File name: Pandora260s1_CameronLA_20240620_L2Fit_fout2c4d20240619p1-8.txt File generation date: 20241203T181249.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v4d20240619.txt Level 1 file used: Pandora260s1_CameronLA_20240620_L1_smca1c4d20240619p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20240620 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0227 305.1633 305.3039 305.4444 305.5849 305.7254 305.8660 306.0064 306.1469 306.2874 306.4279 306.5683 306.7088 306.8492 306.9896 307.1300 307.2704 307.4108 307.5511 307.6915 307.8319 307.9722 308.1125 308.2528 308.3931 308.5334 308.6737 308.8140 308.9542 309.0945 309.2347 309.3750 309.5152 309.6554 309.7956 309.9357 310.0759 310.2161 310.3562 310.4963 310.6365 310.7766 310.9167 311.0568 311.1968 311.3369 311.4770 311.6170 311.7570 311.8971 312.0371 312.1771 312.3171 312.4570 312.5970 312.7369 312.8769 313.0168 313.1567 313.2966 313.4365 313.5764 313.7163 313.8562 313.9960 314.1358 314.2757 314.4155 314.5553 314.6951 314.8349 314.9746 315.1144 315.2541 315.3939 315.5336 315.6733 315.8130 315.9527 316.0924 316.2321 316.3717 316.5114 316.6510 316.7906 316.9302 317.0698 317.2094 317.3490 317.4886 317.6281 317.7676 317.9072 318.0467 318.1862 318.3257 318.4652 318.6047 318.7441 318.8836 319.0230 319.1624 319.3018 319.4412 319.5806 319.7200 319.8594 319.9987 320.1381 320.2774 320.4167 320.5560 320.6953 320.8346 320.9739 321.1132 321.2524 321.3917 321.5309 321.6701 321.8093 321.9485 322.0877 322.2269 322.3660 322.5052 322.6443 322.7834 322.9226 323.0617 323.2007 323.3398 323.4789 323.6179 323.7570 323.8960 324.0350 324.1741 324.3131 324.4520 324.5910 324.7300 324.8689 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240620T125645.1Z 8937.539411 214 1 9.25 2 69.84 73.86 129.59 258.74 0.00 1 0.00 1 0 25 3.855e-02 1.228e-02 2.232e-02 4.035e-03 3.623648e-01 2.043551e-03 4.050483e-03 -6.000000e+00 2.199431e-02 230.79 -2.00 3.24 -2.00 318.09 0.00e+00 4.514197e-04 3.750459e-04 9.042244e-04 -6.000000e+00 9.961380e-04 293.01 -2.00 20.00 -2.00 317.19 0.00e+00 2.870 0.000 302.00 328.00 3 3.8063e+00 5.5210e-03 3.3724e-02 -6.0000e+00 5.4901e-02 9.9042e-03 6.2667e-03 1.8011e-02 -6.0000e+00 5.9200e-02 3.0132e-03 4.0436e-03 8.5113e-03 -6.0000e+00 3.5388e-02 -7.4280e-03 2.1245e-03 2.3408e-03 -6.0000e+00 1.5399e-02 4.2819e-04 5.8213e-04 1.0867e-04 2.1977e-05 -6.0000e+00 9.7374e-04 1.0186e-05 0.0000e+00 12 9 9 12 33 1 98.41 25.00 0.56 0.00001 0.00438 5 4 1 5 0 1541.250 33.50 20.07 25.00 33.07 0.4 985.17 -266 -11941 -8879 -7053 -10083 -6278 -3677 -10135 18436 -4889 -14949 1227 -9313 -1588 -5643 -1128 4640 5492 -249 3492 -809 