 -1243 -1128 229 38 -17 -91 -622 -1008 -774 -279 -166 -495 165 -714 558 -358 516 556 195 1009 1030 455 542 456 -130 137 718 818 1501 877 1157 315 -1062 -214 187 890 205 -349 -143 -205 117 49 -238 134 -804 -433 -1185 -1181 -1557 -1700 -1435 -1005 33 305 -701 243 -14 -42 302 -351 372 627 -335 518 638 278 -670 -573 -1273 -254 177 -680 -1457 -354 -318 405 529 325 317 281 1255 30 267 1049 -5 387 -293 -215 -200 528 1059 377 1052 830 493 706 477 143 75 -313 210 167 -120 -248 523 -403 -932 -369 -1182 -574 SS 20240809T153843.1Z 8987.651887 219 1 2.14 2 30.85 144.97 81.59 107.63 0.00 1 0.00 1 0 17 8.005e-03 6.459e-03 2.521e-03 1.996e-03 1.552823e-01 1.084334e-03 1.888783e-03 -6.000000e+00 4.862000e-03 232.07 -2.00 3.54 -2.00 314.17 0.00e+00 1.326320e-04 8.214008e-05 2.088805e-05 -6.000000e+00 2.196341e-04 288.91 -2.00 20.00 -2.00 313.57 0.00e+00 1.164 0.000 302.00 328.00 3 3.2312e+00 2.7814e-03 1.4211e-02 -6.0000e+00 1.2163e-02 1.9292e-02 3.0713e-03 8.1402e-03 -6.0000e+00 1.3150e-02 8.0488e-04 1.7586e-03 3.9394e-03 -6.0000e+00 7.8381e-03 -2.5447e-03 7.3760e-04 1.0679e-03 -6.0000e+00 3.2531e-03 5.7588e-03 8.1406e-05 6.2693e-05 1.7477e-05 -6.0000e+00 2.5051e-04 -1.0087e-02 0.0000e+00 12 9 1 12 1 1 97.42 27.02 0.36 -0.01009 -0.00948 6 19 1 5 0 304.530 35.50 20.01 27.02 36.90 3.1 1039.60 -1 -2311 -1420 -2720 -1276 -295 440 1139 -152 -1524 -466 286 -67 480 532 269 104 1539 859 1193 909 716 1655 814 647 -4 -692 -226 565 1435 1199 1263 141 -1592 -2163 -1068 -1137 -25 -93 -1116 -1462 -867 -637 -270 -238 -829 -871 -375 -185 773 804 299 816 1138 858 1000 433 404 742 1304 918 1161 1211 930 -418 -570 -33 -225 674 606 -9 77 -137 246 -200 -332 -551 -665 -759 -491 -1271 -1288 -1856 -1315 -775 -684 -311 -110 79 -48 291 425 142 596 563 281 415 247 -74 -377 -265 -1030 -352 109 -386 -1083 -430 -313 272 415 466 622 269 -18 149 261 178 218 -55 285 -160 129 606 251 692 634 523 754 226 425 83 -141 -223 3 334 92 -435 -8 67 -554 -110 -605 -641 0 -1068 -635 -1203 -510 -121 179 504 -69 -713 -215 135 -33 256 294 157 60 883 507 717 552 436 1017 500 412 -2 -438 -139 326 842 726 762 89 -1009 -1325 -656 -734 -18 -71 -929 -1260 -741 -552 -233 -205 -730 -742 -319 -152 632 682 258 706 1015 784 925 405 375 680 1199 851 1104 1219 929 -422 -548 -31 -205 627 602 -9 79 -146 251 -196 -315 -496 -576 -688 -470 -1261 -1340 -1991 -1436 -874 -797 -379 -133 97 -56 333 456 145 613 586 309 485 294 -92 -454 -309 -1168 -400 125 -463 -1339 -537 -406 356 553 637 839 355 -23 181 312 213 265 -71 372 -208 167 780 319 852 764 608 881 269 530 104 -181 -284 4 451 127 -603 -11 95 -769 -151 -838 -880 SS 20240809T154315.7Z 8987.655043 222 1 54.40 2 30.38 146.91 80.82 108.43 0.00 1 0.00 1 0 17 7.459e-03 5.909e-03 6.358e-04 4.926e-04 1.559844e-01 2.678066e-04 1.885004e-03 -6.000000e+00 4.530759e-03 232.07 -2.00 3.54 -2.00 314.31 0.00e+00 2.486727e-04 2.070797e-05 1.391506e-05 -6.000000e+00 2.046579e-04 288.91 -2.00 20.00 -2.00 313.68 0.00e+00 1.159 0.000 302.00 328.00 3 3.7966e+00 6.8742e-04 1.4177e-02 -6.0000e+00 1.1335e-02 2.2141e-02 7.5940e-04 8.1577e-03 -6.0000e+00 1.2254e-02 -1.3246e-04 4.3455e-04 3.9431e-03 -6.0000e+00 7.3039e-03 -3.3575e-03 1.8270e-04 1.0793e-03 -6.0000e+00 3.0317e-03 3.2812e-03 1.5688e-04 1.5527e-05 1.6965e-05 -6.0000e+00 2.3342e-04 -1.0492e-02 0.0000e+00 10 0 0 10 0 0 99.99 27.07 0.32 -0.01049 -0.00931 164 17 1 5 0 331.690 35.75 20.01 27.07 37.52 3.0 1041.78 -403 -1670 -1162 -2663 -1902 -230 -104 1209 354 -995 -858 346 448 -30 632 -217 128 1155 962 1522 966 449 1629 599 363 108 -489 -230 247 863 1624 1131 465 -1289 -2282 -935 -692 -141 -147 -861 -1166 -698 -591 -724 -410 -331 -731 -243 -540 130 697 914 904 1068 450 729 609 467 582 846 1001 1252 1053 749 -15 -769 -79 -375 791 557 -109 118 83 165 -227 -362 -344 -733 -478 -609 -1167 -1367 -1763 -1399 -641 -489 -190 11 273 187 158 434 44 352 479 166 363 413 -83 -409 -373 -647 -191 121 -470 -955 -422 -410 47 451 364 246 196 231 142 274 381 218 227 6 -81 56 333 372 512 620 349 969 607 197 191 -211 -139 -32 29 -74 -224 99 -134 -189 -186 -524 -665 -170 -744 -503 -1079 -750 -87 -41 489 155 -449 -384 158 208 -15 331 -121 73 665 568 912 553 259 945 364 229 69 -305 -134 142 485 932 684 276 -770 -1400 -573 -440 -98 -114 -684 -994 -613 -504 -620 -363 -288 -619 -197 -447 107 567 779 806 940 406 666 561 427 527 770 947 1204 1031 753 -15 -725 -71 -338 751 560 -113 122 88 168 -225 -339 -307 -632 -429 -575 -1171 -1429 -1883 -1572 -735 -576 -234 14 328 222 180 465 46 366 501 182 419 496 -103 -497 -442 -751 -216 137 -554 -1194 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