File name: Pandora260s1_CameronLA_20241006_L2Fit_fout2c6d20240924p1-8.txt File generation date: 20241220T105550.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v6d20240924.txt Level 1 file used: Pandora260s1_CameronLA_20241006_L1_smca1c6d20240924p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20241006 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: redo SO2 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0223 305.1628 305.3034 305.4439 305.5844 305.7249 305.8654 306.0059 306.1464 306.2868 306.4273 306.5677 306.7081 306.8485 306.9889 307.1293 307.2697 307.4101 307.5505 307.6908 307.8311 307.9715 308.1118 308.2521 308.3924 308.5327 308.6729 308.8132 308.9534 309.0937 309.2339 309.3741 309.5143 309.6545 309.7947 309.9349 310.0750 310.2152 310.3553 310.4954 310.6355 310.7756 310.9157 311.0558 311.1959 311.3359 311.4760 311.6160 311.7560 311.8961 312.0361 312.1760 312.3160 312.4560 312.5960 312.7359 312.8758 313.0158 313.1557 313.2956 313.4355 313.5753 313.7152 313.8550 313.9949 314.1347 314.2745 314.4144 314.5542 314.6939 314.8337 314.9735 315.1132 315.2530 315.3927 315.5324 315.6721 315.8118 315.9515 316.0912 316.2308 316.3705 316.5101 316.6498 316.7894 316.9290 317.0686 317.2082 317.3477 317.4873 317.6268 317.7664 317.9059 318.0454 318.1849 318.3244 318.4639 318.6034 318.7428 318.8823 319.0217 319.1611 319.3005 319.4399 319.5793 319.7187 319.8581 319.9974 320.1367 320.2761 320.4154 320.5547 320.6940 320.8333 320.9726 321.1118 321.2511 321.3903 321.5295 321.6688 321.8080 321.9471 322.0863 322.2255 322.3647 322.5038 322.6429 322.7821 322.9212 323.0603 323.1994 323.3384 323.4775 323.6166 323.7556 323.8946 324.0337 324.1727 324.3117 324.4506 324.5896 324.7286 324.8675 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241006T125640.8Z 9045.539361 59 1 54.43 2 80.62 101.84 122.37 99.83 0.00 1 0.00 1 0 17 2.543e-01 8.318e-03 1.596e-01 1.600e-03 6.281616e-01 8.497506e-04 6.883183e-03 -6.000000e+00 1.447413e-01 227.39 -2.00 3.24 -2.00 320.61 0.00e+00 -3.297328e-04 3.605935e-04 2.732399e-03 -6.000000e+00 7.022825e-03 291.99 -2.00 20.00 -2.00 319.90 0.00e+00 5.834 0.002 302.00 328.00 3 8.1653e-01 2.7219e-03 6.6686e-02 -6.0000e+00 3.5906e-01 -8.0502e-02 3.6625e-03 3.5545e-02 -6.0000e+00 3.8895e-01 4.0164e-02 3.6520e-03 1.6140e-02 -6.0000e+00 2.3108e-01 -2.4997e-02 1.8155e-03 4.9516e-03 -6.0000e+00 1.0169e-01 4.0955e-04 1.2450e-04 4.2326e-05 5.0490e-05 -6.0000e+00 6.5504e-03 -1.7426e-04 0.0000e+00 11 9 0 11 32 0 4.07 25.04 0.59 -0.00017 0.00076 204 21 1 5 0 266.790 33.50 20.01 25.04 28.03 0.5 944.72 900000 -94523 -59833 76542 -36075 900000 -85682 -23760 900000 23438 -69099 