File name: Pandora26s1_CambridgeMA_20241101_L2Fit_fout2c7d20230915p1-8.txt File generation date: 20241114T202303.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v7d20230915.txt Level 1 file used: Pandora26s1_CambridgeMA_20241101_L1_smca1c7d20230915p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20241101 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 5 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.1176 305.2583 305.3991 305.5398 305.6805 305.8212 305.9619 306.1026 306.2432 306.3839 306.5245 306.6651 306.8057 306.9464 307.0869 307.2275 307.3681 307.5087 307.6492 307.7897 307.9303 308.0708 308.2113 308.3518 308.4923 308.6327 308.7732 308.9136 309.0541 309.1945 309.3349 309.4753 309.6157 309.7561 309.8964 310.0368 310.1771 310.3175 310.4578 310.5981 310.7384 310.8787 311.0189 311.1592 311.2995 311.4397 311.5799 311.7201 311.8604 312.0005 312.1407 312.2809 312.4211 312.5612 312.7013 312.8415 312.9816 313.1217 313.2618 313.4019 313.5419 313.6820 313.8220 313.9621 314.1021 314.2421 314.3821 314.5221 314.6621 314.8020 314.9420 315.0819 315.2219 315.3618 315.5017 315.6416 315.7815 315.9213 316.0612 316.2010 316.3409 316.4807 316.6205 316.7603 316.9001 317.0399 317.1797 317.3194 317.4592 317.5989 317.7386 317.8783 318.0180 318.1577 318.2974 318.4371 318.5767 318.7164 318.8560 318.9956 319.1352 319.2748 319.4144 319.5540 319.6935 319.8331 319.9726 320.1122 320.2517 320.3912 320.5307 320.6702 320.8096 320.9491 321.0885 321.2280 321.3674 321.5068 321.6462 321.7856 321.9250 322.0643 322.2037 322.3430 322.4823 322.6217 322.7610 322.9003 323.0395 323.1788 323.3181 323.4573 323.5965 323.7358 323.8750 324.0142 324.1534 324.2926 324.4317 324.5709 324.7100 324.8491 324.9883 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241101T122402.4Z 9071.516694 28 1 54.93 2 79.89 120.75 82.08 123.30 0.00 1 0.00 1 0 25 4.833e-01 2.848e-02 2.168e-01 5.668e-03 5.804107e-01 3.138965e-03 6.715335e-03 -6.000000e+00 2.895906e-01 224.08 -2.00 3.54 -2.00 320.94 0.00e+00 5.137468e-03 1.351584e-03 1.295808e-03 -6.000000e+00 1.507215e-02 280.64 -2.00 20.00 -2.00 320.35 0.00e+00 5.455 0.003 302.00 328.00 3 3.2375e+00 1.0024e-02 6.1787e-02 -6.0000e+00 7.2008e-01 2.4846e-01 1.2956e-02 3.0814e-02 -6.0000e+00 7.8909e-01 -4.0346e-01 1.1876e-02 1.6938e-02 -6.0000e+00 4.6657e-01 1.7737e-01 5.7775e-03 6.8355e-03 -6.0000e+00 1.9770e-01 5.2861e-05 -1.0225e-03 1.8398e-04 9.5370e-05 -6.0000e+00 1.5427e-02 4.5579e-03 0.0000e+00 12 8 8 10 0 0 99.99 25.88 0.43 0.00456 -0.00313 38 4 1 5 0 1445.450 34.75 20.00 25.88 26.23 4.2 999.90 900000 900000 900000 -20630 -85464 -199658 -128479 900000 900000 7875 900000 900000 113570 156971 900000 156066 900000 141187 900000 6073 38061 -26748 63169 231602 -18832 14161 -22083 -27650 129741 -40156 38865 75632 -31064 90331 -19106 137406 684 -18192 41511 -19383 -37940 45005 33431 32431 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1019 -1798 1516 -4672 -1727 -989 -1110 456 -678 1217 -1448 -59 -2383 1253 -2099 -2766 -1126 -1896 -239 4797 2592 -1339 -257 1211 393 762 -1727 586 -1497 -337 1106 2154 -2544 2806 3469 -355 410 -317 1247 -108 2107 2903 -2369 -1525 1011 4076 85 -1867 -1182 28 1486 -1495 -3085 -457 SS 20241101T122527.0Z 9071.517673 30 1 53.94 2 79.66 121.01 81.87 123.55 0.00 1 0.00 1 0 25 4.659e-01 2.796e-02 1.581e-01 5.322e-03 5.667175e-01 2.983551e-03 6.548791e-03 -6.000000e+00 2.795168e-01 224.08 -2.00 3.54 -2.00 320.92 0.00e+00 7.208754e-03 1.285920e-03 6.301656e-04 -6.000000e+00 