File name: Pandora26s1_CambridgeMA_20250618_L2Fit_fout2c10d20240425p1-8.txt File generation date: 20250619T045056.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Kelly Chance Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 26 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora26_OF_v3d20230725.txt Instrument calibration file used: Pandora26s1_CF_v10d20240425.txt Level 1 file used: Pandora26s1_CambridgeMA_20250618_L1_smca1c10d20240425p1-8.txt Full location name: Harvard - William James Hall, Cambridge (MA) Short location name: CambridgeMA Country of location: USA Location latitude [deg]: 42.3800 Location longitude [deg]: -71.1100 Location altitude [m]: 60 Local noon date: 20250618 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0963 305.2371 305.3779 305.5186 305.6594 305.8002 305.9409 306.0816 306.2224 306.3631 306.5038 306.6445 306.7851 306.9258 307.0664 307.2071 307.3477 307.4883 307.6289 307.7695 307.9101 308.0507 308.1912 308.3318 308.4723 308.6129 308.7534 308.8939 309.0344 309.1748 309.3153 309.4558 309.5962 309.7366 309.8771 310.0175 310.1579 310.2982 310.4386 310.5790 310.7193 310.8597 311.0000 311.1403 311.2806 311.4209 311.5612 311.7015 311.8417 311.9820 312.1222 312.2624 312.4026 312.5428 312.6830 312.8232 312.9634 313.1035 313.2437 313.3838 313.5239 313.6640 313.8041 313.9442 314.0843 314.2243 314.3644 314.5044 314.6444 314.7844 314.9244 315.0644 315.2044 315.3444 315.4843 315.6243 315.7642 315.9041 316.0440 316.1839 316.3238 316.4637 316.6035 316.7434 316.8832 317.0230 317.1628 317.3026 317.4424 317.5822 317.7220 317.8617 318.0015 318.1412 318.2809 318.4206 318.5603 318.7000 318.8397 318.9793 319.1190 319.2586 319.3982 319.5378 319.6774 319.8170 319.9566 320.0962 320.2357 320.3753 320.5148 320.6543 320.7938 320.9333 321.0728 321.2123 321.3517 321.4912 321.6306 321.7700 321.9094 322.0488 322.1882 322.3276 322.4669 322.6063 322.7456 322.8849 323.0243 323.1636 323.3028 323.4421 323.5814 323.7206 323.8599 323.9991 324.1383 324.2775 324.4167 324.5559 324.6951 324.8342 324.9734 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250618T152428.0Z 9300.641991 295 1 54.69 2 25.37 131.97 78.33 256.08 0.00 1 0.00 1 0 17 2.132e-02 1.252e-02 4.245e-03 2.648e-03 1.736350e-01 1.424980e-03 2.044544e-03 -6.000000e+00 1.297212e-02 232.94 -2.00 3.54 -2.00 315.37 0.00e+00 2.989460e-04 1.340061e-04 1.109759e-04 -6.000000e+00 5.773322e-04 285.83 -2.00 20.00 -2.00 314.67 0.00e+00 1.106 0.000 302.00 328.00 3 6.7817e+00 3.7080e-03 1.4331e-02 -6.0000e+00 3.2558e-02 7.6599e-02 4.1193e-03 8.9579e-03 -6.0000e+00 3.5209e-02 -1.2764e-02 2.3364e-03 4.3183e-03 -6.0000e+00 2.0931e-02 7.1054e-04 1.0066e-03 1.1645e-03 -6.0000e+00 8.6287e-03 1.6497e-04 7.9200e-04 8.4352e-05 1.6617e-05 -6.0000e+00 6.6720e-04 