File name: Pandora260s1_CameronLA_20241018_L2Fit_fout2c6d20240924p1-8.txt File generation date: 20241220T114201.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v6d20240924.txt Level 1 file used: Pandora260s1_CameronLA_20241018_L1_smca1c6d20240924p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20241018 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: redo SO2 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0223 305.1628 305.3034 305.4439 305.5844 305.7249 305.8654 306.0059 306.1464 306.2868 306.4273 306.5677 306.7081 306.8485 306.9889 307.1293 307.2697 307.4101 307.5505 307.6908 307.8311 307.9715 308.1118 308.2521 308.3924 308.5327 308.6729 308.8132 308.9534 309.0937 309.2339 309.3741 309.5143 309.6545 309.7947 309.9349 310.0750 310.2152 310.3553 310.4954 310.6355 310.7756 310.9157 311.0558 311.1959 311.3359 311.4760 311.6160 311.7560 311.8961 312.0361 312.1760 312.3160 312.4560 312.5960 312.7359 312.8758 313.0158 313.1557 313.2956 313.4355 313.5753 313.7152 313.8550 313.9949 314.1347 314.2745 314.4144 314.5542 314.6939 314.8337 314.9735 315.1132 315.2530 315.3927 315.5324 315.6721 315.8118 315.9515 316.0912 316.2308 316.3705 316.5101 316.6498 316.7894 316.9290 317.0686 317.2082 317.3477 317.4873 317.6268 317.7664 317.9059 318.0454 318.1849 318.3244 318.4639 318.6034 318.7428 318.8823 319.0217 319.1611 319.3005 319.4399 319.5793 319.7187 319.8581 319.9974 320.1367 320.2761 320.4154 320.5547 320.6940 320.8333 320.9726 321.1118 321.2511 321.3903 321.5295 321.6688 321.8080 321.9471 322.0863 322.2255 322.3647 322.5038 322.6429 322.7821 322.9212 323.0603 323.1994 323.3384 323.4775 323.6166 323.7556 323.8946 324.0337 324.1727 324.3117 324.4506 324.5896 324.7286 324.8675 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241018T211322.2Z 9057.884285 5 1 54.29 2 61.69 237.56 123.17 34.67 0.00 1 0.00 1 0 17 1.223e-02 8.236e-03 3.399e-04 1.832e-04 2.546273e-01 9.198313e-05 2.857522e-03 -6.000000e+00 6.861227e-03 226.71 -2.00 3.24 -2.00 315.95 0.00e+00 5.845867e-04 9.880366e-06 1.289550e-04 -6.000000e+00 3.130332e-04 291.02 -2.00 20.00 -2.00 315.16 0.00e+00 2.098 0.000 302.00 328.00 3 6.8431e-01 2.3707e-04 2.4098e-02 -6.0000e+00 1.6973e-02 -1.8305e-02 2.6459e-04 1.2008e-02 -6.0000e+00 1.8376e-02 6.1299e-03 1.5291e-04 5.8784e-03 -6.0000e+00 1.1007e-02 -6.5277e-03 7.2107e-05 1.6688e-03 -6.0000e+00 4.8116e-03 2.4665e-02 1.0316e-05 4.8890e-06 1.8541e-05 -6.0000e+00 3.0893e-04 1.4653e-02 0.0000e+00 11 8 0 10 0 0 97.81 29.63 0.41 0.01465 0.01473 1492 157 1 5 0 36.380 36.50 20.20 29.63 31.36 0.7 977.74 551 289 856 -2518 -4099 -3765 -2423 -1052 -197 -901 -2920 -3238 -1495 -896 825 