File name: Pandora260s1_CameronLA_20231014_L2Fit_fout2c1d20230417p1-8.txt File generation date: 20240118T225121.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v1d20230417.txt Level 1 file used: Pandora260s1_CameronLA_20231014_L1_smca1c1d20230417p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20231014 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session and full initial 1.8 lab calibration, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0364 305.1770 305.3177 305.4583 305.5989 305.7394 305.8800 306.0206 306.1611 306.3016 306.4422 306.5827 306.7232 306.8637 307.0041 307.1446 307.2851 307.4255 307.5659 307.7064 307.8468 307.9872 308.1276 308.2679 308.4083 308.5487 308.6890 308.8293 308.9696 309.1100 309.2503 309.3905 309.5308 309.6711 309.8113 309.9516 310.0918 310.2320 310.3722 310.5124 310.6526 310.7928 310.9329 311.0731 311.2132 311.3533 311.4934 311.6335 311.7736 311.9137 312.0538 312.1938 312.3339 312.4739 312.6139 312.7539 312.8939 313.0339 313.1739 313.3139 313.4538 313.5937 313.7337 313.8736 314.0135 314.1534 314.2933 314.4331 314.5730 314.7128 314.8527 314.9925 315.1323 315.2721 315.4119 315.5517 315.6915 315.8312 315.9709 316.1107 316.2504 316.3901 316.5298 316.6695 316.8092 316.9488 317.0885 317.2281 317.3677 317.5074 317.6470 317.7865 317.9261 318.0657 318.2053 318.3448 318.4843 318.6239 318.7634 318.9029 319.0423 319.1818 319.3213 319.4607 319.6002 319.7396 319.8790 320.0184 320.1578 320.2972 320.4366 320.5759 320.7153 320.8546 320.9939 321.1332 321.2725 321.4118 321.5511 321.6904 321.8296 321.9688 322.1081 322.2473 322.3865 322.5257 322.6649 322.8040 322.9432 323.0823 323.2215 323.3606 323.4997 323.6388 323.7779 323.9170 324.0560 324.1951 324.3341 324.4731 324.6122 324.7512 324.8901 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231014T133904.7Z 8687.568804 76 1 54.33 2 72.88 110.35 71.67 110.24 0.00 1 0.00 1 0 17 2.454e-02 8.914e-03 1.836e-03 4.147e-04 3.697423e-01 2.095548e-04 4.119393e-03 -6.000000e+00 1.388507e-02 227.03 -2.00 3.24 -2.00 317.82 0.00e+00 9.797181e-04 3.576687e-05 5.058453e-04 -6.000000e+00 6.333729e-04 291.47 -2.00 20.00 -2.00 316.95 0.00e+00 3.346 0.000 302.00 328.00 3 9.6506e-01 5.5736e-04 3.7655e-02 -6.0000e+00 3.4371e-02 -1.9299e-02 6.3002e-04 1.7721e-02 -6.0000e+00 3.7124e-02 -1.0573e-03 4.0065e-04 8.6709e-03 -6.0000e+00 2.2227e-02 -3.5239e-03 2.1057e-04 2.4677e-03 -6.0000e+00 9.8492e-03 4.7704e-03 -2.3108e-04 1.1137e-05 2.4255e-05 -6.0000e+00 6.2651e-04 -5.7539e-02 0.0000e+00 11 8 0 10 0 0 96.02 24.98 0.43 -0.05754 -0.05928 629 66 1 5 0 86.360 33.50 20.02 24.98 25.83 0.0 984.54 900000 -6299 -3354 -1660 -8348 -8623 -9565 -8697 -4421 -5487 -9337 -7090 -6900 -3919 -2539 -1023 1377 1516 1051 2106 2234 845 1236 1665 368 1006 1221 815 -1516 -1188 -833 -54 966 684 -2739 -4373 -4209 -3660 -1924 -138 -121 -158 186 104 -26 965 281 169 -142 -803 4 603 539 1345 1189 1135 1205 784 321 200 26 1082 1655 2601 2623 603 382 -1150 -957 797 794 1117 923 900 774 -175 -1029 -2411 -2990 -2057 -2103 -1615 -1596 -2330 -1419 -688 56 694 1011 1347 1017 708 -286 -890 -826 -575 -327 519 1052 365 -224 -868 -1689 -1523 -333 -1358 -942 -829 -543 424 962 1223 831 641 202 -513 -163 -143 193 579 535 277 717 911 337 755 -370 -633 377 43 53 -139 -461 -625 -72 84 -27 430 559 191 -142 -377 -1078 900000 -445 -251 -124 -605 -567 -647 -647 -360 -504 -839 -685 -670 -441 -335 -157 228 265 181 377 418 162 234 333 80 232 292 194 -344 -257 -190 -14 249 197 -817 -1223 -1207 -1184 -680 -54 -56 -74 91 53 -13 489 144 86 -73 -414 2 328 318 795 750 740 766 511 208 133 18 714 1192 1951 2020 467 287 -840 -703 609 666 966 826 793 679 -149 -827 -1814 -2234 -1601 -1809 -1499 -1580 -2373 -1506 -753 62 812 1166 1600 1153 770 -300 -913 -853 -625 -370 633 1336 492 -294 -1103 -2039 -1799 -396 -1724 -1249 -1116 -745 596 1418 1864 1291 961 293 -737 -222 -197 281 846 828 431 1085 1342 492 1080 -513 -866 