File name: Pandora260s1_CameronLA_20240408_L2Fit_fwvt1c1d20230417p1-8.txt File generation date: 20240418T202034.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v1d20230417.txt Level 1 file used: Pandora260s1_CameronLA_20240408_L1_smca1c1d20230417p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20240408 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session and full initial 1.8 lab calibration, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used First and last pixel inside fitting window: 1621 1772 Nominal wavelengths inside fitting window [nm]: 492.0003 492.1207 492.2410 492.3614 492.4817 492.6021 492.7224 492.8427 492.9629 493.0832 493.2034 493.3236 493.4438 493.5640 493.6842 493.8044 493.9245 494.0446 494.1647 494.2848 494.4049 494.5249 494.6449 494.7650 494.8850 495.0049 495.1249 495.2448 495.3648 495.4847 495.6046 495.7245 495.8443 495.9642 496.0840 496.2038 496.3236 496.4434 496.5631 496.6829 496.8026 496.9223 497.0420 497.1616 497.2813 497.4009 497.5206 497.6402 497.7597 497.8793 497.9989 498.1184 498.2379 498.3574 498.4769 498.5963 498.7158 498.8352 498.9546 499.0740 499.1934 499.3128 499.4321 499.5514 499.6707 499.7900 499.9093 500.0286 500.1478 500.2670 500.3862 500.5054 500.6246 500.7437 500.8629 500.9820 501.1011 501.2202 501.3392 501.4583 501.5773 501.6963 501.8153 501.9343 502.0532 502.1722 502.2911 502.4100 502.5289 502.6478 502.7666 502.8855 503.0043 503.1231 503.2419 503.3606 503.4794 503.5981 503.7168 503.8355 503.9542 504.0729 504.1915 504.3102 504.4288 504.5474 504.6659 504.7845 504.9030 505.0216 505.1401 505.2585 505.3770 505.4955 505.6139 505.7323 505.8507 505.9691 506.0875 506.2058 506.3241 506.4425 506.5607 506.6790 506.7973 506.9155 507.0337 507.1520 507.2701 507.3883 507.5065 507.6246 507.7427 507.8608 507.9789 508.0970 508.2150 508.3331 508.4511 508.5691 508.6870 508.8050 508.9229 509.0409 509.1588 509.2767 509.3945 509.5124 509.6302 509.7480 509.8658 509.9836 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-404: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240408T152648.5Z 8864.643617 156 1 21.81 2 45.06 110.93 44.73 112.82 0.00 1 0.00 1 0 22 3.391e-03 3.388e-03 1.422e-03 1.418e-03 4.368416e+03 9.480331e+01 2.980686e+02 -6.000000e+00 2.002166e+02 287.61 -2.00 20.00 -2.00 505.25 0.00e+00 3.978125e-04 4.011362e-05 2.678545e-05 -6.000000e+00 9.781388e-05 287.61 -2.00 20.00 -2.00 500.36 0.00e+00 7.889821e-02 2.867213e-02 3.009520e-02 -6.000000e+00 6.839994e-02 228.99 -2.00 3.24 -2.00 501.96 0.00e+00 1.414 0.000 489.00 513.00 1 7.6349e+00 2.2074e-03 3.3141e-03 -6.0000e+00 5.2693e-03 4.9191e-03 5.5863e-04 7.1909e-04 -6.0000e+00 1.3445e-03 7.6003e-04 1.3296e-03 1.5892e-04 2.6605e-05 -6.0000e+00 3.9777e-04 -5.2667e-02 4.6934e-05 12 1 1 12 33 1 99.98 25.06 2.21 -0.05267 -0.04344 14 4 1 4 0 1453.800 33.75 19.98 25.06 26.25 0.8 936.85 900000 -569 -642 -151 -386 -31 287 271 236 113 -5 116 -145 -334 -236 -490 -294 -21 262 266 51 17 173 402 641 687 129 -97 9 -627 -236 -116 -52 199 608 100 -384 -251 126 -46 217 -170 34 387 475 361 325 334 482 -81 -77 -280 -346 -725 -595 -135 -269 -529 -136 6 173 547 441 665 80 508 629 -74 -378 -33 -303 -179 119 -45 -49 213 -196 -270 -564 -627 -155 -353 -328 -356 -8 -285 -525 -330 -25 69 62 195 256 557 586 156 325 179 -95 -130 -159 -509 -730 -452 105 -113 -622 -441 203 -63 -70 47 -34 150 63 269 256 552 270 334 739 347 42 379 173 162 -178 -32 353 131 141 89 -348 175 554 -311 178 437 -311 -517 -226 141 -42 151 228 114 -243 -65 -607 -499 -205 -348 900000 -558 -640 -154 -397 -33 300 287 252 121 -6 121 -149 -348 -243 -504 -303 -22 273 282 53 18 183 424 677 727 136 -103 10 -656 -240 -116 -53 203 633 105 -408 -266 132 -48 222 -175 35 400 496 380 343 350 499 -82 -78 -279 -345 -718 -592 -133 -273 -537 -140 6 177 558 452 681 83 517 631 -74 -372 -32 -298 -175 115 -44 -49 212 -195 -266 -549 -604 -148 -337 -316 -345 -7 -276 -513 -323 -25 68 61 192 254 557 588 155 318 172 -91 -123 -147 -480 -682 -432 100 -111 -611 -432 200 -61 -68 45 -33 149 63 270 254 548 269 331 738 344 41 366 167 156 -173 -31 341 127 136 85 -331 167 520 -294 168 418 -299 -505 -218 137 -41 149 225 113 -240 -63 -584 -481 -195 -332 SQ 20240408T153846.4Z 8864.651926 165 1 54.55 2 42.66 113.44 42.38 115.29 0.00 1 0.00 1 0 15 4.368e-03 4.339e-03 1.278e-03 1.274e-03 5.606589e+03 8.738859e+01 3.831121e+02 -6.000000e+00 2.579230e+02 287.61 -2.00 20.00 -2.00 505.25 0.00e+00 4.670101e-04 3.605887e-05 3.451482e-05 -6.000000e+00 1.259998e-04 287.61 -2.00 20.00 -2.00 500.35 0.00e+00 1.230988e-01 2.578950e-02 3.727002e-02 -6.000000e+00 8.808815e-02 228.99 -2.00 3.24 -2.00 501.95 0.00e+00 1.358 0.000 489.00 513.00 1 8.3071e+00 1.9857e-03 3.8001e-03 -6.0000e+00 6.7864e-03 3.9884e-03 5.0142e-04 8.9778e-04 -6.0000e+00 1.7310e-03 3.8858e-04 8.1751e-04 1.4175e-04 3.3906e-05 -6.0000e+00 5.1233e-04 -5.5012e-02 8.5193e-05 11 9 0 11 32 0 99.96 25.06 2.34 -0.05501 -0.04934 32 3 1 4 0 1704.650 33.75 20.01 25.06 27.10 0.8 944.97 900000 -673 -562 236 45 19 307 75 455 103 213 -131 -136 -487 -486 82 -304 -430 9 350 -352 -39 -62 584 600 865 560 391 -209 -369 -480 152 -269 233 164 -66 -351 197 221 -328 596 -259 -165 366 452 657 162 361 488 -204 39 -484 -288 -1043 -663 144 -388 -545 -387 -149 383 864 605 653 -18 228 78 -107 -499 35 -725 -165 485 -196 187 114 -67 -291 -610 123 -593 -412 -670 -470 176 -603 -487 -275 141 -202 -144 118 410 805 557 306 377 305 -82 -176 66 -744 -821 -789 198 -197 -918 -759 23 -78 -64 115 418 275 60 391 213 610 244 566 1097 200 158 571 289 28 -98 -140 209 413 -22 -134 -195 -389 983 -507 253 483 -120 -878 453 -177 117 242 723 -265 -416 -171 -542 -894 420 -479 900000 -674 -570 237 46 20 324 80 488 110 226 -137 -141 -500 -508 85 -309 -443 10 373 -371 -41 -66 615 634 913 592 411 -217 -388 -492 152 -272 239 173 -69 -372 207 230 -340 608 -267 -171 379 472 690 171 379 505 -208 40 -485 -282 -1019 -649 142 -396 -553 -397 -153 391 879 619 668 -18 232 78 -107 -492 35 -720 -161 472 -194 186 114 -67 -288 -597 118 -570 -396 -649 -457 172 -583 -474 -268 137 -197 -141 116 405 798 555 303 366 290 -78 -164 60 -685 -764 -752 188 -194 -919 -759 23 -76 -63 113 415 269 59 387 213 609 245 566 1081 196 153 559 283 27 -94 -135 200 394 -21 -127 -188 -371 914 -477 238 460 -114 -853 440 -175 116 240 719 -259 -405 -169 -527 -858 394 -453 SQ 20240408T160125.3Z 8864.667654 180 1 18.03 2 38.24 118.79 38.06 120.56 0.00 1 0.00 1 0 15 3.998e-03 3.955e-03 1.604e-03 1.600e-03 3.912040e+03 1.056576e+02 2.867986e+02 -6.000000e+00 2.361008e+02 287.61 -2.00 20.00 -2.00 505.25 0.00e+00 3.856999e-04 4.528547e-05 2.693925e-05 -6.000000e+00 1.153450e-04 287.61 -2.00 20.00 -2.00 500.37 0.00e+00 -2.135656e-03 3.230975e-02 2.339179e-02 -6.000000e+00 8.066038e-02 228.99 -2.00 3.24 -2.00 501.97 0.00e+00 1.272 0.000 489.00 513.00 1 7.6774e+00 2.4881e-03 2.7989e-03 -6.0000e+00 6.2138e-03 5.3662e-03 6.3071e-04 6.0305e-04 -6.0000e+00 1.5856e-03 7.4859e-04 1.0013e-03 1.7970e-04 2.9266e-05 -6.0000e+00 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