File name: Pandora26s1_CambridgeMA_20241105_L2Fit_fout2c7d20230915p1-8.txt File generation date: 20241114T202842.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora26_OF_v2d20230725.txt Instrument calibration file used: Pandora26s1_CF_v7d20230915.txt Level 1 file used: Pandora26s1_CambridgeMA_20241105_L1_smca1c7d20230915p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20241105 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 5 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.1176 305.2583 305.3991 305.5398 305.6805 305.8212 305.9619 306.1026 306.2432 306.3839 306.5245 306.6651 306.8057 306.9464 307.0869 307.2275 307.3681 307.5087 307.6492 307.7897 307.9303 308.0708 308.2113 308.3518 308.4923 308.6327 308.7732 308.9136 309.0541 309.1945 309.3349 309.4753 309.6157 309.7561 309.8964 310.0368 310.1771 310.3175 310.4578 310.5981 310.7384 310.8787 311.0189 311.1592 311.2995 311.4397 311.5799 311.7201 311.8604 312.0005 312.1407 312.2809 312.4211 312.5612 312.7013 312.8415 312.9816 313.1217 313.2618 313.4019 313.5419 313.6820 313.8220 313.9621 314.1021 314.2421 314.3821 314.5221 314.6621 314.8020 314.9420 315.0819 315.2219 315.3618 315.5017 315.6416 315.7815 315.9213 316.0612 316.2010 316.3409 316.4807 316.6205 316.7603 316.9001 317.0399 317.1797 317.3194 317.4592 317.5989 317.7386 317.8783 318.0180 318.1577 318.2974 318.4371 318.5767 318.7164 318.8560 318.9956 319.1352 319.2748 319.4144 319.5540 319.6935 319.8331 319.9726 320.1122 320.2517 320.3912 320.5307 320.6702 320.8096 320.9491 321.0885 321.2280 321.3674 321.5068 321.6462 321.7856 321.9250 322.0643 322.2037 322.3430 322.4823 322.6217 322.7610 322.9003 323.0395 323.1788 323.3181 323.4573 323.5965 323.7358 323.8750 324.0142 324.1534 324.2926 324.4317 324.5709 324.7100 324.8491 324.9883 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241105T131019.9Z 9075.548842 44 1 54.26 2 73.92 130.51 114.54 107.86 0.00 1 0.00 1 0 17 1.535e-01 1.515e-02 3.647e-02 2.928e-03 4.004023e-01 1.506014e-03 4.676522e-03 -6.000000e+00 9.025044e-02 223.72 -2.00 3.54 -2.00 319.21 0.00e+00 3.971679e-04 3.870911e-04 1.704009e-04 -6.000000e+00 4.059617e-03 280.14 -2.00 20.00 -2.00 318.54 0.00e+00 3.550 0.001 302.00 328.00 3 4.2164e+00 4.1822e-03 4.0529e-02 -6.0000e+00 2.2202e-01 4.8808e-02 4.8747e-03 2.0526e-02 -6.0000e+00 2.4198e-01 -4.6647e-02 3.6072e-03 1.0159e-02 -6.0000e+00 1.4443e-01 1.5977e-02 1.8758e-03 2.9790e-03 -6.0000e+00 6.0353e-02 1.4875e-04 1.7051e-04 9.3699e-05 3.7360e-05 -6.0000e+00 4.7908e-03 -5.1128e-04 0.0000e+00 12 8 8 10 0 0 99.94 25.13 0.10 -0.00051 0.00077 64 7 1 5 0 847.640 34.25 20.01 25.13 21.99 4.3 981.36 4383 -5888 94843 -479 -39071 -73085 -61237 15771 47703 1178 19376 21435 -8788 -437 28743 15414 7132 18480 44401 42619 -3234 -17423 30524 5449 -696 3402 -7489 -10027 11081 -11298 -3440 8302 -19862 -1012 -21270 14271 -2608 -3699 1757 -6085 -13638 3580 3234 2330 -2261 10474 -621 134 -440 -3104 -3831 9825 8380 6838 1025 4269 -1716 3762 2317 2358 -1294 1509 -230 -10 7376 -2719 -118 -2655 -2527 3940 1992 271 3432 145 -1462 -1782 453 -1177 -1762 374 -2203 -3124 -2393 -3030 -444 -878 -693 1228 1849 827 -1125 1112 -1378 -1165 764 116 49 301 972 -303 -445 -1417 52 30 -1017 -368 -958 -594 1375 1153 212 -317 200 -521 167 -203 696 -133 -28 -446 202 -512 783 318 149 335 73 1599 245 269 624 -682 -579 254 811 -95 -278 179 135 301 -579 -691 -470 114 -183 1083 -13 -1517 -4028 -3270 437 1049 43 625 753 -489 -26 1502 1021 552 1356 2637 2665 -325 -2055 2336 573 -82 396 -958 -1266 1114 -1487 -463 1102 -3760 -160 -4045 1968 -479 -814 436 -1866 -4472 1144 1068 785 -802 3278 -216 47 -156 -1080 -1448 3504 3248 2847 470 1950 -843 1733 1069 1096 -656 809 -137 -6 4264 -1662 -68 -1622 -1692 2753 1525 199 2616 108 -1018 -1132 265 -706 -1164 276 -1722 -2719 -2218 -3005 -459 -967 -735 1303 1925 898 -1158 1039 -1263 -1090 765 131 58 386 1288 -396 -545 -1624 56 34 -1244 -473 -1306 -855 1938 1756 343 -522 318 -786 234 -297 1024 -192 -43 -712 321 -804 1176 460 222 478 102 2302 359 426 1046 -1205 -991 453 1523 -188 -565 366 274 590 -1099 -1266 -853 SS 20241105T132324.4Z 9075.557922 49 1 54.29 2 72.13 133.21 112.35 109.67 0.00 1 0.00 1 0 17 2.952e-02 5.565e-03 4.702e-03 8.644e-04 3.641390e-01 4.438805e-04 4.323188e-03 -6.000000e+00 1.736530e-02 223.72 -2.00 3.54 -2.00 318.17 0.00e+00 8.275332e-04 8.426877e-05 1.582325e-04 -6.000000e+00 7.808993e-04 280.14 -2.00 20.00 -2.00 317.48 0.00e+00 3.214 0.001 302.00 328.00 3 2.5234e+00 1.1869e-03 3.6709e-02 -6.0000e+00 4.2720e-02 1.8393e-02 1.3493e-03 1.8579e-02 -6.0000e+00 4.6554e-02 -1.3104e-02 8.7695e-04 9.1762e-03 -6.0000e+00 2.7787e-02 -1.0085e-03 4.4942e-04 2.7238e-03 -6.0000e+00 1.1616e-02 1.1739e-03 3.0622e-04 2.7312e-05 3.3658e-05 -6.0000e+00 9.2143e-04 -3.1932e-03 0.0000e+00 10 0 0 10 0 0 100.00 25.20 0.27 -0.00319 -0.00089 366 38 1 5 0 148.320 34.25 20.01 25.20 22.32 4.3 983.05 -9873 -7797 -4284 -11778 -12605 -16182 -14395 -81 -518 -4693 -5067 -3393 -4032 -3056 213 -922 544 1076 4431 3731 571 -1807 2411 567 -51 -282 -2705 -2732 399 -852 409 1842 -3540 -2245 -4646 -467 -1836 -469 -273 -1416 -2161 -136 87 -380 -37 1101 -139 -340 322 224 696 1860 1702 1420 974 1301 430 312 946 1278 938 1619 1026 762 786 -491 253 13 939 817 14 130 330 -9 -347 -172 -119 -576 -620 -631 -1257 -1524 -1778 -1543 -784 -635 -108 102 355 89 181 345 -15 