File name: Pandora26s1_CambridgeMA_20241104_L2Fit_fwvt1c10d20240425p1-8.txt File generation date: 20241218T001555.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v10d20240425.txt Level 1 file used: Pandora26s1_CambridgeMA_20241104_L1_smca1c10d20240425p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20241104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1619 1769 Nominal wavelengths inside fitting window [nm]: 492.0365 492.1571 492.2778 492.3984 492.5190 492.6396 492.7601 492.8807 493.0012 493.1217 493.2422 493.3627 493.4832 493.6036 493.7241 493.8445 493.9649 494.0853 494.2056 494.3260 494.4463 494.5666 494.6869 494.8072 494.9275 495.0477 495.1679 495.2881 495.4083 495.5285 495.6487 495.7688 495.8890 496.0091 496.1292 496.2492 496.3693 496.4893 496.6094 496.7294 496.8494 496.9693 497.0893 497.2092 497.3292 497.4491 497.5690 497.6888 497.8087 497.9285 498.0483 498.1682 498.2879 498.4077 498.5275 498.6472 498.7669 498.8866 499.0063 499.1260 499.2456 499.3653 499.4849 499.6045 499.7241 499.8436 499.9632 500.0827 500.2022 500.3217 500.4412 500.5607 500.6801 500.7995 500.9189 501.0383 501.1577 501.2771 501.3964 501.5157 501.6351 501.7543 501.8736 501.9929 502.1121 502.2313 502.3505 502.4697 502.5889 502.7081 502.8272 502.9463 503.0654 503.1845 503.3036 503.4226 503.5417 503.6607 503.7797 503.8987 504.0176 504.1366 504.2555 504.3744 504.4933 504.6122 504.7311 504.8499 504.9687 505.0875 505.2063 505.3251 505.4439 505.5626 505.6813 505.8000 505.9187 506.0374 506.1561 506.2747 506.3933 506.5119 506.6305 506.7491 506.8676 506.9862 507.1047 507.2232 507.3417 507.4601 507.5786 507.6970 507.8154 507.9338 508.0522 508.1705 508.2889 508.4072 508.5255 508.6438 508.7621 508.8803 508.9986 509.1168 509.2350 509.3532 509.4714 509.5895 509.7076 509.8258 509.9439 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241104T112816.7Z 9074.477971 8 1 53.74 2 89.80 111.55 122.04 100.17 0.00 1 0.00 1 0 15 1.247e-02 1.224e-02 8.389e-04 8.311e-04 1.284638e+04 5.364753e+01 8.520371e+02 -6.000000e+00 6.548749e+02 280.27 -2.00 20.00 -2.00 505.47 0.00e+00 8.215556e-03 2.261045e-05 4.514287e-04 -6.000000e+00 3.414076e-04 280.27 -2.00 20.00 -2.00 501.34 0.00e+00 4.594232e-01 1.548540e-02 1.167905e-01 -6.000000e+00 2.407193e-01 223.81 -2.00 3.54 -2.00 502.77 0.00e+00 20.259 0.158 489.00 513.00 1 5.0381e+00 1.1796e-03 3.9371e-02 -6.0000e+00 1.8401e-02 -5.4773e-02 3.0057e-04 3.1145e-03 -6.0000e+00 4.8371e-03 6.1235e-04 -4.6799e-04 6.7193e-05 1.6881e-04 -6.0000e+00 1.0706e-03 7.4690e-03 -1.2454e-04 12 9 8 11 32 0 -21.58 23.21 7.56 0.00747 0.00422 25 3 1 4 0 2149.380 33.00 19.54 23.21 9.33 4.9 919.02 -2994 -2910 -1749 -164 1031 1347 2138 2147 2187 1402 745 337 -369 -1082 -1298 -1241 -749 -286 447 788 910 835 867 772 1164 1008 1150 1024 45 -1034 -1901 -1863 -1509 -298 536 902 929 446 266 -630 -148 -142 430 607 1317 1478 1249 979 610 312 -938 -2108 -2379 -2903 -1741 -847 220 1118 714 980 750 1152 967 1098 1261 771 227 350 -732 -857 -1746 -1294 -1214 -474 -144 -280 -662 -1144 -1311 -1823 -1619 -1341 -1506 -1083 -1083 -677 -417 -642 -1114 -794 -616 350 815 1288 1782 1032 745 300 -513 -2331 -2613 -2790 -2125 -854 -129 348 683 -799 -912 -1328 -691 181 595 1204 1525 1751 2254 2298 2264 1218 993 316 368 400 673 1060 1224 1109 1118 928 749 8 -194 -797 -1223 -1630 -903 -275 589 463 683 537 686 563 831 804 400 -617 -1516 -2299 -2213 -2496 -2453 -1511 -146 902 1202 1936 1975 2014 1284 675 303 -330 -957 -1143 -1097 -667 -259 414 711 823 758 789 708 1078 946 