File name: Pandora26s1_CambridgeMA_20250508_L2Fit_fout2c10d20240425p1-8.txt File generation date: 20250509T045227.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Kelly Chance Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora26_OF_v3d20230725.txt Instrument calibration file used: Pandora26s1_CF_v10d20240425.txt Level 1 file used: Pandora26s1_CambridgeMA_20250508_L1_smca1c10d20240425p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20250508 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0963 305.2371 305.3779 305.5186 305.6594 305.8002 305.9409 306.0816 306.2224 306.3631 306.5038 306.6445 306.7851 306.9258 307.0664 307.2071 307.3477 307.4883 307.6289 307.7695 307.9101 308.0507 308.1912 308.3318 308.4723 308.6129 308.7534 308.8939 309.0344 309.1748 309.3153 309.4558 309.5962 309.7366 309.8771 310.0175 310.1579 310.2982 310.4386 310.5790 310.7193 310.8597 311.0000 311.1403 311.2806 311.4209 311.5612 311.7015 311.8417 311.9820 312.1222 312.2624 312.4026 312.5428 312.6830 312.8232 312.9634 313.1035 313.2437 313.3838 313.5239 313.6640 313.8041 313.9442 314.0843 314.2243 314.3644 314.5044 314.6444 314.7844 314.9244 315.0644 315.2044 315.3444 315.4843 315.6243 315.7642 315.9041 316.0440 316.1839 316.3238 316.4637 316.6035 316.7434 316.8832 317.0230 317.1628 317.3026 317.4424 317.5822 317.7220 317.8617 318.0015 318.1412 318.2809 318.4206 318.5603 318.7000 318.8397 318.9793 319.1190 319.2586 319.3982 319.5378 319.6774 319.8170 319.9566 320.0962 320.2357 320.3753 320.5148 320.6543 320.7938 320.9333 321.0728 321.2123 321.3517 321.4912 321.6306 321.7700 321.9094 322.0488 322.1882 322.3276 322.4669 322.6063 322.7456 322.8849 323.0243 323.1636 323.3028 323.4421 323.5814 323.7206 323.8599 323.9991 324.1383 324.2775 324.4167 324.5559 324.6951 324.8342 324.9734 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250508T110948.2Z 9259.465142 150 1 54.28 2 73.25 81.72 126.94 309.10 0.00 1 0.00 1 0 17 6.779e-02 5.444e-03 4.137e-03 4.706e-04 4.892953e-01 2.475864e-04 5.658402e-03 -6.000000e+00 4.081921e-02 230.39 -2.00 3.54 -2.00 318.74 0.00e+00 1.157272e-03 5.491699e-05 2.629688e-04 -6.000000e+00 1.803368e-03 281.61 -2.00 20.00 -2.00 318.02 0.00e+00 3.416 0.001 302.00 328.00 3 1.1545e+00 6.7834e-04 4.2664e-02 -6.0000e+00 1.0195e-01 4.0501e-02 7.7589e-04 2.5554e-02 -6.0000e+00 1.1059e-01 -3.9321e-02 5.4022e-04 1.2460e-02 -6.0000e+00 6.5712e-02 9.9740e-03 2.7990e-04 3.6595e-03 -6.0000e+00 2.7088e-02 3.1122e-03 -4.9823e-05 1.4202e-05 4.2716e-05 -6.0000e+00 2.1200e-03 1.8338e-02 -1.2828e-04 10 0 0 10 0 0 99.50 25.85 0.30 0.01834 0.01796 567 60 1 5 0 95.720 34.75 20.03 25.85 25.85 5.2 1042.77 -27860 -20331 -19858 -23978 -29613 -30549 -25494 -17161 -18883 -14645 -17041 -11326 -11000 -8678 -3684 -3441 -452 596 1971 2442 785 -1853 721 -1774 -1634 -1952 -3620 -4092 -1264 -1422 -551 643 -1608 -2449 -3272 -1183 -1566 -362 288 -400 -915 410 668 503 894 944 713 956 307 1061 1162 1495 1287 1121 756 953 411 450 582 746 1143 1527 1388 1075 508 -75 419 149 1013 680 -58 112 86 -18 -368 -492 -456 -696 -520 -665 -1059 -1441 -1907 -1370 -766 -497 -122 -54 223 163 393 504 264 452 254 110 170 154 -398 -564 -480 -443 -3 131 -657 -981 -460 -459 132 229 168 45 108 172 224 493 643 331 161 -61 -138 117 336 160 394 411 384 905 491 64 -58 -257 -32 19 28 -86 -50 80 -183 -188 -47 -370 -358 -895 -666 -660 -793 -989 -1051 -917 -640 -789 -624 -798 -573 -669 -625 -298 -315 -44 62 214 250 83 -207 83 -225 -220 -272 -509 -563 -170 -206 -90 117 -326 -510 -678 -250 -345 -94 89 -132 -334 156 244 187 335 357 272 370 124 452 539 705 656 609 405 525 231 250 319 412 664 912 914 714 340 -52 284 99 741 528 -47 92 69 -14 -284 -346 -323 -478 -397 -553 -955 -1377 -1880 -1368 -813 -534 -136 -62 249 173 404 507 258 457 271 127 206 198 -535 -740 -610 -540 -4 158 -818 -1245 -615 -630 188 343 260 72 165 257 327 697 921 482 249 -94 -212 181 500 237 556 577 532 1311 731 101 -95 -427 -56 33 51 -158 -94 152 -345 -351 -87 -653 -628 SS 20250508T111153.5Z 9259.466591 152 1 54.32 2 72.87 82.05 127.23 309.61 0.00 1 0.00 1 0 17 6.026e-02 5.458e-03 3.977e-03 4.767e-04 4.788755e-01 2.505629e-04 5.553918e-03 -6.000000e+00 3.628790e-02 230.39 -2.00 3.54 -2.00 318.68 0.00e+00 1.052730e-03 5.438740e-05 2.559503e-04 -6.000000e+00 1.603168e-03 281.61 -2.00 20.00 -2.00 317.95 0.00e+00 3.345 0.001 302.00 328.00 3 1.2623e+00 6.8608e-04 4.1777e-02 -6.0000e+00 9.0631e-02 3.8884e-02 7.8325e-04 2.5037e-02 -6.0000e+00 9.8312e-02 -3.5732e-02 5.3899e-04 1.2198e-02 -6.0000e+00 5.8417e-02 8.1333e-03 2.7872e-04 3.5406e-03 -6.0000e+00 2.4081e-02 3.0290e-03 -2.9901e-05 1.4483e-05 4.1898e-05 -6.0000e+00 1.8846e-03 1.8217e-02 -1.2995e-04 10 0 0 10 0 0 98.01 25.87 0.30 0.01822 0.01799 560 59 1 5 0 96.980 34.75 20.02 25.87 26.03 5.2 1043.23 -25485 -15742 -20362 -20406 -24616 -29162 -21214 -14136 -15214 -15739 -14164 -10345 -9753 -9070 -4262 -2519 -1351 1965 1185 2294 1260 -800 1803 -1799 -1589 -1626 -3685 -3298 -1276 -1703 -143 554 -1445 -2147 -2924 -1025 -1438 -209 183 -480 -922 557 528 212 895 813 312 720 262 755 1086 1211 1421 1155 787 923 357 405 578 928 1060 1631 1440 1011 536 -122 347 145 996 775 37 232 128 74 -329 -782 -529 -804 -538 -628 -1129 -1272 -1925 -1414 -805 -566 -165 13 293 219 308 551 284 360 298 143 127 168 -386 -532 -483 -587 -59 133 -717 -951 -487 -449 124 335 165 77 86 230 211 492 546 334 195 -141 -228 139 357 157 477 481 349 976 475 106 20 -262 -56 -12 22 -69 -70 69 -146 -181 -55 -393 -366 -871 -536 -738 -707 -848 -1072 -792 -554 -663 -733 -695 -557 -628 -701 -370 -243 -141 213 125 248 141 -93 217 -241 -226 -238 -547 -474 -180 -258 -24 105 -304 -463 -627 -225 -328 -56 54 -164 -347 219 199 82 346 317 123 287 108 330 516 585 738 640 429 518 205 229 323 521 627 990 962 681 363 -85 237 98 734 606 30 191 103 59 -256 -556 -377 -556 -412 -524 -1020 -1213 -1897 -1412 -854 -609 -184 15 326 242 318 552 276 362 316 165 152 213 -513 -692 -607 -709 -68 160 -886 -1243 -645 -611 175 496 252 119 135 340 304 707 769 495 296 -221 -356 211 541 228 686 664 477 1389 718 169 33 -439 -95 -21 40 -127 -133 129 -278 -331 -99 -701 -649 SS 20250508T111358.6Z 9259.468039 154 1 54.32 2 72.49 82.39 127.52 310.13 0.00 1 0.00 1 0 17 5.318e-02 5.403e-03 3.925e-03 4.955e-04 4.700039e-01 2.603280e-04 5.454030e-03 -6.000000e+00 3.202480e-02 230.39 -2.00 3.54 -2.00 318.60 0.00e+00 1.096310e-03 5.536583e-05 2.375149e-04 -6.000000e+00 1.414836e-03 281.61 -2.00 20.00 -2.00 317.88 0.00e+00 3.276 0.001 302.00 328.00 3 1.4107e+00 7.1160e-04 4.0948e-02 -6.0000e+00 7.9984e-02 3.8162e-02 8.1165e-04 2.4559e-02 -6.0000e+00 8.6762e-02 -3.4250e-02 5.5279e-04 1.1966e-02 -6.0000e+00 5.1555e-02 7.7353e-03 2.8513e-04 3.4871e-03 -6.0000e+00 2.1252e-02 2.8153e-03 -6.2069e-05 1.5089e-05 4.1261e-05 -6.0000e+00 1.6633e-03 1.8202e-02 -1.3412e-04 10 0 0 10 0 0 96.85 25.90 0.30 0.01820 0.01774 513 54 1 5 0 105.870 34.75 20.00 25.90 26.13 5.1 1043.03 -20149 -16549 -13882 -19526 -23995 -23690 -20096 -10183 -16402 -13474 -13165 -9145 -8432 -6769 -2713 -3248 529 1269 2227 2378 568 -1575 1838 -1892 -1047 -1814 -3272 -2765 -729 -882 106 796 -1630 -1665 -3200 -1400 -1138 -350 367 -834 -869 320 648 324 516 528 160 505 279 807 969 1243 1337 1097 693 949 413 347 604 880 1185 1537 1390 1140 589 -30 411 74 977 735 50 177 80 -34 -392 -459 -320 -825 -433 -602 -1009 -1479 -1899 -1354 -779 -539 -154 29 297 210 393 533 325 443 297 93 203 132 -437 -565 -550 -498 -111 115 -733 -965 -522 -453 151 297 167 31 87 165 246 450 651 329 135 -131 -189 91 387 195 374 492 380 989 460 112 -28 -207 -67 11 61 10 -82 62 -170 -214 -29 -393 -433 -710 -617 -512 -727 -889 -892 -801 -414 -779 -660 -687 -521 -572 -545 -247 -335 57 133 245 272 68 -196 233 -267 -156 -280 -508 -415 -107 -139 19 157 -358 -372 -715 -320 -269 -98 112 -297 -339 121 252 129 206 213 65 208 119 362 441 615 712 583 386 544 241 201 344 505 715 952 947 781 406 -21 285 50 729 581 41 147 65 -28 -308 -329 -230 -576 -333 -504 -915 -1421 -1880 -1418 -829 -581 -173 33 332 233 406 536 316 446 314 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