File name: Pandora26s1_CambridgeMA_20240810_L2Fit_fout2c7d20230915p1-8.txt File generation date: 20241010T190844.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v7d20230915.txt Level 1 file used: Pandora26s1_CambridgeMA_20240810_L1_smca1c7d20230915p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20240810 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 5 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.1176 305.2583 305.3991 305.5398 305.6805 305.8212 305.9619 306.1026 306.2432 306.3839 306.5245 306.6651 306.8057 306.9464 307.0869 307.2275 307.3681 307.5087 307.6492 307.7897 307.9303 308.0708 308.2113 308.3518 308.4923 308.6327 308.7732 308.9136 309.0541 309.1945 309.3349 309.4753 309.6157 309.7561 309.8964 310.0368 310.1771 310.3175 310.4578 310.5981 310.7384 310.8787 311.0189 311.1592 311.2995 311.4397 311.5799 311.7201 311.8604 312.0005 312.1407 312.2809 312.4211 312.5612 312.7013 312.8415 312.9816 313.1217 313.2618 313.4019 313.5419 313.6820 313.8220 313.9621 314.1021 314.2421 314.3821 314.5221 314.6621 314.8020 314.9420 315.0819 315.2219 315.3618 315.5017 315.6416 315.7815 315.9213 316.0612 316.2010 316.3409 316.4807 316.6205 316.7603 316.9001 317.0399 317.1797 317.3194 317.4592 317.5989 317.7386 317.8783 318.0180 318.1577 318.2974 318.4371 318.5767 318.7164 318.8560 318.9956 319.1352 319.2748 319.4144 319.5540 319.6935 319.8331 319.9726 320.1122 320.2517 320.3912 320.5307 320.6702 320.8096 320.9491 321.0885 321.2280 321.3674 321.5068 321.6462 321.7856 321.9250 322.0643 322.2037 322.3430 322.4823 322.6217 322.7610 322.9003 323.0395 323.1788 323.3181 323.4573 323.5965 323.7358 323.8750 324.0142 324.1534 324.2926 324.4317 324.5709 324.7100 324.8491 324.9883 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240810T121410.1Z 8988.509839 99 1 3.75 2 64.24 92.47 127.66 68.82 0.00 1 0.00 1 0 17 3.380e-02 9.284e-03 1.511e-02 5.164e-03 3.028530e-01 2.734021e-03 3.571001e-03 -6.000000e+00 2.053186e-02 232.04 -2.00 3.54 -2.00 317.11 0.00e+00 3.695040e-04 3.877781e-04 9.477377e-05 -6.000000e+00 9.275961e-04 288.93 -2.00 20.00 -2.00 316.26 0.00e+00 2.287 0.000 302.00 328.00 3 3.9488e+00 7.2618e-03 2.7830e-02 -6.0000e+00 5.1361e-02 3.4417e-02 8.1517e-03 1.5903e-02 -6.0000e+00 5.5527e-02 -3.9293e-03 4.7774e-03 7.6330e-03 -6.0000e+00 3.3098e-02 -5.9936e-03 2.2677e-03 2.0947e-03 -6.0000e+00 1.3740e-02 7.1980e-04 1.0377e-04 1.6301e-04 2.6539e-05 -6.0000e+00 1.0579e-03 -1.0628e-02 0.0000e+00 12 9 1 12 1 1 999.00 27.01 0.38 -0.01063 -0.00985 2 5 1 5 0 1246.790 35.50 20.00 27.01 31.30 3.3 1012.45 -12256 1646 4678 -9530 -15602 -21271 12786 90 -732 -12277 -3121 1174 231 115 -153 