745 2059 9098 -1548 -3733 557 10145 -914 8727 -2117 -1819 -3497 15 -12219 -7295 -2343 -3927 966 2140 474 -2075 -156 699 -434 2939 -475 322 -1521 -679 143 804 87 2257 3047 431 -117 698 -131 -96 1450 1732 1657 3023 2280 872 749 -2622 -299 968 362 1244 1289 879 1168 -779 -815 -4186 -4129 -2194 -1951 -1085 -2307 -1930 -1364 442 353 1151 1431 1401 416 -951 -1990 -1793 -2090 -835 103 1912 1399 6 -520 -348 -1472 -1953 -912 -1048 -717 -377 -127 917 1759 2037 1401 1055 -425 -243 -1219 -579 508 582 776 162 629 702 821 216 -770 -815 330 -862 -432 -944 -633 -606 -756 34 -103 1232 840 227 209 -424 -768 -13 -756 -580 -441 -575 -324 -195 -650 1016 -371 -1265 90 -868 -163 -713 -157 657 815 -38 535 -134 121 334 1481 -301 -782 115 1825 -171 1448 -424 -405 -882 4 -3492 -1863 -611 -1204 313 830 212 -931 -72 326 -205 1350 -225 150 -717 -320 71 432 51 1274 1799 268 -75 451 -84 -60 903 1149 1131 2237 1786 658 524 -1838 -212 772 307 1113 1172 778 970 -636 -597 -3179 -2974 -1755 -1677 -1040 -2315 -2024 -1425 490 417 1331 1678 1614 478 -1016 -2091 -1776 -2154 -893 122 2385 1843 9 -679 -439 -1713 -2356 -1119 -1386 -936 -518 -174 1338 2630 3193 2199 1581 -627 -348 -1708 -829 728 897 1186 247 976 1055 1171 311 -1065 -1089 462 -1278 -654 -1513 -1038 -979 -1294 59 -187 2240 1567 421 372 -759 -1323 SS 20240620T131432.6Z 8937.551766 220 1 54.32 2 66.12 75.66 133.21 260.25 0.00 1 0.00 1 0 17 1.502e-02 8.890e-03 5.062e-04 2.063e-04 3.082101e-01 1.049959e-04 3.396175e-03 -6.000000e+00 8.564510e-03 230.79 -2.00 3.24 -2.00 316.71 0.00e+00 7.539045e-04 1.322090e-05 2.385040e-04 -6.000000e+00 3.879654e-04 293.02 -2.00 20.00 -2.00 315.83 0.00e+00 2.452 0.000 302.00 328.00 3 4.7960e-01 2.7543e-04 2.8612e-02 -6.0000e+00 2.1378e-02 -9.5148e-03 3.0774e-04 1.4742e-02 -6.0000e+00 2.3055e-02 1.5066e-04 1.8020e-04 7.1286e-03 -6.0000e+00 1.3781e-02 -3.9604e-03 8.7575e-05 1.9832e-03 -6.0000e+00 5.9945e-03 1.9519e-02 1.5788e-04 5.5067e-06 2.0818e-05 -6.0000e+00 3.7933e-04 2.4813e-03 0.0000e+00 11 8 0 10 0 0 99.91 25.00 0.40 0.00248 0.00367 1408 148 1 5 0 38.570 33.50 20.08 25.00 33.94 0.4 991.80 -651 -909 52 -2718 -5276 -5493 -3845 -2055 -1109 -1716 -3894 -4584 -2789 -1149 530 994 564 1299 1207 2160 2114 663 1566 1446 1111 1088 883 -265 -1400 -1117 435 271 1607 185 -3617 -4357 -4099 -2650 -698 112 -177 -183 157 -42 476 628 20 -39 -611 -770 507 854 837 1406 917 918 1156 544 301 109 395 1259 1780 2563 1608 -114 -213 -1613 -243 808 743 1111 620 910 456 -458 -1102 -2659 -2281 -1805 -1847 -1351 -2026 -2159 -1221 -591 128 501 1160 1142 740 530 -642 -820 -684 -526 -216 881 913 186 -219 -1000 -1623 -962 -435 -1312 -758 -787 -342 636 953 1167 793 532 58 -380 -24 -208 375 578 374 321 855 747 553 622 -615 19 312 -59 47 -432 -357 -573 11 151 -181 638 412 60 -78 -532 -1046 -89 -140 8 -436 -764 -742 -536 -316 -192 -323 -749 -890 -554 -263 129 275 156 371 364 673 682 215 507 468 384 395 329 -95 -472 -388 149 102 617 78 -1503 -1704 -1710 -1185 -350 61 -103 -113 96 -26 295 392 13 -25 -388 -488 318 581 582 993 682 698 865 414 225 83 294 988 1468 2208 1408 -100 -177 -1303 -198 715 693 1061 606 863 424 -402 -935 -2130 -1833 -1563 -1705 -1345 -2088 -2331 -1343 -680 151 598 1401 1357 849 591 -682 -843 -722 -576 -249 1097 1188 243 -279 -1252 -1923 -1141 -528 -1687 -984 -1049 -465 890 1399 1746 1179 768 82 -507 -32 -282 524 830 550 471 1247 1058 763 840 -819 25 417 -82 68 -644 -544 -877 17 248 -303 1079 701 102 -129 -872 -1696 SS 20240620T132403.6Z 8937.558374 227 1 54.30 2 64.11 76.61 135.16 261.06 0.00 1 0.00 1 0 17 1.377e-02 8.884e-03 3.709e-04 1.721e-04 2.872644e-01 8.758787e-05 3.171347e-03 -6.000000e+00 7.853145e-03 230.79 -2.00 3.24 -2.00 316.40 0.00e+00 6.979041e-04 1.026994e-05 1.932960e-04 -6.000000e+00 3.557477e-04 293.02 -2.00 20.00 -2.00 315.53 0.00e+00 2.276 0.000 302.00 328.00 3 3.2462e-01 2.2877e-04 2.6590e-02 -6.0000e+00 1.9603e-02 -7.7913e-03 2.5507e-04 1.3726e-02 -6.0000e+00 2.1140e-02 9.0489e-04 1.4814e-04 6.6369e-03 -6.0000e+00 1.2637e-02 -4.6632e-03 7.0927e-05 1.8445e-03 -6.0000e+00 5.4964e-03 2.7863e-02 9.9350e-05 4.5855e-06 1.9841e-05 -6.0000e+00 3.4783e-04 2.7117e-03 0.0000e+00 11 8 0 10 0 0 88.57 25.01 0.42 0.00271 0.00346 1915 201 1 5 0 28.350 33.50 19.96 25.01 34.73 0.4 997.04 -40 -229 606 -2504 -4438 -4479 -3265 -1358 -303 -1052 -3632 -3814 -2246 -1080 806 1146 536 1150 1208 2095 1994 622 1602 1313 1176 1140 789 -300 -1314 -1109 416 203 1572 47 -3538 -4265 -3750 -2498 -742 177 -308 -272 95 -122 351 521 6 -94 -658 -785 457 791 788 1411 829 927 1148 569 306 148 386 1251 1716 2531 1553 -182 -226 -1619 -221 795 737 1116 602 989 459 -459 -1054 -2600 -2233 -1794 -1896 -1337 -2032 -2144 -1201 -615 136 485 1135 1134 748 564 -625 -823 -631 -466 -219 923 918 216 -189 -1004 -1579 -977 -461 -1325 -728 -777 -366 594 950 1132 801 555 52 -370 -29 -227 343 574 341 319 835 713 535 619 -604 47 302 -37 61 -412 -363 -542 30 111 -177 622 399 63 -83 -546 -1052 -7 -41 113 -464 -797 -747 -563 -257 -59 -225 -793 -831 -540 -277 220 353 176 366 403 721 711 223 571 469 446 454 322 -118 -482 -417 153 82 646 21 -1563 -1771 -1654 -1186 -396 102 -192 -178 62 -81 231 345 4 -61 -421 -520 299 538 571 1035 641 702 891 448 237 113 297 1017 1464 2250 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