805 457 1194 1101 1829 1566 394 1746 1466 1116 1137 912 -150 -1170 -605 980 528 1652 -243 -3450 -3684 -3208 -2213 -782 9 -396 -397 -81 -294 332 253 -105 -108 -784 -546 672 778 783 1420 848 914 948 506 204 159 566 1187 1618 2364 1242 -337 -216 -1239 100 697 573 924 453 869 330 -555 -939 -2342 -1805 -1573 -1764 -1309 -2064 -1966 -1035 -557 49 346 1082 954 546 482 -398 -515 -401 -356 -138 1003 763 -60 -326 -868 -1326 -821 -561 -1329 -764 -708 -186 590 881 1012 714 493 139 -184 75 -156 346 439 119 174 786 652 500 504 -384 333 444 -28 12 -330 -186 -434 18 106 -278 577 332 -86 -201 -517 -870 121 66 201 -584 -907 -776 -517 -230 -48 -238 -777 -861 -408 -280 273 281 168 450 433 700 619 155 685 612 494 498 407 -64 -490 -243 409 239 763 -116 -1674 -1682 -1567 -1171 -446 6 -263 -277 -56 -208 231 177 -73 -76 -543 -373 474 569 584 1113 671 735 781 406 167 128 461 991 1418 2155 1142 -303 -183 -1045 85 629 545 927 450 861 320 -507 -822 -1994 -1535 -1395 -1667 -1330 -2162 -2144 -1155 -651 59 421 1330 1151 633 540 -421 -523 -418 -397 -162 1227 974 -78 -413 -1047 -1559 -953 -690 -1684 -979 -929 -254 829 1260 1496 1040 691 188 -241 95 -204 469 613 171 249 1122 903 672 662 -494 420 576 -38 17 -469 -268 -641 28 165 -439 922 534 -139 -315 -804 -1339 SS 20241018T211836.3Z 9057.887920 8 1 54.31 2 62.66 238.52 122.53 35.84 0.00 1 0.00 1 0 17 1.224e-02 8.215e-03 3.000e-04 1.551e-04 2.622579e-01 7.782489e-05 2.939081e-03 -6.000000e+00 6.865856e-03 226.71 -2.00 3.24 -2.00 316.08 0.00e+00 5.790278e-04 8.557293e-06 1.397246e-04 -6.000000e+00 3.131852e-04 291.02 -2.00 20.00 -2.00 315.27 0.00e+00 2.165 0.000 302.00 328.00 3 2.7341e-01 2.0086e-04 2.4852e-02 -6.0000e+00 1.6984e-02 -2.0943e-02 2.2427e-04 1.2359e-02 -6.0000e+00 1.8385e-02 7.0894e-03 1.2996e-04 6.0481e-03 -6.0000e+00 1.1012e-02 -6.8046e-03 6.1746e-05 1.7145e-03 -6.0000e+00 4.8167e-03 3.4449e-02 2.9805e-05 4.1473e-06 1.9047e-05 -6.0000e+00 3.0896e-04 1.1344e-02 0.0000e+00 11 8 0 10 0 0 81.29 28.32 0.42 0.01134 0.01157 2192 230 1 5 0 24.770 36.00 20.02 28.32 32.69 0.5 981.21 220 97 693 -1940 -4194 -3698 -2670 -777 -228 -874 -3422 -3032 -1634 -844 635 915 373 1106 1089 1878 1372 297 1482 1559 936 928 809 -184 -1175 -600 893 403 1669 -168 -3483 -3711 -3301 -2202 -753 27 -325 -456 -11 -294 193 363 -154 -61 -671 -639 631 802 836 1343 777 1027 1044 518 217 233 523 1262 1636 2411 1311 -337 -180 -1221 5 752 575 922 500 866 334 -510 -1036 -2288 -1866 -1598 -1802 -1327 -2066 -1992 -1091 -535 67 344 1072 999 571 470 -394 -475 -415 -379 -97 977 815 -76 -323 -867 -1337 -875 -487 -1332 -796 -711 -195 569 886 1011 726 487 173 -248 85 -156 320 481 149 166 790 649 478 534 -410 334 464 -6 8 -324 -174 -444 12 108 -258 573 317 -81 -199 -527 -861 44 22 150 -444 -858 -701 -525 -168 -52 -214 -849 -746 -443 -245 196 317 128 391 403 716 543 117 582 613 392 407 362 -79 -468 -243 354 174 736 -81 -1626 -1627 -1545 -1115 -412 17 -216 -306 -7 -208 136 256 -107 -41 -450 -424 432 569 630 1026 600 806 839 421 173 183 416 1027 1400 2148 1220 -297 -155 -1014 4 688 555 911 504 847 320 -460 -897 -1925 -1568 -1399 -1738 -1334 -2208 -2155 -1208 -620 80 415 1308 1197 660 525 -427 -495 -431 -420 -113 1192 1039 -99 -410 -1048 -1574 -1014 -598 -1685 -1043 -955 -266 799 1268 1500 1062 687 236 -328 108 -206 436 676 215 239 1133 903 646 706 -532 425 604 -9 11 -464 -253 -662 18 169 -412 927 515 -131 -317 -828 -1339 SS 20241018T212344.4Z 9057.891486 11 1 54.32 2 63.61 239.45 121.88 36.97 0.00 1 0.00 1 0 17 1.245e-02 8.163e-03 3.287e-04 1.616e-04 2.704502e-01 8.099616e-05 3.029927e-03 -6.000000e+00 6.990846e-03 226.71 -2.00 3.24 -2.00 316.23 0.00e+00 6.140148e-04 9.256918e-06 1.529753e-04 -6.000000e+00 3.188302e-04 291.02 -2.00 20.00 -2.00 315.42 0.00e+00 2.237 0.000 302.00 328.00 3 2.7236e-01 2.0948e-04 2.5669e-02 -6.0000e+00 1.7293e-02 -2.1079e-02 2.3404e-04 1.2764e-02 -6.0000e+00 1.8717e-02 6.8620e-03 1.3587e-04 6.2506e-03 -6.0000e+00 1.1211e-02 -6.7150e-03 6.5076e-05 1.7750e-03 -6.0000e+00 4.9060e-03 3.1753e-02 5.7110e-05 4.3101e-06 1.9193e-05 -6.0000e+00 3.1438e-04 8.3947e-03 0.0000e+00 11 8 0 10 0 0 96.50 27.41 0.41 0.00839 0.00882 2109 221 1 5 0 25.750 35.25 19.99 27.41 33.49 0.4 984.52 -59 -90 608 -1823 -4420 -3806 -2718 -725 -185 -1000 -3592 -3383 -1650 -912 542 983 582 1261 1198 1875 1454 367 1419 1425 784 837 761 -270 -1175 -685 896 333 1532 -140 -3575 -3748 -3306 -2327 -757 72 -289 -352 -66 -235 194 351 -133 -182 -699 -713 557 752 782 1331 773 1019 1072 542 222 193 511 1289 1591 2421 1326 -284 -151 -1215 -12 737 587 922 510 821 348 -526 -992 -2292 -1906 -1596 -1816 -1291 -2019 -2035 -1100 -557 34 364 1049 1009 563 471 -418 -504 -432 -380 -101 983 805 -35 -328 -869 -1361 -879 -506 -1342 -816 -724 -212 606 867 992 705 492 143 -235 59 -138 297 460 146 143 784 690 445 524 -436 320 482 8 15 -352 -187 -452 8 104 -240 561 372 -78 -203 -511 -871 -11 -18 129 -381 -829 -716 -489 -143 -41 -224 -820 -768 -412 -244 165 316 198 441 439 668 537 135 521 556 308 344 319 -109 -467 -261 355 136 676 -64 -1591 -1650 -1470 -1120 -411 43 -183 -235 -44 -159 130 236 -89 -124 -469 -474 382 535 568 1018 598 801 864 426 178 152 408 1050 1364 2160 1198 -252 -127 -1020 -10 658 553 918 502 810 337 -479 -840 -1888 -1568 -1414 -1716 -1272 -2119 -2167 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