File name: Pandora26s1_CambridgeMA_20241105_L2Fit_fout2c10d20240425p1-8.txt File generation date: 20241218T001627.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v10d20240425.txt Level 1 file used: Pandora26s1_CambridgeMA_20241105_L1_smca1c10d20240425p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20241105 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0963 305.2371 305.3779 305.5186 305.6594 305.8002 305.9409 306.0816 306.2224 306.3631 306.5038 306.6445 306.7851 306.9258 307.0664 307.2071 307.3477 307.4883 307.6289 307.7695 307.9101 308.0507 308.1912 308.3318 308.4723 308.6129 308.7534 308.8939 309.0344 309.1748 309.3153 309.4558 309.5962 309.7366 309.8771 310.0175 310.1579 310.2982 310.4386 310.5790 310.7193 310.8597 311.0000 311.1403 311.2806 311.4209 311.5612 311.7015 311.8417 311.9820 312.1222 312.2624 312.4026 312.5428 312.6830 312.8232 312.9634 313.1035 313.2437 313.3838 313.5239 313.6640 313.8041 313.9442 314.0843 314.2243 314.3644 314.5044 314.6444 314.7844 314.9244 315.0644 315.2044 315.3444 315.4843 315.6243 315.7642 315.9041 316.0440 316.1839 316.3238 316.4637 316.6035 316.7434 316.8832 317.0230 317.1628 317.3026 317.4424 317.5822 317.7220 317.8617 318.0015 318.1412 318.2809 318.4206 318.5603 318.7000 318.8397 318.9793 319.1190 319.2586 319.3982 319.5378 319.6774 319.8170 319.9566 320.0962 320.2357 320.3753 320.5148 320.6543 320.7938 320.9333 321.0728 321.2123 321.3517 321.4912 321.6306 321.7700 321.9094 322.0488 322.1882 322.3276 322.4669 322.6063 322.7456 322.8849 323.0243 323.1636 323.3028 323.4421 323.5814 323.7206 323.8599 323.9991 324.1383 324.2775 324.4167 324.5559 324.6951 324.8342 324.9734 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241105T131019.9Z 9075.548842 44 1 54.26 2 73.92 130.51 114.54 107.86 0.00 1 0.00 1 0 17 1.563e-01 1.513e-02 3.751e-02 2.930e-03 4.005148e-01 1.505074e-03 4.693119e-03 -6.000000e+00 9.186520e-02 223.72 -2.00 3.54 -2.00 319.22 0.00e+00 3.920937e-04 3.879096e-04 1.727501e-04 -6.000000e+00 4.133625e-03 280.14 -2.00 20.00 -2.00 318.54 0.00e+00 3.550 0.001 302.00 328.00 3 4.3718e+00 4.1804e-03 4.0549e-02 -6.0000e+00 2.2599e-01 4.8073e-02 4.8745e-03 2.0571e-02 -6.0000e+00 2.4635e-01 -4.5122e-02 3.6116e-03 1.0167e-02 -6.0000e+00 1.4704e-01 1.5176e-02 1.8789e-03 2.9437e-03 -6.0000e+00 6.1402e-02 1.2731e-04 -2.6157e-04 9.3742e-05 3.7300e-05 -6.0000e+00 4.8786e-03 1.2609e-02 -2.0787e-04 12 8 8 10 0 0 99.94 25.13 0.12 0.01261 0.01064 64 7 1 5 0 847.640 34.25 20.01 25.13 21.99 4.3 981.36 5735 -4780 99347 1038 -38176 -73254 -60907 17133 49691 2149 19649 21565 -8462 -646 29220 15723 7356 18380 44900 43102 -3069 -17352 