1.473444e-02 280.64 -2.00 20.00 -2.00 320.34 0.00e+00 5.348 0.003 302.00 328.00 3 3.2996e+00 9.5184e-03 6.0570e-02 -6.0000e+00 6.9562e-01 2.0640e-01 1.2296e-02 3.0592e-02 -6.0000e+00 7.6284e-01 -3.7464e-01 1.1352e-02 1.6644e-02 -6.0000e+00 4.5151e-01 1.6973e-01 5.5281e-03 8.7253e-03 -6.0000e+00 1.9144e-01 5.6221e-05 -8.0587e-04 1.7519e-04 1.0502e-04 -6.0000e+00 1.4945e-02 2.4939e-03 0.0000e+00 12 8 8 10 0 0 99.98 25.89 0.66 0.00249 -0.00356 35 4 1 5 0 1541.040 34.75 20.00 25.89 26.32 4.2 1000.56 900000 900000 900000 -16129 -95420 -199225 -124091 900000 900000 -55305 900000 900000 74885 900000 900000 77688 900000 277696 900000 900000 47265 -20082 900000 107047 -20019 34659 -15403 -2505 138379 -28291 37166 131410 -23681 63395 -49878 149080 2945 -2031 21235 -19641 -38211 55436 30515 38650 85 71671 4983 22999 11107 -122 -6567 75171 53422 35784 17101 15117 -8169 17347 11997 11836 4601 8051 675 89 35822 -3985 942 -4758 -6220 15543 3406 1979 13419 -4337 -2007 -3103 3551 -1174 -4578 3333 -7882 -262 -6041 -8724 -700 -1585 -1980 4913 3168 1322 -1410 1471 -5917 -1780 -389 -1915 439 577 612 -905 -1105 -2042 1264 -2317 -2646 -2526 -1049 -913 3947 1669 -735 -416 869 210 763 -1218 189 -641 -527 -582 1303 -955 1437 2215 160 1213 534 1207 167 705 1920 -998 -495 507 1051 179 -842 -232 502 415 -984 -1356 -587 900000 900000 900000 -167 -2021 -11626 -3562 900000 900000 -937 900000 900000 529 900000 900000 1005 900000 1438 900000 900000 1052 -873 900000 1385 -953 969 -702 -99 1361 -1626 1289 2041 -1900 2166 -5164 2161 204 -173 1693 -2684 -6864 4133 3033 3621 12 5009 691 2738 1552 -20 -1282 7082 6748 5724 3426 3162 -2170 3520 2528 2524 1120 2096 211 30 8679 -1407 315 -1761 -2586 5809 1545 932 5502 -1994 -824 -1177 1210 -437 -1988 1560 -4310 -148 -3923 -6204 -491 -1190 -1560 3686 2393 973 -998 954 -4043 -1226 -296 -1701 436 640 715 -1056 -1207 -2066 1181 -2306 -2815 -2847 -1240 -1065 4814 2299 -1119 -652 1328 309 1062 -1686 263 -944 -819 -932 2034 -1482 2109 3108 220 1598 703 1675 261 1205 3506 -1830 -949 1019 2231 398 -1944 -539 1142 908 -2070 -2736 -1165 SS 20241101T125429.7Z 9071.537844 42 1 3.08 2 75.21 126.58 77.73 128.97 0.00 1 0.00 1 0 17 2.008e-01 1.722e-02 1.381e-01 1.235e-02 4.267752e-01 6.347907e-03 5.016618e-03 -6.000000e+00 1.183653e-01 224.08 -2.00 3.54 -2.00 319.20 0.00e+00 3.081663e-04 1.640317e-03 8.555909e-04 -6.000000e+00 5.323499e-03 280.64 -2.00 20.00 -2.00 318.52 0.00e+00 3.839 0.001 302.00 328.00 3 3.4569e+00 1.7647e-02 4.3767e-02 -6.0000e+00 2.9138e-01 2.9606e-02 2.0550e-02 2.2213e-02 -6.0000e+00 3.1735e-01 -5.1292e-02 1.5077e-02 1.0946e-02 -6.0000e+00 1.8943e-01 2.1905e-02 7.8118e-03 3.0797e-03 -6.0000e+00 7.9224e-02 2.3690e-04 3.9460e-04 3.8959e-04 4.0294e-05 -6.0000e+00 6.2684e-03 -7.6167e-03 0.0000e+00 12 9 9 12 1 1 999.00 26.03 0.28 -0.00762 -0.00465 1 4 1 5 0 1534.810 34.75 20.00 26.03 26.81 4.1 1002.15 -51523 -30106 -35673 -68864 2411 -73469 -48820 -57718 148562 -30399 -19542 195 -22825 -16959 -8752 -4180 26791 1098 40424 9831 56664 -20421 15723 24146 -3477 -9221 -4609 -11117 20211 -6467 -1506 32180 -9555 1619 -15852 -1399 -4074 -5400 2698 -5684 -3635 4352 2501 3499 -220 5057 -5488 6503 4918 1913 -5475 9147 2777 11555 1943 1918 -2337 -2032 5460 3059 -1217 686 -861 1314 9400 -1585 -489 469 -1736 2825 788 -1299 7161 326 1939 -5411 -1498 -3107 -2846 1614 -1979 -1622 -2823 -3912 -1263 250 -290 -749 398 -515 132 2613 -1859 -1733 268 -203 1611 -893 1452 -2287 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