230 347 87 276 159 -196 -585 -538 -621 -87 62 -507 -836 -438 -446 246 424 245 51 233 130 288 317 554 164 99 -175 -135 -22 314 79 386 579 268 956 579 166 229 -238 -127 85 168 -42 -159 23 -178 -177 -164 -511 -241 -550 -459 -245 -685 -696 -932 -885 -5 -34 -334 -378 -275 -383 -338 26 -127 79 165 687 603 97 -319 426 99 -9 -54 -518 -503 77 -157 82 400 -870 -550 -1140 -113 -507 -151 -96 -572 -958 -62 41 -181 -18 522 -66 -162 154 112 344 979 958 846 605 826 259 201 598 813 584 1088 754 551 603 -363 179 10 690 668 12 111 296 -8 -273 -131 -85 -416 -487 -525 -1110 -1485 -1750 -1610 -868 -705 -124 119 412 99 197 347 -16 238 366 97 344 205 -264 -774 -666 -753 -102 75 -626 -1092 -601 -615 361 634 386 78 359 188 408 433 763 237 145 -268 -209 -34 459 116 543 777 373 1296 850 251 366 -378 -209 147 294 -77 -285 42 -322 -324 -289 -873 -408 SS 20241105T132456.8Z 9075.558991 51 1 54.40 2 71.92 133.53 112.10 109.88 0.00 1 0.00 1 0 17 3.242e-02 6.044e-03 5.992e-03 1.089e-03 3.610276e-01 5.586768e-04 4.276870e-03 -6.000000e+00 1.907517e-02 223.72 -2.00 3.54 -2.00 318.22 0.00e+00 3.865671e-04 1.073525e-04 1.311234e-04 -6.000000e+00 8.577822e-04 280.14 -2.00 20.00 -2.00 317.53 0.00e+00 3.180 0.001 302.00 328.00 3 2.9906e+00 1.4966e-03 3.6321e-02 -6.0000e+00 4.6926e-02 1.9666e-02 1.7049e-03 1.8386e-02 -6.0000e+00 5.1138e-02 -1.3118e-02 1.1091e-03 9.0810e-03 -6.0000e+00 3.0523e-02 -9.9875e-04 5.6680e-04 2.6149e-03 -6.0000e+00 1.2760e-02 7.6377e-04 2.6019e-04 3.4489e-05 3.2587e-05 -6.0000e+00 1.0122e-03 -3.2828e-03 0.0000e+00 10 0 0 10 0 0 100.00 25.20 0.16 -0.00328 -0.00133 226 24 1 5 0 240.680 34.25 19.99 25.20 22.37 4.3 983.55 -5301 -4190 -1533 -10916 -13738 -21861 -17019 -1224 -1110 -4142 -2979 -1952 -1618 -1925 726 1317 1396 2172 6348 6299 -490 -1924 5233 1203 625 -253 -3134 -2908 1585 -1277 691 1958 -5294 -2720 -4638 -61 -2009 -944 -307 -1677 -2834 -176 269 -391 -577 1094 -336 -393 -254 -487 170 1924 1889 1612 1034 1190 73 624 1240 840 732 1812 604 633 1318 -864 338 -423 522 1067 174 178 295 49 -267 -422 -12 -539 -211 -466 -929 -1652 -1976 -1534 -678 -528 -174 269 473 261 321 660 333 248 344 250 336 299 1 -619 -440 -813 -316 -103 -404 -894 -633 -543 364 413 57 -178 29 154 255 269 656 288 121 -195 -210 -51 309 218 289 436 253 1100 502 193 84 -221 -93 55 192 4 -240 75 -129 52 -143 -488 -315 -280 -236 -85 -624 -760 -1321 -1066 -73 -73 -293 -217 -155 -149 -208 88 174 197 323 947 973 -82 -333 883 225 124 -47 -594 -580 296 -254 148 414 -1289 -651 -1108 -14 -541 -298 -114 -662 -1233 -78 123 -182 -270 503 -155 -182 -118 -237 88 1059 1025 926 620 731 46 387 756 518 475 1262 429 473 967 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