File name: Pandora260s1_CameronLA_20240821_L2Fit_fout2c1d20230417p1-8.txt File generation date: 20240907T052443.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v1d20230417.txt Level 1 file used: Pandora260s1_CameronLA_20240821_L1_smca1c1d20230417p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20240821 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session and full initial 1.8 lab calibration, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0364 305.1770 305.3177 305.4583 305.5989 305.7394 305.8800 306.0206 306.1611 306.3016 306.4422 306.5827 306.7232 306.8637 307.0041 307.1446 307.2851 307.4255 307.5659 307.7064 307.8468 307.9872 308.1276 308.2679 308.4083 308.5487 308.6890 308.8293 308.9696 309.1100 309.2503 309.3905 309.5308 309.6711 309.8113 309.9516 310.0918 310.2320 310.3722 310.5124 310.6526 310.7928 310.9329 311.0731 311.2132 311.3533 311.4934 311.6335 311.7736 311.9137 312.0538 312.1938 312.3339 312.4739 312.6139 312.7539 312.8939 313.0339 313.1739 313.3139 313.4538 313.5937 313.7337 313.8736 314.0135 314.1534 314.2933 314.4331 314.5730 314.7128 314.8527 314.9925 315.1323 315.2721 315.4119 315.5517 315.6915 315.8312 315.9709 316.1107 316.2504 316.3901 316.5298 316.6695 316.8092 316.9488 317.0885 317.2281 317.3677 317.5074 317.6470 317.7865 317.9261 318.0657 318.2053 318.3448 318.4843 318.6239 318.7634 318.9029 319.0423 319.1818 319.3213 319.4607 319.6002 319.7396 319.8790 320.0184 320.1578 320.2972 320.4366 320.5759 320.7153 320.8546 320.9939 321.1332 321.2725 321.4118 321.5511 321.6904 321.8296 321.9688 322.1081 322.2473 322.3865 322.5257 322.6649 322.8040 322.9432 323.0823 323.2215 323.3606 323.4997 323.6388 323.7779 323.9170 324.0560 324.1951 324.3341 324.4731 324.6122 324.7512 324.8901 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240821T124321.2Z 8999.530107 241 1 22.07 2 78.17 83.02 78.67 258.39 0.00 1 0.00 1 0 25 3.277e-01 1.318e-02 2.055e-01 4.858e-03 5.536768e-01 2.634973e-03 6.102199e-03 -6.000000e+00 1.903677e-01 229.30 -2.00 3.24 -2.00 320.43 0.00e+00 -1.337879e-03 1.055310e-03 2.657380e-03 -6.000000e+00 1.048129e-02 294.48 -2.00 20.00 -2.00 319.66 0.00e+00 4.724 0.001 302.00 328.00 3 3.1076e+00 8.3416e-03 5.5786e-02 -6.0000e+00 4.7551e-01 -1.3616e-01 1.0906e-02 3.2959e-02 -6.0000e+00 5.1594e-01 6.2741e-02 1.0311e-02 1.3613e-02 -6.0000e+00 3.0674e-01 -2.4565e-02 5.2169e-03 5.5180e-03 -6.0000e+00 1.3616e-01 1.2823e-04 4.7060e-04 1.3561e-04 3.5545e-05 -6.0000e+00 8.8252e-03 -1.9643e-02 0.0000e+00 12 9 9 12 33 1 83.12 25.07 0.90 -0.01964 -0.01611 14 4 1 5 0 1471.020 33.50 19.96 25.07 31.21 0.4 967.89 900000 900000 -116605 900000 -62975 900000 -181256 215292 900000 14467 900000 900000 57036 900000 7985 36482 900000 900000 11664 18648 35583 25339 76890 43394 -9225 18562 82798 900000 85798 17934 10590 8852 -4122 -19780 -31988 -35864 46885 14522 21317 17436 -4161 -3475 -7945 770 -7095 8677 7141 -4432 11312 22341 5758 -2266 -9364 3392 5710 -749 -5602 5067 -2743 202 1049 -942 1576 3399 3442 3973 3357 -4405 3489 2358 -1225 -235 1746 766 -1198 -843 -1231 -7182 -4070 -2982 -1619 -49 -1628 -2759 -108 -876 848 873 1703 1205 5266 -634 15 209 -982 848 924 1455 278 -699 -1654 -227 -2358 -2765 674 -943 -80 -660 -899 536 1109 772 621 242 351 -468 -411 -289 590 -34 1142 670 626 347 589 282 -1554 -1207 163 -492 -380 -1401 -628 -143 -446 49 396 1361 561 693 -178 -498 -719 900000 900000 -1203 900000 -387 900000 -3506 1018 900000 68 900000 900000 270 900000 87 362 900000 900000 204 326 555 443 836 739 -297 491 1213 900000 1136 475 345 347 -214 -1356 -2435 -2713 1685 851 1451 1533 -529 -478 -1213 112 -1124 1198 1020 -723 1631 3021 1007 -485 -2157 754 1340 -197 -1623 1348 -775 54 281 -277 509 1223 1343 1513 1232 -1757 1366 1082 -666 -124 922 431 -643 -406 -540 -3223 -1868 -1580 -913 -31 -1183 -2158 -88 -716 724 779 1532 1073 4583 -543 12 162 -828 741 927 1547 335 -882 -2018 -250 -2580 -2929 745 -1060 -93 -824 -1205 728 1666 1175 964 366 534 -672 -577 -419 900 -52 1784 1096 992 536 868 402 -2158 -1638 238 -816 -650 -2599 -1137 -269 -901 99 832 2890 1226 1487 -366 -1032 -1422 SS 20240821T124825.8Z 8999.533631 244 1 54.50 2 77.08 83.62 79.70 259.06 0.00 1 0.00 1 0 17 3.411e-01 1.065e-02 1.478e-01 2.289e-03 5.192682e-01 1.180723e-03 5.732132e-03 -6.000000e+00 1.938283e-01 229.30 -2.00 3.24 -2.00 319.97 0.00e+00 -2.939060e-04 4.029259e-04 2.019592e-03 -6.000000e+00 8.921029e-03 294.48 -2.00 20.00 -2.00 319.14 0.00e+00 4.353 0.001 302.00 328.00 3 2.9732e+00 3.5422e-03 5.0930e-02 -6.0000e+00 4.8177e-01 -7.5249e-02 4.4035e-03 2.8480e-02 -6.0000e+00 5.2016e-01 1.9690e-02 3.8471e-03 1.2618e-02 -6.0000e+00 3.1150e-01 -1.2576e-02 2.0089e-03 3.9966e-03 -6.0000e+00 1.3690e-01 2.1058e-04 4.3852e-04 6.1483e-05 3.4505e-05 -6.0000e+00 8.7325e-03 -1.9377e-02 0.0000e+00 12 8 8 10 0 0 99.73 25.07 0.68 -0.01938 -0.01608 53 6 1 5 0 1028.230 33.50 19.98 25.07 31.43 0.4 969.99 900000 -42154 -116201 51001 -68581 14605 205726 -70190 56510 -16682 -14144 29665 3238 22056 -7133 -5452 257069 56846 -12680 18562 8707 -4669 3445 15770 -19449 -3453 9926 60817 17851 75307 1658 7737 -6575 -10762 -17561 -20434 13540 -1313 7117 7208 -3204 -114 -3898 -71 315 5253 -940 -95 2560 6035 74 -2130 -2169 -1759 2105 1400 -1283 3157 -2909 -176 -1404 -900 2071 3093 3030 2380 3285 -3687 1471 1731 311 877 1424 943 -683 -882 -1884 -5578 -4252 -2249 -2132 -643 -1074 -1671 -241 79 198 1202 1246 1189 4031 265 -391 -311 -512 188 -26 1313 214 -489 -1108 -949 -1462 -2047 140 -1664 -1126 -780 -722 776 920 1252 653 248 137 -717 374 -330 447 47 414 413 777 745 372 360 -1140 -541 218 -173 -233 -974 -516 -517 -240 339 46 814 591 229 162 -612 -441 900000 -433 -2749 228 -918 81 459 -1143 303 -208 -180 258 44 310 -166 -150 574 1028 -501 572 311 -192 135 602 -1163 -190 498 1792 765 1832 95 490 -555 -1059 -1807 -2057 1049 -138 850 1060 -550 -21 -771 -14 62 1006 -194 -20 531 1255 18 -587 -654 -576 712 498 -489 1172 -1125 -65 -528 -362 906 1384 1463 1128 1468 -1763 705 955 198 549 901 629 -432 -505 -984 -2900 -2287 -1376 -1409 -479 -897 -1383 -209 74 196 1235 1301 1221 3781 239 -357 -275 -449 186 -28 1571 272 -646 -1408 -1179 -1647 -2241 162 -2113 -1394 -1022 -1011 1104 1446 1988 1057 391 215 -1060 534 -490 699 75 673 659 1268 1182 565 527 -1721 -793 324 -290 -404 -1729 -949 -993 -465 701 99 1686 1252 479 339 -1227 -886 SS 20240821T125350.0Z 8999.537384 247 1 8.50 2 75.92 84.26 80.80 259.77 0.00 1 0.00 1 0 17 2.375e-01 1.356e-02 1.450e-01 6.358e-03 4.762083e-01 3.237171e-03 5.401364e-03 -6.000000e+00 1.349187e-01 229.30 -2.00 3.24 -2.00 319.61 0.00e+00 1.571988e-05 9.680148e-04 2.108792e-03 -6.000000e+00 6.189593e-03 294.48 -2.00 20.00 -2.00 318.74 0.00e+00 4.016 0.001 302.00 328.00 3 3.3423e+00 9.3884e-03 4.7068e-02 -6.0000e+00 3.3536e-01 -4.2063e-02 1.1294e-02 2.6677e-02 -6.0000e+00 3.6192e-01 -1.9937e-02 9.0258e-03 1.1491e-02 -6.0000e+00 2.1683e-01 7.3873e-03 4.7897e-03 3.6042e-03 -6.0000e+00 9.4726e-02 2.0813e-04 5.2569e-04 1.7125e-04 3.1099e-05 -6.0000e+00 6.0269e-03 -2.0020e-02 0.0000e+00 12 9 9 12 33 1 78.20 25.06 0.13 -0.02002 -0.01607 5 4 1 5 0 1416.100 33.75 20.08 25.06 31.66 0.4 971.41 147686 -75809 -91648 -65792 -74080 30407 1490 -61603 -37330 -51662 -33460 458 -21308 70691 -7312 -20970 97992 29559 -9736 19283 3491 -7614 -12704 822 -12199 2282 13718 22831 27106 39810 4618 -1057 -3969 2115 -14642 -4361 -6302 582 3559 917 783 64 -1838 -1861 2558 -1071 2055 -602 7103 2916 -1912 -1602 -5026 413 5555 2946 -2488 4103 -522 540 -577 -288 1732 2329 3385 3105 4132 -1584 1502 1377 -18 762 2095 570 765 -2430 -1164 -5127 -5317 -2744 -793 -968 -1435 -3053 -1224 -96 -76 898 1187 756 3366 230 -664 -1051 -1327 -449 1348 1528 1094 -825 -2171 -172 -1265 -1911 -562 -2334 160 -1677 -1202 1154 1079 1429 745 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