File name: Pandora26s1_CambridgeMA_20250605_L2Fit_fout2c10d20240425p1-8.txt File generation date: 20250606T045543.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Kelly Chance Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora26_OF_v3d20230725.txt Instrument calibration file used: Pandora26s1_CF_v10d20240425.txt Level 1 file used: Pandora26s1_CambridgeMA_20250605_L1_smca1c10d20240425p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20250605 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0963 305.2371 305.3779 305.5186 305.6594 305.8002 305.9409 306.0816 306.2224 306.3631 306.5038 306.6445 306.7851 306.9258 307.0664 307.2071 307.3477 307.4883 307.6289 307.7695 307.9101 308.0507 308.1912 308.3318 308.4723 308.6129 308.7534 308.8939 309.0344 309.1748 309.3153 309.4558 309.5962 309.7366 309.8771 310.0175 310.1579 310.2982 310.4386 310.5790 310.7193 310.8597 311.0000 311.1403 311.2806 311.4209 311.5612 311.7015 311.8417 311.9820 312.1222 312.2624 312.4026 312.5428 312.6830 312.8232 312.9634 313.1035 313.2437 313.3838 313.5239 313.6640 313.8041 313.9442 314.0843 314.2243 314.3644 314.5044 314.6444 314.7844 314.9244 315.0644 315.2044 315.3444 315.4843 315.6243 315.7642 315.9041 316.0440 316.1839 316.3238 316.4637 316.6035 316.7434 316.8832 317.0230 317.1628 317.3026 317.4424 317.5822 317.7220 317.8617 318.0015 318.1412 318.2809 318.4206 318.5603 318.7000 318.8397 318.9793 319.1190 319.2586 319.3982 319.5378 319.6774 319.8170 319.9566 320.0962 320.2357 320.3753 320.5148 320.6543 320.7938 320.9333 321.0728 321.2123 321.3517 321.4912 321.6306 321.7700 321.9094 322.0488 322.1882 322.3276 322.4669 322.6063 322.7456 322.8849 323.0243 323.1636 323.3028 323.4421 323.5814 323.7206 323.8599 323.9991 324.1383 324.2775 324.4167 324.5559 324.6951 324.8342 324.9734 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250605T110948.2Z 9287.465142 102 1 54.29 2 70.22 77.02 140.20 330.40 0.00 1 0.00 1 0 17 2.413e-02 5.280e-03 1.637e-03 3.556e-04 3.984144e-01 1.880521e-04 4.643996e-03 -6.000000e+00 1.464387e-02 232.31 -2.00 3.54 -2.00 317.95 0.00e+00 7.369025e-04 3.275462e-05 1.664797e-04 -6.000000e+00 6.498451e-04 284.53 -2.00 20.00 -2.00 317.16 0.00e+00 2.922 0.000 302.00 328.00 3 1.2161e+00 5.0714e-04 3.5926e-02 -6.0000e+00 3.6712e-02 -1.1851e-03 5.7215e-04 2.0908e-02 -6.0000e+00 3.9734e-02 -2.6050e-02 3.5464e-04 1.0083e-02 -6.0000e+00 2.3614e-02 7.2810e-03 1.7601e-04 2.8217e-03 -6.0000e+00 9.7325e-03 5.3899e-03 2.8303e-04 1.1028e-05 3.3829e-05 -6.0000e+00 7.5495e-04 1.4063e-02 -5.9352e-05 10 0 0 10 0 0 18.03 26.42 0.29 0.01406 0.01619 756 79 1 5 0 71.790 35.25 20.01 26.42 30.48 5.2 1058.53 -7295 -7533 -7664 -8772 -11531 -11725 -8303 -5941 -5283 -5357 -5049 -3837 -2190 -2166 -611 -699 511 1640 953 2375 1231 299 1827 598 -37 -94 -1376 -1112 -366 354 740 1240 205 -1285 -2194 -616 -711 -232 -330 -924 -929 -496 34 -243 -34 10 -378 -41 -229 303 698 770 1007 843 528 994 438 352 648 887 1254 1671 1482 1109 412 -5 342 120 1029 583 -164 154 14 195 -271 -443 -150 -592 -445 -807 -1233 -1481 -1776 -1333 -679 -520 -82 46 237 243 431 536 213 608 329 132 185 169 -406 -608 -630 -703 -260 27 -650 -951 -432 -381 104 287 232 99 136 190 189 464 602 274 195 -135 -227 4 336 125 467 485 460 936 541 172 70 -218 -25 88 119 -28 -76 87 -138 -218 -158 -488 -457 -468 -527 -542 -594 -759 -781 -582 -456 -441 -471 -465 -387 -232 -271 -87 -111 86 291 179 419 224 56 353 125 -8 -21 -314 -244 -78 79 181 336 56 -359 -607 -174 -226 -81 -128 -412 -424 -238 16 -121 -17 5 -190 -20 -117 162 377 449 593 526 343 628 282 225 431 563 834 1204 1107 834 310 -4 251 91 804 487 -142 136 12 169 -227 -339 -112 -450 -352 -696 -1152 -1466 -1815 -1387 -751 -588 -93 53 270 274 468 560 213 619 352 153 223 216 -526 -796 -799 -857 -306 33 -821 -1229 -567 -530 150 430 356 153 204 276 266 648 825 395 291 -203 -343 6 494 182 649 666 619 1303 792 257 111 -350 -40 146 203 -50 -135 157 -248 -387 -276 -827 -771 SS 20250605T111153.3Z 9287.466589 104 1 54.33 2 69.84 77.34 140.38 331.12 0.00 1 0.00 1 0 17 2.257e-02 5.251e-03 1.466e-03 3.382e-04 3.910752e-01 1.785588e-04 4.564110e-03 -6.000000e+00 1.369809e-02 232.31 -2.00 3.54 -2.00 317.85 0.00e+00 7.283949e-04 3.023015e-05 1.472988e-04 -6.000000e+00 6.078748e-04 284.53 -2.00 20.00 -2.00 317.05 0.00e+00 2.871 0.000 302.00 328.00 3 1.1795e+00 4.8111e-04 3.5285e-02 -6.0000e+00 3.4341e-02 -2.7678e-03 5.4255e-04 2.0519e-02 -6.0000e+00 3.7167e-02 -2.4018e-02 3.3381e-04 9.8895e-03 -6.0000e+00 2.2089e-02 6.4327e-03 1.6469e-04 2.7660e-03 -6.0000e+00 9.1039e-03 5.9284e-03 3.0205e-04 1.0542e-05 3.3934e-05 -6.0000e+00 7.0620e-04 1.4055e-02 -5.9603e-05 10 0 0 10 0 0 9.30 26.43 0.29 0.01406 0.01632 806 85 1 5 0 67.400 35.00 20.00 26.43 30.59 5.2 1058.88 -7590 -6969 -7200 -9113 -10306 -9882 -7632 -4626 -5295 -6330 -4814 -3196 -2161 -1341 -565 -389 328 1289 765 1977 1268 1011 2147 667 188 -79 -1081 -923 -33 589 1022 1017 102 -1138 -1855 -452 -673 -144 -349 -927 -988 -515 -174 -334 110 20 -375 -89 -219 163 843 704 930 991 588 944 571 359 582 883 1247 1606 1387 1045 298 -74 348 207 996 531 -175 131 7 112 -173 -426 -207 -566 -418 -698 -1165 -1404 -1836 -1342 -772 -494 -99 37 292 145 352 573 244 576 365 93 187 166 -461 -642 -595 -651 -201 30 -628 -973 -449 -393 55 287 237 96 115 162 179 481 570 350 163 -131 -269 47 355 203 455 538 404 979 563 156 82 -188 -20 55 93 -31 -72 