File name: Pandora260s1_CameronLA_20230901_L2Fit_fout2c3d20230417p1-8.txt File generation date: 20241203T141809.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v3d20230417.txt Level 1 file used: Pandora260s1_CameronLA_20230901_L1_smca1c3d20230417p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20230901 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1217 305.2623 305.4028 305.5434 305.6839 305.8244 305.9649 306.1054 306.2459 306.3864 306.5268 306.6673 306.8077 306.9482 307.0886 307.2290 307.3694 307.5098 307.6501 307.7905 307.9308 308.0712 308.2115 308.3518 308.4921 308.6324 308.7727 308.9130 309.0532 309.1935 309.3337 309.4739 309.6141 309.7544 309.8945 310.0347 310.1749 310.3150 310.4552 310.5953 310.7354 310.8755 311.0156 311.1557 311.2958 311.4359 311.5759 311.7160 311.8560 311.9960 312.1360 312.2760 312.4160 312.5560 312.6959 312.8359 312.9758 313.1158 313.2557 313.3956 313.5355 313.6753 313.8152 313.9551 314.0949 314.2348 314.3746 314.5144 314.6542 314.7940 314.9338 315.0735 315.2133 315.3530 315.4928 315.6325 315.7722 315.9119 316.0516 316.1912 316.3309 316.4705 316.6102 316.7498 316.8894 317.0290 317.1686 317.3082 317.4478 317.5873 317.7269 317.8664 318.0059 318.1455 318.2850 318.4244 318.5639 318.7034 318.8428 318.9823 319.1217 319.2611 319.4005 319.5399 319.6793 319.8187 319.9581 320.0974 320.2367 320.3761 320.5154 320.6547 320.7940 320.9333 321.0725 321.2118 321.3510 321.4903 321.6295 321.7687 321.9079 322.0471 322.1862 322.3254 322.4646 322.6037 322.7428 322.8819 323.0210 323.1601 323.2992 323.4383 323.5773 323.7164 323.8554 323.9944 324.1335 324.2725 324.4114 324.5504 324.6894 324.8283 324.9673 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230901T124601.6Z 8644.531963 236 1 54.61 2 78.68 86.90 82.08 262.11 0.00 1 0.00 1 0 17 4.991e-01 1.064e-02 2.016e-01 2.538e-03 5.743137e-01 1.326655e-03 6.134858e-03 -6.000000e+00 2.856900e-01 228.98 -2.00 3.24 -2.00 320.53 0.00e+00 -3.018631e-04 5.471213e-04 1.991912e-03 -6.000000e+00 1.371952e-02 294.13 -2.00 20.00 -2.00 319.74 0.00e+00 4.916 0.001 302.00 328.00 3 2.6902e+00 4.2464e-03 5.6963e-02 -6.0000e+00 7.1173e-01 -9.0524e-02 5.5730e-03 3.0875e-02 -6.0000e+00 7.7467e-01 2.6224e-02 5.2445e-03 1.3993e-02 -6.0000e+00 4.5590e-01 -1.6309e-02 2.6240e-03 4.1241e-03 -6.0000e+00 1.9555e-01 1.5953e-04 -2.3889e-05 6.8986e-05 4.1325e-05 -6.0000e+00 1.3028e-02 5.7934e-04 0.0000e+00 12 9 8 11 32 0 99.71 25.00 0.75 0.00058 0.00040 73 8 1 5 0 748.080 33.50 20.01 25.00 26.88 0.2 995.32 900000 -83192 195495 257471 900000 900000 -69701 900000 900000 -68218 93134 -127713 -65199 50836 10792 302944 97187 59 