180 -5 3654 906 2197 2708 -6982 6580 2094 -983 2420 -1557 923 1234 -1110 4433 992 -574 -1724 -3540 378 -1418 671 269 -945 -1713 -1610 -536 1333 -674 493 -480 2155 516 1265 14 1827 1605 3256 109 574 -1218 647 1340 2580 595 194 -634 7 568 -1385 -471 -225 88 1797 463 -15 153 -397 -796 -913 482 -530 425 409 -1666 -3166 -2079 -1796 -1385 -805 68 367 713 437 518 1018 566 -98 208 475 608 794 -369 -847 -50 -458 -166 260 -801 -1023 -264 -1213 1133 346 65 -475 297 1013 -605 -197 252 454 362 50 61 198 517 463 -4 554 -224 974 -54 516 123 691 -842 226 28 98 198 253 24 -995 -490 -153 -384 -1549 194 535 -1181 -1917 -2753 1269 11 -101 -1793 -470 182 37 21 -32 41 -1 900 239 590 735 -1937 1802 634 -295 719 -472 284 365 -342 1384 319 -199 -609 -1239 130 -553 279 132 -498 -987 -970 -328 808 -417 300 -290 1253 305 762 9 1160 1084 2270 81 434 -889 492 999 1914 441 155 -519 6 472 -1173 -377 -181 77 1602 425 -14 144 -380 -705 -779 376 -411 349 355 -1557 -3293 -2163 -1975 -1540 -947 83 435 876 514 594 1068 591 -103 221 555 750 1016 -474 -1118 -61 -553 -194 313 -993 -1340 -344 -1679 1623 509 96 -707 440 1457 -822 -267 343 616 524 73 90 287 759 651 -5 741 -293 1287 -74 745 179 1033 -1314 349 45 161 334 434 41 -1676 -792 -249 -618 SS 20240810T121923.9Z 8988.513471 102 1 54.32 2 63.28 93.38 126.80 69.94 0.00 1 0.00 1 0 17 1.038e-02 5.417e-03 8.613e-04 3.541e-04 2.922292e-01 1.881070e-04 3.469018e-03 -6.000000e+00 6.301658e-03 232.04 -2.00 3.54 -2.00 316.69 0.00e+00 3.154325e-04 2.383208e-05 8.207490e-05 -6.000000e+00 2.847569e-04 288.93 -2.00 20.00 -2.00 315.84 0.00e+00 2.211 0.000 302.00 328.00 3 1.8475e+00 4.9584e-04 2.6883e-02 -6.0000e+00 1.5764e-02 1.9107e-02 5.5512e-04 1.5313e-02 -6.0000e+00 1.7043e-02 -5.1132e-03 3.2072e-04 7.3816e-03 -6.0000e+00 1.0159e-02 -1.9667e-03 1.4812e-04 2.0025e-03 -6.0000e+00 4.2163e-03 6.4847e-03 9.7865e-05 1.1139e-05 2.6503e-05 -6.0000e+00 3.2476e-04 -9.3183e-03 0.0000e+00 10 0 0 10 0 0 99.98 27.02 0.29 -0.00932 -0.00858 926 97 1 5 0 58.650 35.50 20.01 27.02 31.84 3.3 1015.40 -2557 -3080 -2814 -4027 -4243 -2791 -3048 -329 -996 -2046 -1604 -402 -34 -486 458 -104 405 1141 996 1641 1019 547 2071 786 469 183 -633 -580 166 983 1394 950 195 -1353 -2573 -1067 -1082 -327 -193 -790 -1063 -637 -458 -539 -283 -225 -691 -272 -303 226 875 778 947 971 598 865 544 414 747 993 1301 1531 1229 1027 133 -467 58 -151 958 621 -102 160 -95 65 -111 -414 -289 -738 -305 -611 -1009 -1297 -1781 -1409 -682 -559 -169 -5 184 148 199 442 199 476 517 162 193 300 -219 -502 -516 -677 -294 92 -518 -974 -466 -457 39 344 294 167 194 174 145 313 503 308 210 -14 -215 7 284 217 475 568 347 1003 689 241 115 -166 -71 21 83 -52 -188 47 -130 -205 -126 -462 -538 -374 -484 -440 -598 -588 -379 -447 -52 -173 -373 -298 -79 -7 -114 120 -30 113 330 300 507 321 175 676 274 172 69 -236 -205 56 334 505 348 76 -540 -1010 -423 -477 -157 -103 -452 -660 -412 -303 -340 -188 -149 -452 -174 -194 148 570 542 698 711 454 669 427 323 575 768 1048 1258 1038 906 116 -404 47 -125 810 558 -100 153 -94 62 -102 -363 -234 -591 -260 -557 -985 -1330 -1877 -1568 -774 -647 -204 -7 225 173 223 473 210 498 553 185 235 383 -281 -654 -632 -803 -351 109 -638 -1271 -612 -631 54 495 441 244 281 243 196 418 674 418 293 -21 -310 9 404 306 637 753 447 1312 928 336 168 -243 -106 32 129 -85 -305 77 -214 -340 -200 -738 -853 SS 20240810T122353.6Z 8988.516593 105 1 54.26 2 62.45 94.17 126.06 70.88 0.00 1 0.00 1 0 17 8.608e-03 5.467e-03 3.075e-04 1.511e-04 2.836131e-01 8.054083e-05 3.379660e-03 -6.000000e+00 5.227300e-03 232.04 -2.00 3.54 -2.00 316.29 0.00e+00 3.567909e-04 9.279851e-06 6.617939e-05 -6.000000e+00 2.362016e-04 288.93 -2.00 20.00 -2.00 315.47 0.00e+00 2.151 0.000 302.00 328.00 3 2.7263e-01 2.1093e-04 2.6118e-02 -6.0000e+00 1.3076e-02 1.0850e-02 2.3556e-04 1.4841e-02 -6.0000e+00 1.4137e-02 -5.3714e-03 1.3476e-04 7.1522e-03 -6.0000e+00 8.4269e-03 -9.7311e-04 6.0795e-05 1.9425e-03 -6.0000e+00 3.4975e-03 3.3801e-02 9.5209e-05 4.7391e-06 2.6403e-05 -6.0000e+00 2.6938e-04 -9.5334e-03 0.0000e+00 10 0 0 10 0 0 99.98 27.04 0.29 -0.00953 -0.00882 2448 257 1 5 0 22.160 35.75 20.01 27.04 32.24 3.3 1017.31 -1401 -2294 -2398 -3587 -2798 -1743 -1164 -74 -679 -1603 -1693 -415 207 31 519 -118 61 931 740 1162 885 708 1293 693 361 60 -839 -764 93 678 1230 719 384 -1640 -2441 -1239 -1035 -193 26 -541 -853 -550 -272 -478 -62 -112 -476 -85 -137 484 1010 839 934 965 587 883 696 425 649 922 1202 1443 1236 960 -43 -503 48 -182 892 569 -254 -18 -180 36 -246 -403 -317 -659 -331 -683 -1135 -1280 -1862 -1420 -736 -592 -186 -50 160 122 237 398 176 552 447 161 200 302 -224 -518 -497 -682 -296 71 -484 -953 -470 -407 28 357 330 211 202 249 215 421 573 297 217 9 -217 28 291 246 487 595 330 1000 701 233 120 -216 -94 -18 48 -61 -167 60 -147 -237 -149 -488 -560 -255 -449 -468 -665 -519 -318 -227 -15 -147 -362 -392 -101 53 9 159 -39 20 318 263 424 328 266 499 267 146 25 -345 -298 37 269 488 311 167 -727 -1060 -544 -504 -98 15 -338 -554 -372 -189 -320 -42 -77 -325 -57 -91 329 693 616 697 725 456 700 558 340 512 731 957 1232 1096 858 -38 -435 41 -156 788 522 -244 -18 -177 35 -228 -352 -265 -543 -291 -626 -1128 -1307 -1979 -1545 -826 -687 -226 -60 195 143 271 431 184 574 481 187 243 378 -292 -662 -612 -807 -348 84 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