91 -161 -256 -155 -493 -425 -530 -525 -548 -670 -724 -698 -574 -378 -476 -605 -475 -313 -245 -178 -86 -66 59 224 140 372 245 199 438 147 44 -19 -260 -213 -7 138 263 268 29 -333 -536 -133 -224 -52 -141 -432 -471 -257 -89 -174 57 10 -196 -47 -116 85 471 402 567 638 374 616 379 237 379 579 857 1136 1019 811 231 -55 262 152 799 455 -155 120 6 96 -142 -334 -159 -441 -338 -614 -1064 -1360 -1841 -1424 -840 -548 -115 44 339 160 375 586 249 597 396 106 229 216 -605 -824 -739 -776 -239 36 -778 -1277 -599 -537 78 423 357 146 174 237 254 657 788 495 238 -198 -412 70 528 290 638 746 550 1374 806 235 128 -296 -32 92 160 -54 -128 165 -291 -447 -265 -842 -721 SS 20250605T111359.3Z 9287.468047 106 1 54.32 2 69.46 77.66 140.57 331.86 0.00 1 0.00 1 0 17 2.076e-02 5.289e-03 1.332e-03 3.246e-04 3.845761e-01 1.715248e-04 4.489928e-03 -6.000000e+00 1.259841e-02 232.31 -2.00 3.54 -2.00 317.77 0.00e+00 7.147932e-04 2.827065e-05 1.593067e-04 -6.000000e+00 5.590655e-04 284.53 -2.00 20.00 -2.00 316.97 0.00e+00 2.821 0.000 302.00 328.00 3 1.1547e+00 4.6090e-04 3.4673e-02 -6.0000e+00 3.1584e-02 -1.7354e-03 5.1903e-04 2.0150e-02 -6.0000e+00 3.4183e-02 -2.3384e-02 3.1684e-04 9.7178e-03 -6.0000e+00 2.0315e-02 6.1565e-03 1.5571e-04 2.7089e-03 -6.0000e+00 8.3732e-03 6.4217e-03 3.0081e-04 1.0116e-05 3.3005e-05 -6.0000e+00 6.4949e-04 1.3968e-02 -5.7504e-05 10 0 0 10 0 0 6.99 26.44 0.31 0.01397 0.01623 846 89 1 5 0 64.200 35.00 20.01 26.44 30.67 5.2 1059.03 -6474 -6492 -6109 -7701 -9738 -9229 -6683 -4864 -3938 -5521 -5449 -3125 -2269 -1458 -637 -579 68 1293 963 2046 1287 874 1993 565 359 86 -1169 -1200 -106 639 1383 1064 642 -1169 -1913 -669 -968 -225 -344 -859 -944 -561 -142 -346 -30 -55 -410 -208 -333 154 771 685 966 960 725 916 503 325 669 1065 1224 1664 1401 1059 355 -121 451 123 1049 544 -162 139 -123 120 -324 -407 -259 -694 -437 -712 -1257 -1350 -1871 -1382 -630 -487 -115 22 202 153 326 478 258 622 406 91 165 170 -414 -614 -578 -650 -202 23 -626 -908 -448 -409 45 326 271 88 108 206 203 487 556 330 177 -132 -201 125 335 175 442 479 406 1019 516 101 40 -237 -8 54 89 -40 -68 81 -141 -233 -171 -493 -423 -485 -527 -498 -604 -735 -699 -537 -430 -377 -513 -529 -328 -275 -207 -103 -104 12 239 187 408 264 183 432 132 89 22 -298 -294 -25 158 372 294 191 -359 -579 -207 -314 -86 -146 -392 -469 -275 -72 -177 -16 -28 -210 -107 -173 83 447 405 609 606 477 618 345 222 450 721 825 1214 1061 847 283 -92 332 93 823 457 -147 125 -109 104 -273 -327 -195 -528 -345 -612 -1173 -1333 -1914 -1441 -697 -552 -131 25 231 173 355 499 267 630 431 104 199 217 -551 -798 -726 -786 -235 28 -787 -1169 -586 -567 65 485 413 135 161 296 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