File name: Pandora260s1_CameronLA_20231101_L2Fit_fout2c3d20230417p1-8.txt File generation date: 20241203T160401.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v3d20230417.txt Level 1 file used: Pandora260s1_CameronLA_20231101_L1_smca1c3d20230417p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20231101 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1217 305.2623 305.4028 305.5434 305.6839 305.8244 305.9649 306.1054 306.2459 306.3864 306.5268 306.6673 306.8077 306.9482 307.0886 307.2290 307.3694 307.5098 307.6501 307.7905 307.9308 308.0712 308.2115 308.3518 308.4921 308.6324 308.7727 308.9130 309.0532 309.1935 309.3337 309.4739 309.6141 309.7544 309.8945 310.0347 310.1749 310.3150 310.4552 310.5953 310.7354 310.8755 311.0156 311.1557 311.2958 311.4359 311.5759 311.7160 311.8560 311.9960 312.1360 312.2760 312.4160 312.5560 312.6959 312.8359 312.9758 313.1158 313.2557 313.3956 313.5355 313.6753 313.8152 313.9551 314.0949 314.2348 314.3746 314.5144 314.6542 314.7940 314.9338 315.0735 315.2133 315.3530 315.4928 315.6325 315.7722 315.9119 316.0516 316.1912 316.3309 316.4705 316.6102 316.7498 316.8894 317.0290 317.1686 317.3082 317.4478 317.5873 317.7269 317.8664 318.0059 318.1455 318.2850 318.4244 318.5639 318.7034 318.8428 318.9823 319.1217 319.2611 319.4005 319.5399 319.6793 319.8187 319.9581 320.0974 320.2367 320.3761 320.5154 320.6547 320.7940 320.9333 321.0725 321.2118 321.3510 321.4903 321.6295 321.7687 321.9079 322.0471 322.1862 322.3254 322.4646 322.6037 322.7428 322.8819 323.0210 323.1601 323.2992 323.4383 323.5773 323.7164 323.8554 323.9944 324.1335 324.2725 324.4114 324.5504 324.6894 324.8283 324.9673 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231101T125533.6Z 8705.538583 249 1 55.10 2 84.73 109.97 49.74 282.59 0.00 1 0.00 1 0 25 6.811e-01 5.250e-02 3.607e-01 1.464e-02 7.636215e-01 9.769368e-03 1.572072e-02 -6.000000e+00 4.314724e-01 225.93 -2.00 3.24 -2.00 322.66 0.00e+00 4.021513e-02 7.859816e-03 2.427292e-02 -6.000000e+00 3.078032e-02 289.89 -2.00 20.00 -2.00 322.24 0.00e+00 9.427 0.010 302.00 328.00 3 8.5145e-01 5.2034e-02 1.4287e-01 -6.0000e+00 1.0568e+00 1.0693e+00 8.0420e-02 1.1328e-01 -6.0000e+00 1.1662e+00 -1.5420e+00 7.3292e-02 6.4166e-02 -6.0000e+00 6.9258e-01 5.7627e-01 3.0697e-02 2.6845e-02 -6.0000e+00 3.1848e-01 9.5027e-06 2.0769e-05 5.0567e-04 7.1497e-04 -6.0000e+00 2.2186e-02 1.7917e-03 0.0000e+00 12 9 8 11 32 0 31.30 24.76 2.11 0.00179 0.00195 32 3 1 5 0 1721.670 33.50 20.00 24.76 8.72 1.7 807.02 252122 52877 900000 900000 900000 900000 -142022 900000 900000 -92559 900000 -48798 900000 900000 31570 278562 900000 900000 900000 900000 900000 900000 900000 -85719 900000 900000 900000 900000 900000 900000 900000 900000 -20304 5259 900000 900000 900000 900000 900000 900000 900000 107909 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900000 900000 900000 3326 4266 3584 5412 1541 407 965 239 3611 3151 -17843 81 1558 1250 6106 5464 3767 8547 6132 -4581 2907 1092 0 -3960 -3402 4105 9220 3336 4735 8560 11102 110 1719 -14075 3680 4358 -7530 9747 1922 -2562 -4450 -9389 2408 1092 -450 -1099 -4301 2143 -7559 3217 -8748 7479 2043 5382 5430 -753 287 -594 7141 -1164 -5382 8338 1136 -435 -4023 -3592 5263 -9855 -5695 1930 5937 5558 484 2954 3573 153 -9583 SS 20231101T130712.7Z 8705.546675 252 1 54.39 2 82.37 111.52 52.13 283.53 0.00 1 0.00 1 0 25 5.032e-01 1.223e-02 2.070e-01 2.572e-03 7.180749e-01 1.410025e-03 7.895559e-03 -6.000000e+00 2.888147e-01 225.93 -2.00 3.24 -2.00 321.41 0.00e+00 -3.089823e-04 7.821803e-04 5.966789e-03 -6.000000e+00 1.572136e-02 289.89 -2.00 20.00 -2.00 320.79 0.00e+00 6.989 0.004 302.00 328.00 3 6.8735e-01 5.2527e-03 8.3895e-02 -6.0000e+00 7.1833e-01 -6.6558e-02 8.0097e-03 5.5953e-02 -6.0000e+00 7.8618e-01 -3.7577e-02 8.5374e-03 2.2591e-02 -6.0000e+00 4.6330e-01 1.5082e-02 3.9141e-03 6.1176e-03 -6.0000e+00 1.9833e-01 1.5191e-04 -2.0947e-04 6.9558e-05 8.3962e-05 -6.0000e+00 1.3770e-02 6.9194e-04 0.0000e+00 12 8 8 10 0 0 30.16 24.76 0.74 0.00069 -0.00088 153 16 1 5 0 355.460 33.50 19.99 24.76 9.35 1.6 812.29 -292043 -146008 900000 900000 900000 900000 -229587 900000 900000 -223949 900000 -237569 15141 16754 -78952 900000 900000 -28836 900000 89289 -51999 -1621 900000 -96731 -22070 19237 900000 26523 900000 -15230 55692 -26457 -28488 -46531 -37299 19133 -16335 30136 21073 18646 28871 -11849 8365 1795 37982 4203 3004 41859 15921 -4926 500 -6588 11254 15879 3606 -4418 3274 -53 4600 1718 -4524 -2089 8429 8639 5276 9766 -3014 2731 1594 2837 906 715 493 754 -1070 -4410 -10199 -7595 -4050 -3262 1648 -1649 -1998 811 205 -1012 1097 1007 1185 5492 -211 -165 154 -2007 -153 173 1930 366 116 -1876 -1623 -2084 -2467 583 -1418 -801 -1067 -1023 586 683 1351 1049 596 468 -519 5 -740 271 579 631 411 927 1397 -718 1238 -998 -1480 496 -116 -607 -637 -626 -510 -481 -284 69 629 728 590 -7 144 -602 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-6.000000e+00 3.859260e-03 289.89 -2.00 20.00 -2.00 319.06 0.00e+00 4.975 0.001 302.00 328.00 3 4.1494e-01 1.0762e-03 5.6359e-02 -6.0000e+00 2.0731e-01 -5.1069e-02 1.3178e-03 2.8077e-02 -6.0000e+00 2.2559e-01 7.4369e-03 1.1378e-03 1.3450e-02 -6.0000e+00 1.3510e-01 -8.6533e-03 5.9370e-04 3.6170e-03 -6.0000e+00 5.8266e-02 1.4786e-03 -4.8671e-05 1.9265e-05 4.1426e-05 -6.0000e+00 3.8510e-03 3.0340e-04 0.0000e+00 11 8 0 10 0 0 7.96 24.72 0.52 0.00030 -0.00006 529 56 1 5 0 102.730 33.50 20.00 24.72 10.58 1.6 821.90 -71256 -64327 -19316 -55857 -29687 -41519 -63685 -14553 -41205 -61413 -23783 -47560 -31673 -24302 -13969 7410 -1306 -10328 -1777 -9844 -13583 -11003 -6237 -11970 -7112 -5519 -129 -11897 -1750 -9893 -4797 -4270 -5441 -9112 -11056 -7610 -8379 -3028 -377 -451 902 -539 659 -108 2610 -16 -403 1419 -859 -482 1304 1001 2662 1979 1704 1645 1104 910 778 298 1425 1948 3796 3751 1276 567 -1182 -649 955 1268 1173 1402 1001 506 -567 -1915 -3302 -3630 -2418 -2136 -1266 -1212 -2145 -1376 -652 146 1022 1333 1597 1362 659 -382 -1118 -1112 -804 -267 576 1112 305 -305 -1097 -1880 -1735 -294 -1360 -1097 -799 -467 452 1123 1196 832 629 97 -546 -141 -269 74 432 312 160 620 1014 351 613 -492 -754 270 -64 -64 -275 -469 -620 -214 -84 -64 419 649 359 160 -79 -675 -448 -897 -851 -170 -655 -248 -410 -893 -146 -613 -1190 -330 -987 -711 -636 -407 201 -43 -407 -69 -439 -638 -509 -300 -676 -414 -335 -7 -732 -96 -657 -361 -372 -551 -978 -1132 -782 -999 -417 -57 -81 176 -114 144 -24 577 -4 -95 340 -219 -131 360 307 876 713 646 652 452 369 308 118 590 828 1798 1973 645 295 -621 -351 534 819 770 949 666 318 -352 -1079 -1782 -2010 -1509 -1470 -935 -1014 -1836 -1235 -627 140 1025 1367 1626 1324 631 -346 -977 -1010 -776 -279 652 1358 400 -392 -1386 -2156 -1946 -341 -1652 -1395 -1020 -635 635 1671 1863 1347 1003 147 -816 -201 -392 114 678 511 259 969 1602 537 897 -733 -1083 405 -99 -106 -478 -858 -1139 -414 -168 -129 866 1370 759 323 -158 -1285 -861 SS 20231101T133034.0Z 8705.562893 260 1 54.31 2 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