88001 103331 -141 -12108 29482 -26439 2801 11639 197198 -13572 99668 -8932 18107 -17396 -21495 -10295 -17435 19410 3064 12012 16940 4566 2029 -2382 1608 235 4675 -3312 -1617 10678 4914 -312 -3882 -6037 1378 7698 4411 -2192 2749 -3245 2750 -723 -2852 970 840 5138 1283 3302 -3224 -984 2683 236 665 1647 -407 -78 -1453 -1047 -4699 -3800 -3066 -2504 -693 -1553 -2667 -365 -255 -833 1320 1363 1867 4861 -286 -100 499 -1458 504 466 1681 376 158 -615 -960 -1428 -1848 36 -1590 -1341 -679 -669 627 1063 1241 1130 337 597 -830 -352 -593 226 136 271 174 428 906 -64 609 -860 -1034 258 -37 -369 -480 -723 -438 -583 -30 -29 703 911 522 11 -43 -634 -161 900000 -580 484 637 900000 900000 -517 900000 900000 -725 230 -3064 -1064 327 128 749 625 1 740 792 -3 -305 540 -948 82 331 878 -473 1109 -329 609 -977 -1451 -637 -1087 874 188 826 1387 504 254 -332 226 34 657 -516 -252 1521 774 -56 -815 -1310 304 1738 1086 -604 745 -924 717 -195 -827 303 299 1949 512 1232 -1277 -396 1183 124 347 880 -218 -43 -733 -472 -2078 -1709 -1566 -1384 -436 -1118 -2095 -274 -207 -726 1181 1251 1696 4083 -235 -83 395 -1228 435 464 1765 456 191 -784 -1141 -1534 -1996 37 -1821 -1606 -856 -842 851 1506 1924 1821 538 907 -1197 -518 -893 334 214 446 284 671 1376 -95 914 -1261 -1462 380 -58 -649 -863 -1374 -817 -1157 -63 -62 1506 1992 1144 22 -91 -1274 -315 SS 20230901T125137.3Z 8644.535848 239 1 7.13 2 77.46 87.59 83.23 262.83 0.00 1 0.00 1 0 17 3.131e-01 1.074e-02 2.715e-01 6.580e-03 5.319025e-01 3.366921e-03 5.663277e-03 -6.000000e+00 1.761958e-01 228.98 -2.00 3.24 -2.00 320.07 0.00e+00 -9.111467e-04 1.195128e-03 1.163445e-03 -6.000000e+00 8.348092e-03 294.13 -2.00 20.00 -2.00 319.22 0.00e+00 4.476 0.001 302.00 328.00 3 2.7081e+00 1.0238e-02 5.1681e-02 -6.0000e+00 4.3839e-01 -1.1411e-01 1.2890e-02 2.7058e-02 -6.0000e+00 4.7617e-01 6.7778e-02 1.1497e-02 1.2577e-02 -6.0000e+00 2.8395e-01 -3.1837e-02 5.9239e-03 3.8505e-03 -6.0000e+00 1.2296e-01 2.4707e-04 -3.8144e-04 1.7692e-04 3.2644e-05 -6.0000e+00 8.2352e-03 4.3444e-04 0.0000e+00 12 9 9 12 33 33 -25.69 25.01 0.63 0.00043 -0.00243 6 7 1 5 0 785.790 33.50 20.00 25.01 27.16 0.2 998.17 900000 -24674 40410 900000 205042 -53382 -39214 900000 60928 123952 128116 -73399 74513 43151 -2820 97135 17868 -2714 23710 99152 24452 -21583 13437 -16438 -1040 21844 83367 -9270 56842 -4102 3055 3281 -4533 -14568 -492 -3047 -1300 14749 1773 -8288 -1507 -4871 -328 3181 2372 -7440 2478 4477 4182 -962 -1928 -3630 2487 2015 4214 -2320 2203 -1825 4367 -2104 -2783 -203 974 5276 76 4552 -2314 -2664 579 -845 997 2139 549 2612 -3305 -915 -4072 -2438 -1202 -1913 -1497 -1522 -1794 -1352 -235 104 -49 2483 1835 2568 178 -578 627 -1173 1530 589 1769 563 573 -1110 -366 -2516 -1394 317 -1747 -1127 -384 -736 -283 1328 1170 609 -194 943 -589 -96 -261 524 404 227 -385 23 1139 -94 322 -325 -712 530 -168 -676 -67 -320 -654 -1050 17 -105 285 524 814 284 424 -568 -451 900000 -174 259 900000 1315 -479 -352 900000 391 795 822 -1648 478 470 -60 872 390 -80 578 1208 643 -914 439 -812 -48 855 1764 -470 1458 -213 174 217 -372 -1355 -37 -246 -119 1409 241 -1348 -253 -900 -61 575 438 -1548 472 859 834 -216 -492 -1045 735 651 1403 -863 809 -692 1515 -775 -1087 -79 423 2430 37 2019 -1085 -1294 308 -488 616 1354 347 1527 -1869 -491 -2118 -1266 -699 -1221 -1097 -1173 -1494 -1184 -220 97 -48 2438 1806 2392 169 -514 525 -1033 1474 613 1952 715 729 -1402 -454 -2872 -1564 344 -2111 -1419 -477 -980 -407 1972 1798 975 -307 1478 -875 -136 -376 790 620 365 -618 36 1788 -143 469 -458 -1024 791 -267 -1137 -116 -579 -1234 -2007 35 -214 593 1111 1720 578 856 -1103 -853 SS 20230901T125542.4Z 8644.538685 242 1 54.17 2 76.58 88.09 84.07 263.35 0.00 1 0.00 1 0 17 8.450e-02 8.510e-03 2.156e-02 1.062e-03 4.994299e-01 5.326410e-04 5.388735e-03 -6.000000e+00 4.729229e-02 228.98 -2.00 3.24 -2.00 319.53 0.00e+00 8.288200e-04 1.566849e-04 1.268414e-03 -6.000000e+00 2.188757e-03 294.13 -2.00 20.00 -2.00 318.64 0.00e+00 4.201 0.001 302.00 328.00 3 1.8937e+00 1.5419e-03 4.8417e-02 -6.0000e+00 1.1743e-01 -7.8968e-02 1.8488e-03 2.4994e-02 -6.0000e+00 1.2741e-01 1.9820e-02 1.4695e-03 1.1930e-02 -6.0000e+00 7.6315e-02 -1.3530e-02 7.7711e-04 3.1792e-03 -6.0000e+00 3.2837e-02 7.4407e-04 3.8760e-05 2.8332e-05 3.3335e-05 -6.0000e+00 2.1461e-03 3.0126e-04 0.0000e+00 11 8 0 10 0 0 94.92 25.03 0.56 0.00030 0.00059 183 19 1 5 0 295.980 33.50 20.00 25.03 27.44 0.1 1000.43 -36889 -38212 -20890 -20317 -21149 -814 -43560 9951 -12497 -22969 -22348 -35091 -17570 -6326 -532 2337 6880 -8171 7510 7874 -3351 -6395 1553 -6806 -5014 -856 6855 -6070 2357 -6029 282 -1763 -5760 -6874 -9784 -2954 -5212 -122 1345 856 -119 -1250 -347 -343 1110 -252 -431 861 -717 201 126 -623 1090 2532 1254 801 820 63 -77 227 -81 2086 2767 3210 1040 927 -1673 -921 1198 912 1474 1213 667 438 -369 -1164 -3180 -2872 -2358 -2187 -1573 -1282 -2089 -947 -370 335 1055 1457 1758 1640 833 -316 -602 -1040 -209 -212 638 914 382 -476 -1002 -1987 -1581 -383 -1320 -1032 -1080 -413 453 902 1184 875 505 2 -508 -367 -307 116 396 383 264 657 882 193 485 -544 -678 288 -17 -164 -246 -548 -536 -177 -59 26 491 720 404 103 -54 -695 -532 -550 -645 -307 -273 -265 -9 -807 126 -224 -483 -481 -996 -522 -208 -20 98 300 -453 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