30840 5301 -599 3558 -7329 -9854 11333 -11229 -3398 8376 -19863 -890 -21363 14178 -2647 -3801 1654 -6187 -13727 3538 3207 2313 -2280 10487 -622 133 -532 -3139 -3882 9794 8350 6812 1001 4255 -1724 3772 2326 2352 -1322 1470 -225 -29 7388 -2705 -110 -2669 -2559 3913 1973 296 3439 196 -1436 -1750 482 -1165 -1767 363 -2189 -3112 -2381 -3023 -462 -875 -690 1233 1836 840 -1109 1110 -1354 -1144 781 125 53 301 987 -288 -446 -1416 57 34 -1018 -372 -948 -601 1382 1156 209 -323 192 -541 166 -198 691 -139 -24 -462 194 -522 760 309 129 334 80 1599 258 265 629 -680 -576 258 814 -97 -273 183 135 291 -577 -694 -454 146 -146 1079 28 -1462 -4019 -3219 465 1065 78 629 752 -467 -39 1511 1033 565 1344 2643 2672 -307 -2038 2344 556 -71 413 -934 -1239 1133 -1473 -455 1108 -3751 -141 -4059 1953 -485 -835 409 -1895 -4496 1129 1057 778 -808 3278 -217 46 -189 -1091 -1466 3490 3234 2835 459 1943 -846 1737 1072 1093 -670 788 -134 -18 4270 -1653 -64 -1631 -1713 2734 1511 217 2621 146 -1000 -1111 282 -699 -1167 267 -1710 -2708 -2207 -2997 -477 -964 -732 1308 1911 911 -1141 1037 -1241 -1071 781 142 62 386 1307 -377 -546 -1623 62 39 -1245 -477 -1292 -866 1947 1760 339 -533 305 -816 233 -290 1016 -200 -36 -737 309 -819 1142 447 192 477 112 2302 379 421 1054 -1203 -985 461 1529 -191 -554 374 275 571 -1095 -1272 -826 SS 20241105T132324.4Z 9075.557922 49 1 54.29 2 72.13 133.21 112.35 109.67 0.00 1 0.00 1 0 25 2.923e-02 5.587e-03 4.705e-03 8.643e-04 3.640866e-01 4.439785e-04 4.325746e-03 -6.000000e+00 1.719432e-02 223.72 -2.00 3.54 -2.00 318.18 0.00e+00 8.307763e-04 8.455919e-05 1.498492e-04 -6.000000e+00 7.732879e-04 280.14 -2.00 20.00 -2.00 317.49 0.00e+00 3.214 0.001 302.00 328.00 3 2.6786e+00 1.1870e-03 3.6711e-02 -6.0000e+00 4.2299e-02 1.8729e-02 1.3495e-03 1.8586e-02 -6.0000e+00 4.6098e-02 -1.3251e-02 8.7704e-04 9.1755e-03 -6.0000e+00 2.7515e-02 -1.0517e-03 4.4929e-04 2.7207e-03 -6.0000e+00 1.1497e-02 1.0051e-03 2.2960e-04 2.7288e-05 3.3670e-05 -6.0000e+00 9.1241e-04 1.0952e-02 -8.8095e-05 10 0 0 10 0 0 100.00 25.20 0.27 0.01095 0.01268 366 38 1 5 0 148.320 34.25 20.01 25.20 22.32 4.3 983.05 -9877 -7761 -4068 -11449 -12218 -16016 -14389 -211 -544 -4649 -4983 -3580 -4285 -3217 59 -984 528 1083 4454 3788 661 -1753 2404 504 -35 -192 -2543 -2569 477 -882 285 1782 -3517 -2150 -4578 -527 -2010 -681 -446 -1512 -2191 -144 123 -327 7 1153 -71 -285 352 196 649 1823 1679 1405 974 1310 460 356 980 1280 908 1576 991 771 841 -423 286 -3 884 779 -2 144 368 50 -279 -111 -80 -579 -658 -669 -1290 -1547 -1790 -1559 -798 -647 -111 106 366 105 200 357 -14 227 337 80 271 152 -198 -589 -543 -625 -89 66 -504 -830 -433 -438 256 431 246 43 