900000 -60388 -2038 -43164 -13366 160348 80177 -9198 42610 31733 -11270 -5106 4230 -35732 -10366 -4252 46872 8904 77100 -6248 3782 -18736 -12330 -24088 -14437 12960 -8840 1094 2520 3475 -792 -5064 -2558 -3025 6673 -1037 -4413 3942 3384 653 570 -3372 2729 1736 3279 -1896 1911 -460 1504 -1303 818 1685 3995 3111 773 1802 -2112 597 2126 59 1156 1179 1063 112 -1463 -2350 -4133 -3439 -2589 -2935 -379 -1392 -1995 -794 -37 544 1314 1686 1583 2602 228 -835 -468 -1416 -396 56 1642 737 -269 -943 -1205 -1164 -1313 -4 -1396 -916 -365 -224 495 1011 998 704 302 233 -621 71 -137 534 239 -27 229 872 764 -254 166 -1206 -442 145 -224 -378 -603 -416 -661 -350 14 -186 921 733 217 32 -196 -339 900000 -427 -215 119 -96 900000 -401 -70 900000 58 -463 900000 -508 -12 -505 -144 350 437 -136 405 356 -197 -88 75 -1053 -259 -105 687 183 829 -182 121 -888 -625 -1356 -707 525 -528 74 209 335 -87 -623 -320 -385 791 -136 -618 533 488 107 97 -665 558 390 766 -491 487 -118 368 -331 220 509 1354 1170 295 660 -819 242 903 29 609 633 551 55 -651 -1046 -1826 -1480 -1305 -1763 -237 -994 -1532 -642 -30 463 1159 1508 1394 2136 178 -672 -370 -1138 -364 55 1848 889 -342 -1155 -1358 -1251 -1349 -4 -1665 -1067 -451 -298 685 1480 1591 1156 488 358 -906 107 -202 828 396 -44 378 1377 1175 -379 252 -1785 -638 215 -382 -681 -1123 -814 -1298 -735 30 -416 2069 1612 492 70 -420 -688 SS 20241006T130531.7Z 9045.545506 64 1 54.26 2 78.75 103.01 120.56 100.72 0.00 1 0.00 1 0 17 1.597e-01 8.350e-03 2.329e-02 9.064e-04 5.488070e-01 4.634095e-04 6.046919e-03 -6.000000e+00 9.001514e-02 227.39 -2.00 3.24 -2.00 319.80 0.00e+00 7.762124e-04 1.487787e-04 1.758035e-03 -6.000000e+00 4.109536e-03 291.99 -2.00 20.00 -2.00 319.01 0.00e+00 4.946 0.001 302.00 328.00 3 6.5931e-01 1.3533e-03 5.6219e-02 -6.0000e+00 2.2295e-01 -3.6881e-02 1.6584e-03 2.8333e-02 -6.0000e+00 2.4103e-01 -3.6744e-03 1.4314e-03 1.3527e-02 -6.0000e+00 1.4439e-01 -5.1836e-03 7.5251e-04 3.7182e-03 -6.0000e+00 6.3249e-02 1.1690e-03 6.4530e-05 2.3621e-05 4.0602e-05 -6.0000e+00 4.0314e-03 -4.8520e-04 0.0000e+00 11 8 0 10 0 0 -1.03 25.05 0.52 -0.00049 -0.00000 365 38 1 5 0 148.640 33.50 20.01 25.05 28.87 0.5 951.39 -74517 -57086 -63846 -39634 -55726 -31349 -48545 -50946 -28899 -42171 -59897 -26254 -40559 -21141 -25352 -18675 1183 1251 -11878 -2171 -3469 -10505 -8940 -5244 -11958 -8658 -3573 1692 -8308 -575 -5353 -4961 -4952 -5473 -10673 -10713 -4018 -7060 -826 -6 108 174 -368 182 -824 2552 -563 -321 761 776 1129 1708 179 2338 1906 2461 1302 1619 184 861 25 1373 2202 3503 2497 340 1011 -1429 199 1471 819 1162 1218 1203 341 -932 -2117 -3378 -3255 -1738 -2006 -1106 -1902 -2018 -1233 -108 341 822 