1.4640e-02 2.5591e-05 12 8 8 10 0 0 99.92 27.03 -0.38 0.01464 0.02059 35 4 1 5 0 1562.400 35.50 20.01 27.03 32.76 5.3 1065.91 560 -1484 1129 -3944 -6017 -11253 -5600 7468 1204 -269 -2947 125 3719 1443 -1575 -4010 565 2543 1560 6675 3272 -944 5512 1491 2177 451 -3503 -2106 -1637 27 807 1128 782 -207 -4015 2311 -1604 -1085 -482 -946 -1480 1068 1181 -444 -1532 1238 -285 -648 -1478 -3354 -1385 711 3022 2639 264 923 -2699 857 875 534 -1316 832 271 803 3321 -1780 292 -72 -860 3913 -8 881 1345 341 -1178 -1553 -1254 -2117 -2320 -355 -2421 -1740 -1274 -1069 -38 264 217 1342 1411 835 394 -642 -769 -645 -401 -390 1472 1332 -609 -1151 -465 -1380 -967 239 -1205 -594 -528 -1214 1713 1493 431 240 296 602 -157 -1101 -369 37 -121 88 1294 97 745 1311 -79 383 -196 160 -304 -120 285 -2048 -749 90 828 735 -528 902 364 -440 -427 -330 -439 160 -450 325 -1098 -1569 -3034 -1516 1944 356 -82 -920 39 1229 541 -664 -1824 252 1138 721 2989 1523 -459 2561 749 1122 217 -1692 -1033 -754 12 370 541 389 -103 -1983 1092 -871 -621 -319 -705 -1183 860 964 -368 -1274 984 -223 -490 -1098 -2557 -1079 570 2473 2241 234 823 -2297 761 768 475 -1243 750 260 781 3025 -1570 258 -63 -818 3580 -8 914 1372 336 -1086 -1413 -1041 -1719 -1986 -329 -2310 -1782 -1373 -1213 -45 335 267 1662 1724 1055 460 -689 -763 -630 -412 -436 1773 1729 -763 -1404 -572 -1609 -1103 282 -1544 -735 -682 -1643 2354 2148 642 352 412 770 -202 -1365 -458 48 -155 119 1757 132 975 1761 -102 467 -231 191 -383 -158 388 -2900 -987 122 1176 1087 -813 1392 563 -671 -631 -474 -626 SS 20250618T152706.2Z 9300.643822 299 1 1.16 2 25.01 133.11 78.79 256.54 0.00 1 0.00 1 0 17 7.700e-03 6.230e-03 4.145e-03 3.297e-03 1.512554e-01 1.799714e-03 1.841436e-03 -6.000000e+00 4.680218e-03 232.94 -2.00 3.54 -2.00 314.15 0.00e+00 2.838055e-04 1.337286e-04 3.153905e-05 -6.000000e+00 2.084531e-04 285.83 -2.00 20.00 -2.00 313.58 0.00e+00 1.103 0.000 302.00 328.00 3 3.5836e+00 4.6274e-03 1.3629e-02 -6.0000e+00 1.1747e-02 1.6175e-02 5.1090e-03 7.9778e-03 -6.0000e+00 1.2707e-02 2.6502e-03 2.9195e-03 3.8539e-03 -6.0000e+00 7.5537e-03 -5.3361e-03 1.2140e-03 1.0690e-03 -6.0000e+00 3.1112e-03 4.3377e-03 1.8199e-04 1.0384e-04 1.6974e-05 -6.0000e+00 2.4101e-04 1.6218e-02 -1.7890e-04 12 1 1 12 1 1 999.00 27.06 0.34 0.01622 0.01759 2 15 1 5 0 383.370 35.75 20.01 27.06 32.76 5.3 1066.50 499 -1614 -1051 -2715 -812 741 1761 1681 568 -582 -1030 241 -574 -313 805 -258 -2 197 269 1068 1792 1249 1429 715 555 -199 35 -123 156 88 121 752 -1562 -969 -2651 16 -1628 -114 -596 -545 -1682 -351 -565 -814 -585 -80 -483 -101 -161 478 383 1120 1240 674 668 568 488 746 591 388 489 1533 752 800 -389 -329 813 -113 625 903 -653 -832 230 142 -374 157 819 -724 15 -598 -543 -1149 -1192 -1527 -1123 -389 213 -76 366 73 72 -182 -143 932 