214 105 266 308 559 175 111 -174 -143 -36 298 56 362 558 268 981 612 194 246 -226 -110 109 192 -29 -151 24 -194 -204 -191 -530 -231 -549 -457 -232 -666 -674 -921 -883 -13 -35 -331 -372 -290 -407 -355 7 -135 77 166 691 612 112 -309 425 88 -6 -37 -487 -473 92 -162 57 387 -864 -526 -1124 -128 -556 -220 -156 -611 -972 -66 58 -156 3 546 -34 -136 169 98 321 960 945 837 605 832 277 213 620 815 566 1059 728 557 645 -313 202 -2 649 637 -2 123 329 43 -220 -85 -57 -418 -517 -557 -1139 -1508 -1762 -1627 -884 -718 -129 124 424 117 218 359 -14 234 355 89 338 197 -268 -779 -671 -758 -104 80 -622 -1086 -595 -604 375 646 387 65 328 152 376 420 770 254 164 -268 -220 -54 436 82 509 750 372 1331 899 294 393 -359 -180 188 334 -53 -271 44 -351 -374 -336 -904 -391 SS 20241105T132456.8Z 9075.558991 51 1 54.40 2 71.92 133.53 112.10 109.88 0.00 1 0.00 1 0 17 3.200e-02 6.057e-03 6.005e-03 1.089e-03 3.609869e-01 5.586100e-04 4.280436e-03 -6.000000e+00 1.882297e-02 223.72 -2.00 3.54 -2.00 318.23 0.00e+00 4.002077e-04 1.073825e-04 1.244464e-04 -6.000000e+00 8.465591e-04 280.14 -2.00 20.00 -2.00 317.53 0.00e+00 3.180 0.001 302.00 328.00 3 3.1457e+00 1.4965e-03 3.6325e-02 -6.0000e+00 4.6306e-02 1.9949e-02 1.7049e-03 1.8396e-02 -6.0000e+00 5.0465e-02 -1.3132e-02 1.1091e-03 9.0827e-03 -6.0000e+00 3.0121e-02 -1.1034e-03 5.6673e-04 2.6124e-03 -6.0000e+00 1.2586e-02 6.5390e-04 1.3628e-04 3.4468e-05 3.2623e-05 -6.0000e+00 9.9887e-04 1.0806e-02 -1.0101e-04 10 0 0 10 0 0 100.00 25.20 0.16 0.01081 0.01183 226 24 1 5 0 240.680 34.25 19.99 25.20 22.37 4.3 983.55 -5343 -4059 -1030 -10319 -13222 -21761 -16905 -1276 -1080 -4055 -2961 -1955 -1830 -2133 589 1264 1383 2179 6371 6352 -412 -1885 5212 1217 611 -198 -3007 -2719 1650 -1261 600 1889 -5290 -2616 -4561 -65 -2172 -1154 -488 -1792 -2889 -194 299 -344 -541 1141 -286 -354 -239 -515 120 1882 1857 1595 1041 1205 105 657 1267 853 699 1764 570 649 1380 -795 365 -433 478 1025 156 187 326 105 -197 -354 32 -545 -246 -498 -962 -1667 -1990 -1550 -695 -535 -180 275 486 281 337 673 337 242 339 245 332 298 2 -622 -440 -819 -313 -98 -403 -889 -632 -541 368 420 55 -186 13 133 235 257 656 296 133 -193 -220 -64 293 197 269 418 253 1119 533 219 100 -211 -77 77 214 16 -233 76 -143 29 -165 -504 -305 -282 -228 -57 -587 -729 -1313 -1056 -76 -70 -286 -215 -155 -168 -230 71 167 196 324 950 980 -69 -327 879 228 121 -37 -570 -542 308 -251 128 399 -1288 -626 -1089 -15 -585 -364 -182 -708 -1257 -87 136 -160 -253 524 -132 -164 -111 -251 63 1036 1008 916 624 740 66 408 772 526 454 1229 405 484 1013 -567 249 -303 363 860 132 164 280 86 -160 -261 22 -377 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