528 63 80 -220 -732 -1020 -120 145 -47 772 1026 352 -254 -664 -1882 SS 20231014T134529.1Z 8687.573253 80 1 54.32 2 71.59 111.31 70.41 111.20 0.00 1 0.00 1 0 17 2.048e-02 8.949e-03 1.062e-03 2.985e-04 3.478542e-01 1.508716e-04 3.883925e-03 -6.000000e+00 1.158989e-02 227.03 -2.00 3.24 -2.00 317.43 0.00e+00 8.567303e-04 2.305417e-05 3.892262e-04 -6.000000e+00 5.286789e-04 291.47 -2.00 20.00 -2.00 316.57 0.00e+00 3.125 0.000 302.00 328.00 3 5.7067e-01 3.9776e-04 3.5201e-02 -6.0000e+00 2.8690e-02 -1.8342e-02 4.4744e-04 1.6604e-02 -6.0000e+00 3.0987e-02 -1.6058e-03 2.7511e-04 8.1218e-03 -6.0000e+00 1.8553e-02 -2.8075e-03 1.4214e-04 2.3092e-03 -6.0000e+00 8.2211e-03 9.0048e-03 -2.7658e-04 8.0029e-06 2.3533e-05 -6.0000e+00 5.2296e-04 -5.7504e-02 0.0000e+00 11 8 0 10 0 0 97.74 24.98 0.43 -0.05750 -0.05958 941 99 1 5 0 57.720 33.50 20.00 24.98 26.08 0.0 987.70 900000 -3228 -2025 -3783 -5965 -7475 -7595 -6649 -3891 -3891 -5833 -7081 -5498 -3722 -1234 -29 1063 1434 867 2219 2523 691 1527 1683 1078 1071 917 357 -825 -1498 -240 -45 916 924 -2477 -4583 -4137 -3709 -1465 -172 -33 -136 217 64 470 958 378 94 -231 -819 42 946 609 1466 1105 867 1210 673 384 179 87 919 1729 2424 2419 555 168 -1153 -891 726 754 1075 854 800 824 -251 -906 -2327 -2775 -1959 -2055 -1598 -1608 -2318 -1495 -753 -46 572 1017 1338 915 740 -292 -925 -851 -550 -448 527 1121 399 -195 -754 -1720 -1481 -303 -1277 -900 -789 -597 412 949 1237 878 658 163 -462 -177 -191 244 588 544 268 714 862 388 761 -385 -576 357 100 58 -163 -434 -604 -72 87 -32 399 541 175 -150 -392 -1122 900000 -286 -193 -371 -541 -621 -642 -616 -400 -445 -703 -859 -721 -569 -199 -5 216 306 198 483 572 161 350 407 282 297 265 102 -222 -388 -64 -13 277 310 -860 -1496 -1378 -1301 -600 -80 -17 -70 116 36 261 533 213 52 -128 -457 24 554 367 936 716 581 831 474 268 123 60 655 1279 1879 1931 443 129 -897 -693 590 647 994 786 726 739 -218 -736 -1845 -2173 -1600 -1784 -1502 -1617 -2404 -1560 -843 -53 665 1209 1580 1066 822 -312 -957 -882 -601 -512 630 1446 529 -252 -939 -2097 -1762 -365 -1596 -1174 -1049 -811 574 1388 1871 1348 1001 240 -646 -241 -265 345 866 826 410 1063 1284 556 1063 -536 -787 484 145 86 -250 -689 -959 -116 147 -56 701 950 309 -263 -677 -1870 SS 20231014T135049.9Z 8687.576966 83 1 54.31 2 70.51 112.12 69.37 112.03 0.00 1 0.00 1 0 17 1.797e-02 8.923e-03 8.416e-04 2.707e-04 3.315939e-01 1.367610e-04 3.697740e-03 -6.000000e+00 1.017179e-02 227.03 -2.00 3.24 -2.00 317.24 0.00e+00 7.577024e-04 1.989681e-05 3.464121e-04 -6.000000e+00 4.639568e-04 291.47 -2.00 20.00 -2.00 316.38 0.00e+00 2.963 0.000 302.00 328.00 3 5.4836e-01 3.5881e-04 3.3399e-02 -6.0000e+00 2.5179e-02 -1.6069e-02 4.0287e-04 1.5772e-02 -6.0000e+00 2.7195e-02 -8.5919e-04 2.4438e-04 7.7003e-03 -6.0000e+00 1.6283e-02 -3.2730e-03 1.2464e-04 2.1827e-03 -6.0000e+00 7.2158e-03 1.0986e-02 -1.6226e-04 7.2645e-06 2.2450e-05 -6.0000e+00 4.5890e-04 -5.8202e-02 0.0000e+00 11 8 0 10 0 0 81.10 25.00 0.42 -0.05820 -0.05942 1141 120 1 5 0 47.590 33.50 19.90 25.00 26.38 0.0 990.61 900000 -2442 -940 -2635 -5474 -5859 -5766 -5264 -2980 -2812 -4989 -6176 -4873 -3018 -806 426 923 1439 1310 2012 2583 998 1622 1553 1169 1055 1207 396 -940 -1522 -370 53 876 833 -2607 -4508 -4391 -3484 -1625 -347 -258 -51 58 182 357 897 316 38 -194 -887 122 838 563 1358 1076 885 1268 647 465 201 201 960 1601 2411 2337 379 36 -1201 -870 735 717 1025 820 834 828 -202 -871 -2174 -2755 -1986 -2023 -1563 -1591 -2380 -1463 -732 -60 571 982 1296 892 682 -337 -895 -837 -529 -396 512 1092 372 -174 -768 -1742 -1463 -341 -1222 -903 -823 -582 434 914 1280 837 648 136 -439 -135 -206 245 610 511 261 714 836 391 798 -362 -534 355 110 52 -126 -424 -619 -45 86 -6 392 545 148 -155 -402 -1157 900000 -260 -107 -307 -593 -574 -572 -574 -362 -379 -709 -879 -748 -492 -151 92 200 326 315 503 669 265 424 429 323 308 366 119 -266 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