File name: Pandora26s1_CambridgeMA_20240818_L2Fit_fwvt1c7d20230915p1-8.txt File generation date: 20241010T180848.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v7d20230915.txt Level 1 file used: Pandora26s1_CambridgeMA_20240818_L1_smca1c7d20230915p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20240818 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 5 First and last pixel inside fitting window: 1619 1769 Nominal wavelengths inside fitting window [nm]: 492.0520 492.1726 492.2933 492.4139 492.5345 492.6551 492.7757 492.8962 493.0168 493.1373 493.2578 493.3783 493.4988 493.6192 493.7397 493.8601 493.9805 494.1009 494.2212 494.3416 494.4619 494.5823 494.7026 494.8229 494.9431 495.0634 495.1836 495.3038 495.4241 495.5442 495.6644 495.7846 495.9047 496.0248 496.1449 496.2650 496.3851 496.5051 496.6252 496.7452 496.8652 496.9852 497.1051 497.2251 497.3450 497.4649 497.5848 497.7047 497.8246 497.9444 498.0643 498.1841 498.3039 498.4237 498.5434 498.6632 498.7829 498.9026 499.0223 499.1420 499.2617 499.3813 499.5009 499.6205 499.7401 499.8597 499.9793 500.0988 500.2183 500.3379 500.4574 500.5768 500.6963 500.8157 500.9352 501.0546 501.1739 501.2933 501.4127 501.5320 501.6513 501.7706 501.8899 502.0092 502.1285 502.2477 502.3669 502.4861 502.6053 502.7245 502.8436 502.9627 503.0819 503.2010 503.3200 503.4391 503.5582 503.6772 503.7962 503.9152 504.0342 504.1531 504.2721 504.3910 504.5099 504.6288 504.7477 504.8665 504.9854 505.1042 505.2230 505.3418 505.4606 505.5793 505.6981 505.8168 505.9355 506.0542 506.1729 506.2915 506.4101 506.5288 506.6474 506.7660 506.8845 507.0031 507.1216 507.2401 507.3586 507.4771 507.5956 507.7140 507.8324 507.9508 508.0692 508.1876 508.3060 508.4243 508.5426 508.6609 508.7792 508.8975 509.0157 509.1340 509.2522 509.3704 509.4886 509.6068 509.7249 509.8430 509.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240818T143852.6Z 8996.610332 1806 1 53.90 2 40.71 126.92 155.09 318.49 0.00 1 0.00 1 0 15 3.383e-03 3.350e-03 8.834e-04 8.815e-04 4.746898e+03 5.428889e+01 3.329757e+02 -6.000000e+00 1.838378e+02 288.74 -2.00 20.00 -2.00 505.26 0.00e+00 4.818706e-04 2.419367e-05 3.509088e-05 -6.000000e+00 9.456483e-05 288.74 -2.00 20.00 -2.00 500.41 0.00e+00 2.742015e-02 1.706289e-02 3.003594e-02 -6.000000e+00 6.559436e-02 231.55 -2.00 3.54 -2.00 502.00 0.00e+00 1.318 0.000 489.00 513.00 1 7.1825e+00 1.3068e-03 3.2831e-03 -6.0000e+00 5.0266e-03 6.6047e-03 3.4089e-04 7.3634e-04 -6.0000e+00 1.3189e-03 1.2154e-03 7.0679e-04 7.3057e-05 3.7636e-05 -6.0000e+00 2.9059e-04 -2.8939e-03 -1.1520e-04 10 0 0 10 0 0 99.83 26.38 1.33 -0.00289 0.00201 15 2 1 4 0 3592.980 35.00 20.00 26.38 28.56 3.5 999.09 -738 -456 -193 -45 436 221 653 544 329 0 101 -86 24 -132 -440 -267 110 144 16 14 47 161 434 89 477 -36 148 499 -226 -62 -534 -90 -65 213 -37 61 339 26 32 -388 66 21 199 -132 250 186 7 199 30 -161 -220 -692 -551 -692 -525 -310 -273 134 -45 480 40 185 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-175 SQ 20240818T144020.6Z 8996.611349 1808 1 53.70 2 40.50 127.35 155.26 319.15 0.00 1 0.00 1 0 15 3.535e-03 3.493e-03 9.453e-04 9.428e-04 5.154586e+03 5.875603e+01 3.660493e+02 -6.000000e+00 1.921246e+02 288.74 -2.00 20.00 -2.00 505.26 0.00e+00 4.874152e-04 2.577623e-05 3.604505e-05 -6.000000e+00 9.882544e-05 288.74 -2.00 20.00 -2.00 500.37 0.00e+00 2.957636e-03 1.830852e-02 3.107429e-02 -6.000000e+00 6.854772e-02 231.55 -2.00 3.54 -2.00 501.97 0.00e+00 1.314 0.000 489.00 513.00 1 7.3075e+00 1.4015e-03 3.3681e-03 -6.0000e+00 5.2530e-03 8.1990e-03 3.6509e-04 7.7848e-04 -6.0000e+00 1.3783e-03 1.0742e-03 5.3042e-04 7.8135e-05 4.2528e-05 -6.0000e+00 3.0368e-04 -2.7564e-03 -1.1337e-04 10 0 0 10 0 0 99.81 26.39 1.25 -0.00276 0.00092 15 2 1 4 0 3579.740 35.00 20.00 26.39 28.55 3.5 999.18 -611 -397 -205 262 475 266 616 479 435 -228 71 -52 -46 -261 -424 -256 170 -6 -114 16 56 201 495 -24 561 201 217 383 -62 -63 -521 -79 -84 298 -56 119 218 163 165 -523 18 -81 183 -163 199 242 46 186 -29 -262 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145 -35 -297 -153 -302 315 53 212 -98 242 111 385 148 -366 -12 -604 -596 -235 SQ 20240818T151143.9Z 8996.633147 2110 1 15.19 2 36.22 137.61 158.16 335.04 0.00 1 0.00 1 0 22 3.562e-03 3.538e-03 1.688e-03 1.684e-03 4.211525e+03 1.026666e+02 3.087177e+02 -6.000000e+00 1.935534e+02 288.73 -2.00 20.00 -2.00 505.26 0.00e+00 5.877051e-04 4.620508e-05 3.987886e-05 -6.000000e+00 9.956038e-05 288.73 -2.00 20.00 -2.00 500.42 0.00e+00 2.471412e-03 3.261543e-02 2.474678e-02 -6.000000e+00 6.906092e-02 231.55 -2.00 3.54 -2.00 502.01 0.00e+00 1.239 0.000 489.00 513.00 1 6.9616e+00 2.4980e-03 2.9291e-03 -6.0000e+00 5.2922e-03 4.6671e-03 6.5137e-04 6.3119e-04 -6.0000e+00 1.3887e-03 1.5350e-03 7.3609e-04 1.3954e-04 3.6815e-05 -6.0000e+00 3.0595e-04 1.2935e-02 -2.1258e-04 12 1 1 12 1 1 97.94 26.46 1.26 0.01294 0.01804 3 1 1 4 0 3795.450 35.25 20.00 26.46 29.52 3.5 1004.71 -945 14 -172 698 391 233 569 622 538 -260 206 -13 50 -385 -486 -309 73 107 -251 269 65 280 337 -148 423 224 309 173 -60 -232 -514 -135 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