1082 963 42 -938 -1765 -1664 -1363 -275 515 849 905 433 256 -610 -144 -135 413 594 1305 1484 1262 987 611 308 -913 -2023 -2259 -2781 -1693 -849 217 1119 724 991 761 1177 1001 1142 1309 796 232 353 -739 -856 -1736 -1282 -1216 -477 -147 -287 -673 -1145 -1298 -1800 -1591 -1324 -1504 -1082 -1093 -691 -427 -653 -1129 -799 -622 355 812 1300 1776 1048 737 289 -485 -2193 -2523 -2609 -2026 -842 -128 353 696 -820 -926 -1357 -718 192 617 1257 1605 1852 2400 2495 2490 1302 1084 340 390 423 720 1143 1328 1174 1185 987 802 8 -210 -862 -1325 -1718 -966 -301 649 517 749 595 764 633 935 904 447 -683 -1655 -2581 -2417 SQ 20241104T114038.7Z 9074.486559 10 1 54.28 2 87.69 113.66 119.90 101.95 0.00 1 0.00 1 0 22 4.808e-03 4.756e-03 1.162e-04 1.160e-04 9.209096e+03 7.280233e+00 6.328404e+02 -6.000000e+00 2.525619e+02 280.27 -2.00 20.00 -2.00 505.37 0.00e+00 3.523789e-03 3.132020e-06 1.986472e-04 -6.000000e+00 1.316772e-04 280.27 -2.00 20.00 -2.00 500.89 0.00e+00 9.995440e-01 2.193955e-03 7.089064e-02 -6.000000e+00 9.287747e-02 223.81 -2.00 3.54 -2.00 502.41 0.00e+00 15.261 0.067 489.00 513.00 1 1.9884e+00 1.6727e-04 2.4939e-02 -6.0000e+00 7.0990e-03 -2.4031e-02 4.3085e-05 2.0658e-03 -6.0000e+00 1.8673e-03 2.6939e-02 -2.3934e-04 9.4861e-06 1.0165e-04 -6.0000e+00 4.1291e-04 6.4382e-03 -1.5847e-04 12 8 8 10 0 0 97.54 23.22 1.87 0.00644 0.00478 621 65 1 4 0 87.390 33.00 19.48 23.22 9.45 4.9 919.44 -1040 -921 -397 28 416 703 812 919 806 580 426 195 -110 -347 -502 -469 -298 -10 154 222 312 242 210 330 373 442 579 501 -13 -319 -603 -638 -463 -8 152 320 308 31 -161 -283 -216 -192 40 225 413 440 461 375 226 -125 -492 -909 -1184 -1044 -748 -344 -67 210 197 267 242 346 466 537 491 328 160 30 -190 -439 -537 -485 -339 -97 0 -65 -145 -306 -581 -742 -740 -627 -586 -475 -434 -329 -252 -347 -407 -342 -219 69 380 491 605 540 355 142 -363 -846 -1089 -998 -792 -406 -149 44 34 -242 -379 -394 -274 -87 186 396 551 755 912 994 832 693 446 223 161 263 196 331 393 357 387 487 323 141 24 -240 -463 -403 -341 -141 143 234 225 296 301 338 398 344 114 -276 -631 -869 -857 -945 -831 -362 27 396 672 794 899 792 565 415 188 -105 -331 -476 -446 -282 -10 151 219 309 240 209 324 370 442 578 499 -13 -311 -574 -608 -446 -8 151 320 311 31 -160 -278 -216 -190 40 226 421 447 469 379 229 -125 -484 -884 -1151 -1013 -730 -343 -68 214 202 273 246 354 475 550 501 332 161 30 -191 -435 -525 -474 -335 -97 0 -65 -144 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6.1585e-03 -1.6368e-04 12 9 9 12 1 1 98.33 23.22 1.77 0.00616 0.00512 636 83 1 4 0 68.360 33.00 20.57 23.22 9.51 4.9 919.54 -1046 -916 -413 28 427 704 812 879 796 567 410 182 -110 -328 -479 -423 -268 -9 128 214 298 230 190 326 338 438 562 496 -25 -313 -629 -673 -489 -24 152 331 338 75 -116 -244 -232 -192 41 200 404 435 447 354 212 -103 -474 -918 -1151 -1038 -731 -354 -68 217 192 273 261 361 454 539 500 329 164 39 -201 -442 -538 -504 -351 -78 -4 -84 -157 -267 -542 -717 -714 -626 -596 -493 -408 -293 -243 -325 -385 -326 -190 46 388 465 589 521 321 128 -344 -832 -1036 -978 -771 -388 -151 36 33 -228 -349 -395 -284 -95 166 394 547 783 903 940 793 669 420 215 154 240 235 325 391 348 334 490 315 132 33 -261 -442 -382 -337 -135 143 253 227 271 300 339 393 352 91 -268 -606 -863 -830 -941 -830 -380 27 409 677 786 864 785 555 395 176 -105 -314 -456 -404 -255 -9 126 212 296 226 187 321 336 440 563 496 -24 -302 -601 -643 -473 -24 151 333 341 75 -115 -241 -229 -191 41 201 413 443 455 358 215 -103 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