File name: Pandora260s1_CameronLA_20240708_L2Fit_fwvt1c4d20240619p1-8.txt File generation date: 20241203T181856.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v4d20240619.txt Level 1 file used: Pandora260s1_CameronLA_20240708_L1_smca1c4d20240619p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20240708 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1622 1772 Nominal wavelengths inside fitting window [nm]: 492.1084 492.2288 492.3492 492.4696 492.5900 492.7103 492.8306 492.9510 493.0713 493.1915 493.3118 493.4320 493.5523 493.6725 493.7927 493.9129 494.0330 494.1532 494.2733 494.3934 494.5135 494.6336 494.7536 494.8737 494.9937 495.1137 495.2337 495.3536 495.4736 495.5935 495.7135 495.8334 495.9532 496.0731 496.1930 496.3128 496.4326 496.5524 496.6722 496.7920 496.9117 497.0314 497.1512 497.2709 497.3905 497.5102 497.6298 497.7495 497.8691 497.9887 498.1083 498.2278 498.3474 498.4669 498.5864 498.7059 498.8254 498.9448 499.0643 499.1837 499.3031 499.4225 499.5418 499.6612 499.7805 499.8998 500.0191 500.1384 500.2577 500.3769 500.4962 500.6154 500.7346 500.8538 500.9729 501.0921 501.2112 501.3303 501.4494 501.5685 501.6876 501.8066 501.9256 502.0446 502.1636 502.2826 502.4015 502.5205 502.6394 502.7583 502.8772 502.9961 503.1149 503.2337 503.3526 503.4714 503.5901 503.7089 503.8277 503.9464 504.0651 504.1838 504.3025 504.4211 504.5398 504.6584 504.7770 504.8956 505.0142 505.1327 505.2513 505.3698 505.4883 505.6068 505.7252 505.8437 505.9621 506.0805 506.1989 506.3173 506.4357 506.5540 506.6724 506.7907 506.9090 507.0272 507.1455 507.2637 507.3820 507.5002 507.6184 507.7365 507.8547 507.9728 508.0909 508.2090 508.3271 508.4452 508.5632 508.6813 508.7993 508.9173 509.0353 509.1532 509.2712 509.3891 509.5070 509.6249 509.7428 509.8606 509.9785 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240708T130338.3Z 8955.544194 88 1 53.68 2 69.57 75.24 98.53 62.41 0.00 1 0.00 1 0 15 3.362e-03 3.339e-03 7.715e-04 7.698e-04 8.095130e+03 5.540113e+01 5.353790e+02 -6.000000e+00 2.028934e+02 293.96 -2.00 20.00 -2.00 505.28 0.00e+00 4.774236e-04 2.218039e-05 3.898600e-05 -6.000000e+00 9.840796e-05 293.96 -2.00 20.00 -2.00 500.42 0.00e+00 3.127386e-01 1.546611e-02 4.804983e-02 -6.000000e+00 6.733908e-02 230.27 -2.00 3.24 -2.00 502.02 0.00e+00 2.835 0.000 489.00 513.00 1 6.9445e+00 1.1945e-03 5.8349e-03 -6.0000e+00 5.2035e-03 4.1929e-03 2.9901e-04 1.1853e-03 -6.0000e+00 1.3197e-03 1.2072e-03 7.0936e-04 8.3459e-05 3.8957e-05 -6.0000e+00 3.9063e-04 -1.4211e-03 3.8915e-05 10 0 0 10 0 0 99.94 25.05 2.04 -0.00142 0.00350 41 4 1 4 0 1309.080 33.50 19.98 25.05 34.27 0.3 990.88 -757 -638 -106 -126 206 523 270 225 160 182 14 -133 -230 -363 -258 -468 -164 30 -35 -54 119 89 287 472 617 335 165 -141 -220 -181 -80 -165 73 548 -73 -151 -87 223 -105 236 40 29 446 379 607 229 371 183 -257 -317 -418 -547 -991 -456 16 -294 -2 -84 -204 203 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236 290 402 121 -130 -344 -507 -626 15 -422 SQ 20240708T131731.0Z 8955.553832 94 1 28.49 2 66.65 76.67 95.95 64.27 0.00 1 0.00 1 0 22 2.954e-03 2.940e-03 1.291e-04 1.288e-04 6.990211e+03 9.105358e+00 4.641003e+02 -6.000000e+00 1.782933e+02 293.96 -2.00 20.00 -2.00 505.27 0.00e+00 4.184681e-04 3.706769e-06 3.440518e-05 -6.000000e+00 8.647946e-05 293.96 -2.00 20.00 -2.00 500.45 0.00e+00 1.937962e-01 2.583098e-03 4.221135e-02 -6.000000e+00 5.919803e-02 230.27 -2.00 3.24 -2.00 502.04 0.00e+00 2.504 0.000 489.00 513.00 1 2.8829e+00 1.9948e-04 5.1368e-03 -6.0000e+00 4.5741e-03 2.6062e-03 5.0005e-05 1.0366e-03 -6.0000e+00 1.1607e-03 7.4358e-02 1.1750e-03 1.4091e-05 3.4870e-05 -6.0000e+00 3.4333e-04 1.3580e-03 -6.7299e-06 10 0 0 10 0 0 99.98 25.02 2.03 0.00136 0.00951 594 62 1 4 0 47.950 33.50 19.92 25.02 34.47 0.3 992.43 -517 -292 -217 -225 79 397 450 340 321 231 66 -161 -231 -273 -372 -371 -85 92 -47 -87 71 186 297 476 424 340 224 -9 -225 -268 -283 -205 174 321 -60 -157 1 37 -70 1 66 99 207 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173 238 85 -119 -238 -303 -304 -63 7 -182 -58 58 148 162 309 333 225 60 -144 -372 -455 -386 -269 SQ 20240708T131747.5Z 8955.554022 94 2 4.18 2 66.60 76.70 95.90 64.30 0.00 1 0.00 1 0 22 2.989e-03 2.975e-03 3.103e-04 3.097e-04 7.029091e+03 2.188553e+01 4.656673e+02 -6.000000e+00 1.803739e+02 293.96 -2.00 20.00 -2.00 505.28 0.00e+00 4.265543e-04 8.911225e-06 3.492828e-05 -6.000000e+00 8.748724e-05 293.96 -2.00 20.00 -2.00 500.46 0.00e+00 1.892514e-01 6.208203e-03 4.273274e-02 -6.000000e+00 5.987957e-02 230.27 -2.00 3.24 -2.00 502.05 0.00e+00 2.498 0.000 489.00 513.00 1 2.7056e+00 4.7943e-04 5.1608e-03 -6.0000e+00 4.6268e-03 2.0128e-03 1.2016e-04 1.0464e-03 -6.0000e+00 1.1739e-03 8.8866e-02 9.7277e-04 3.3864e-05 3.4558e-05 -6.0000e+00 3.4731e-04 1.7434e-03 1.5260e-06 12 1 1 12 1 1 89.11 25.02 2.02 0.00174 0.00849 86 62 1 4 0 47.950 33.50 19.92 25.02 34.47 0.3 992.43 -514 -314 -225 -221 100 391 491 307 260 195 106 -102 -184 -289 -433 -327 -65 83 -28 -100 65 152 364 464 473 287 268 -27 -199 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