1489 1547 1337 234 -596 -761 -1063 -478 -200 1106 970 -213 -676 -1031 -1428 -1203 -394 -1556 -977 -656 -180 493 925 895 711 287 96 -416 89 -67 371 421 137 217 955 856 145 455 -837 -130 237 -204 -150 -560 -333 -583 -184 47 -141 758 575 15 -112 -257 -488 -869 -671 -886 -434 -650 -274 -545 -675 -358 -667 -1181 -395 -857 -465 -726 -607 36 41 -491 -87 -148 -482 -416 -260 -697 -525 -215 95 -489 -32 -357 -390 -453 -566 -1136 -1082 -410 -870 -118 -1 20 35 -78 40 -184 563 -131 -75 183 195 308 521 56 779 687 921 515 649 73 333 10 574 949 1689 1321 180 508 -738 107 837 535 809 805 824 220 -548 -1228 -1910 -1935 -1102 -1401 -879 -1601 -1807 -1097 -103 343 811 1486 1607 1310 214 -549 -684 -963 -492 -222 1320 1240 -286 -872 -1292 -1615 -1375 -455 -1965 -1218 -867 -242 724 1435 1434 1162 457 152 -618 128 -100 585 677 227 353 1489 1359 221 668 -1251 -189 355 -332 -258 -995 -617 -1089 -364 97 -289 1569 1219 31 -232 -506 -952 SS 20241006T131113.8Z 9045.549465 67 1 54.34 2 77.55 103.78 119.40 101.29 0.00 1 0.00 1 0 17 1.096e-01 8.286e-03 1.150e-02 6.841e-04 5.054655e-01 3.461204e-04 5.540698e-03 -6.000000e+00 6.176757e-02 227.39 -2.00 3.24 -2.00 319.37 0.00e+00 8.091352e-04 9.596739e-05 1.281512e-03 -6.000000e+00 2.819971e-03 291.99 -2.00 20.00 -2.00 318.54 0.00e+00 4.504 0.001 302.00 328.00 3 5.9635e-01 9.8424e-04 5.1118e-02 -6.0000e+00 1.5298e-01 -3.7541e-02 1.1711e-03 2.5261e-02 -6.0000e+00 1.6539e-01 1.2282e-03 9.3372e-04 1.2238e-02 -6.0000e+00 9.9081e-02 -6.7177e-03 4.9800e-04 3.3838e-03 -6.0000e+00 4.3400e-02 1.9723e-03 9.0301e-05 1.7967e-05 3.4868e-05 -6.0000e+00 2.7664e-03 -2.9661e-04 0.0000e+00 11 8 0 10 0 0 -0.40 25.05 0.46 -0.00030 0.00038 490 51 1 5 0 110.880 33.50 19.97 25.05 29.30 0.5 954.58 -49622 -35529 -37538 -20400 -48199 -35206 -36433 -31107 -25132 -25649 -36621 -20998 -29339 -14854 -11284 -8448 -2420 -583 -5176 -1274 -5122 -6033 -5460 -2805 -6172 -4355 -2647 -2140 -5336 -2788 -4729 -1693 -2550 -2693 -7365 -8245 -5614 -4977 -1249 1414 321 -221 310 439 438 2231 784 12 403 317 1050 1412 1283 1892 1650 2024 1182 1035 58 66 -157 1174 1960 3149 2236 167 318 -1213 157 1224 915 1190 946 912 262 -757 -1630 -3112 -2864 -2107 -2087 -1467 -1885 -2120 -1188 -92 414 895 1363 1430 1048 450 -668 -714 -787 -555 -294 998 913 -116 -533 -1145 -1443 -1144 -510 -1462 -925 -736 -174 511 910 1044 705 419 70 -396 34 -68 331 426 275 181 861 800 218 417 -796 -94 396 -86 -182 -446 -302 -594 -135 68 -177 612 531 96 -118 -273 -635 -821 -607 -716 -328 -923 -564 -634 -589 -520 -594 -980 -507 -926 -506 -458 -400 -121 -31 -315 -79 -347 -413 -381 -209 -521 -387 -241 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