333 336 684 449 -325 -182 -316 -906 -116 343 -636 -849 -331 -141 311 324 165 -175 416 191 132 129 354 104 -44 -409 -556 -504 365 150 452 1214 369 607 749 40 167 -104 53 415 -49 59 167 312 -295 -191 -398 -278 -821 220 -750 -471 -1203 -324 305 719 753 259 -272 -481 115 -285 -171 449 -152 -1 115 161 647 1083 760 886 443 356 -129 22 -76 95 52 75 458 -1004 -608 -1626 10 -1070 -82 -463 -454 -1453 -310 -488 -705 -520 -69 -407 -85 -131 391 326 958 1105 602 608 524 452 684 538 358 455 1502 757 820 -385 -309 732 -102 603 891 -677 -889 240 147 -372 145 714 -645 13 -572 -551 -1186 -1300 -1711 -1300 -462 255 -93 441 87 80 -198 -148 941 356 367 791 542 -394 -219 -370 -1035 -129 389 -757 -1036 -419 -181 402 438 222 -238 547 239 156 151 417 125 -55 -530 -737 -660 474 187 545 1422 434 721 904 49 213 -131 68 538 -65 82 233 441 -419 -266 -554 -377 -1112 SS 20250618T155359.8Z 9300.662498 308 1 55.05 2 21.79 146.42 83.43 261.18 0.00 1 0.00 1 0 17 3.364e-02 2.448e-02 3.300e-03 2.166e-03 1.472287e-01 1.162470e-03 1.869971e-03 -6.000000e+00 2.044121e-02 232.94 -2.00 3.54 -2.00 315.20 0.00e+00 1.585192e-03 1.054426e-04 1.502734e-04 -6.000000e+00 9.105556e-04 285.84 -2.00 20.00 -2.00 314.52 0.00e+00 1.077 0.000 302.00 328.00 3 6.5967e+00 3.0195e-03 1.3338e-02 -6.0000e+00 5.1305e-02 2.9594e-02 3.3528e-03 7.9755e-03 -6.0000e+00 5.5508e-02 8.3249e-03 1.9042e-03 3.7435e-03 -6.0000e+00 3.2995e-02 -6.2429e-03 8.1416e-04 1.1986e-03 -6.0000e+00 1.3587e-02 2.1728e-04 -6.3576e-04 6.9051e-05 1.6039e-05 -6.0000e+00 1.0532e-03 1.5237e-02 -3.0897e-04 12 9 9 12 32 32 99.99 27.29 1.12 0.01524 0.01046 30 3 1 5 0 1834.810 -99.00 20.01 27.29 34.32 5.2 1073.50 1914 868 6295 7567 -5251 3831 -15860 -11185 -328 2231 2137 3564 2145 2289 4687 5039 1338 -2890 2986 6118 -11358 -7826 2668 -102 2294 2744 1727 1752 3796 2745 -725 -6853 -2895 -736 661 2665 -3334 11864 -599 -1865 206 -3188 -1000 -49 -1459 573 547 1433 865 -2043 1469 1675 1213 1016 -5745 704 229 694 -1703 1663 2360 2900 -4053 1703 569 350 2011 -225 1141 182 725 6166 830 1018 252 617 752 825 41 1330 -953 2435 -3506 46 307 -702 -1657 -9404 1306 1741 -284 -3770 823 895 3 528 748 2040 52 539 -1072 418 -156 1547 -4238 -24 -759 395 2137 87 555 -2120 -360 211 -23 263 -258 148 2776 473 1054 1442 -293 4435 1985 -4291 670 1261 -1315 740 2500 -3961 1378 -2938 -2786 813 -430 630 1407 845 337 216 -1894 577 274 2012 2193 -1586 1034 -5511 -3673 -113 755 719 1228 819 880 1918 2160 610 -1405 1401 2836 -6293 -4177 1303 -53 1193 1427 877 835 1677 1209 -342 -3601 -1508 -368 313 1262 -1854 6582 -400 -1408 162 -2685 -838 -41 -1224 463 428 1071 633 -1546 1116 1331 1010 874 -5376 625 204 612 -1528 1462 2152 2803 -4095 1653 535 328 1728 -196 1051 172 728 6033 848 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