File name: Pandora260s1_CameronLA_20241021_L2Fit_fout2c4d20240619p1-8.txt File generation date: 20241203T191813.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v4d20240619.txt Level 1 file used: Pandora260s1_CameronLA_20241021_L1_smca1c4d20240619p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20241021 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0227 305.1633 305.3039 305.4444 305.5849 305.7254 305.8660 306.0064 306.1469 306.2874 306.4279 306.5683 306.7088 306.8492 306.9896 307.1300 307.2704 307.4108 307.5511 307.6915 307.8319 307.9722 308.1125 308.2528 308.3931 308.5334 308.6737 308.8140 308.9542 309.0945 309.2347 309.3750 309.5152 309.6554 309.7956 309.9357 310.0759 310.2161 310.3562 310.4963 310.6365 310.7766 310.9167 311.0568 311.1968 311.3369 311.4770 311.6170 311.7570 311.8971 312.0371 312.1771 312.3171 312.4570 312.5970 312.7369 312.8769 313.0168 313.1567 313.2966 313.4365 313.5764 313.7163 313.8562 313.9960 314.1358 314.2757 314.4155 314.5553 314.6951 314.8349 314.9746 315.1144 315.2541 315.3939 315.5336 315.6733 315.8130 315.9527 316.0924 316.2321 316.3717 316.5114 316.6510 316.7906 316.9302 317.0698 317.2094 317.3490 317.4886 317.6281 317.7676 317.9072 318.0467 318.1862 318.3257 318.4652 318.6047 318.7441 318.8836 319.0230 319.1624 319.3018 319.4412 319.5806 319.7200 319.8594 319.9987 320.1381 320.2774 320.4167 320.5560 320.6953 320.8346 320.9739 321.1132 321.2524 321.3917 321.5309 321.6701 321.8093 321.9485 322.0877 322.2269 322.3660 322.5052 322.6443 322.7834 322.9226 323.0617 323.2007 323.3398 323.4789 323.6179 323.7570 323.8960 324.0350 324.1741 324.3131 324.4520 324.5910 324.7300 324.8689 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241021T125945.0Z 9060.541493 247 1 54.34 2 82.20 107.46 42.91 280.71 0.00 1 0.00 1 0 25 4.838e-01 1.345e-02 1.650e-01 3.061e-03 6.678263e-01 1.746062e-03 7.720711e-03 -6.000000e+00 2.840767e-01 226.55 -2.00 3.24 -2.00 321.23 0.00e+00 8.456912e-05 9.042788e-04 5.999793e-03 -6.000000e+00 1.533546e-02 290.78 -2.00 20.00 -2.00 320.62 0.00e+00 6.861 0.004 302.00 328.00 3 1.0455e+00 6.2630e-03 8.1795e-02 -6.0000e+00 7.0657e-01 -4.8172e-02 9.2494e-03 5.3991e-02 -6.0000e+00 7.6990e-01 -4.3154e-02 9.7268e-03 2.0512e-02 -6.0000e+00 4.5280e-01 1.3151e-02 4.5619e-03 6.6187e-03 -6.0000e+00 1.9666e-01 1.2271e-04 5.6271e-05 8.6443e-05 7.7104e-05 -6.0000e+00 1.3502e-02 3.8720e-03 0.0000e+00 12 8 8 10 0 0 73.47 24.71 0.75 0.00387 0.00429 103 11 1 5 0 527.480 33.50 20.00 24.71 19.96 0.8 884.72 900000 -190114 -269432 900000 -214808 900000 900000 900000 900000 -93022 -136415 900000 -191632 900000 900000 44773 900000 900000 -8079 900000 900000 -5124 -15992 900000 -57377 -41098 900000 900000 900000 900000 -30861 40356 -28918 -15855 -24172 -27261 184043 25673 53119 23688 18627 12700 -13877 1754 -1158 30414 2135 -206 52419 39620 6525 -7944 -5854 7062 12669 7608 -4895 8481 -2872 931 -3306 811 3848 4854 8092 7500 6828 -3783 4355 2339 -904 -124 1240 -214 1042 -1260 -3101 -10199 -8017 -3755 -2716 1180 -2732 -2923 -1070 -490 -1728 1331 1504 1216 6912 -517 -1880 1794 587 -4 204 3085 780 -1473 -1603 -862 -2330 -1488 -57 -2261 -1448 -322 -809 745 1332 918 710 -18 938 -705 308 -277 916 69 523 713 982 1225 -518 413 -1405 -1064 90 86 -680 -730 -848 -561 -611 153 32 1265 519 -60 -46 -164 -149 900000 -1080 -3789 900000 -1626 900000 900000 900000 900000 -352 -933 900000 -3192 900000 900000 146 900000 900000 -65 900000 900000 -46 -166 900000 -1143 -758 900000 900000 900000 900000 -643 504 -860 -472 -769 -860 766 619 1217 909 881 699 -1065 120 -83 1628 156 -16 2541 2333 598 -964 -775 910 1681 1122 -862 1334 -495 151 -564 144 759 1094 1950 1809 1621 -1025 1175 685 -313 -46 458 -77 344 -421 -963 -3349 -2793 -1360 -1161 565 -1539 -1766 -678 -334 -1162 907 1040 830 4577 -344 -1207 1109 402 -3 174 2984 809 -1627 -1701 -902 -2209 -1340 -55 -2384 -1467 -345 -948 963 1798 1362 1089 -28 1347 -974 415 -389 1354 110 842 1109 1470 1782 -738 565 -1884 -1517 131 144 -1194 -1397 -1610 -1121 -1316 331 71 2860 1206 -138 -99 -357 -308 SS 20241021T131624.1Z 9060.553057 252 1 54.28 2 78.78 109.73 46.34 282.00 0.00 1 0.00 1 0 17 1.202e-01 8.129e-03 2.012e-02 8.633e-04 5.191885e-01 4.383520e-04 5.692723e-03 -6.000000e+00 6.746666e-02 226.55 -2.00 3.24 -2.00 319.67 0.00e+00 8.640125e-04 1.330754e-04 1.436357e-03 -6.000000e+00 3.075190e-03 290.78 -2.00 20.00 -2.00 318.88 0.00e+00 4.959 0.001 302.00 328.00 3 6.4592e-01 1.2647e-03 5.5438e-02 -6.0000e+00 1.6684e-01 -5.0329e-02 1.5309e-03 2.6217e-02 -6.0000e+00 1.8057e-01 1.0541e-02 1.2962e-03 1.2769e-02 -6.0000e+00 1.0816e-01 -1.0934e-02 6.8561e-04 3.5517e-03 -6.0000e+00 4.7363e-02 1.2204e-03 1.3039e-04 2.2779e-05 3.7826e-05 -6.0000e+00 3.0332e-03 3.3882e-03 0.0000e+00 11 8 0 10 0 0 3.56 24.70 0.53 0.00339 0.00437 384 40 1 5 0 141.330 33.25 20.00 24.70 20.91 0.8 893.19 -45281 -35942 -46416 -38617 -47509 -24991 -38676 -48130 -17253 -24432 -21241 -26068 -47517 -22535 -13869 -12971 4702 4982 -7608 -390 -2513 -8698 -4872 -3155 -8927 -7902 -3448 1805 -3730 -430 -4812 -2154 -4957 -4322 -8085 -10082 -4754 -5306 -2547 65 -201 255 -1017 128 891 831 -276 -247 0 899 638 975 203 2257 2465 1332 1416 1528 208 19 614 1438 2401 3003 2412 630 240 -1145 350 1051 1025 1518 703 1026 138 -1010 -1402 -3790 -2688 -1955 -2181 -893 -1885 -2182 -1115 -334 361 886 1422 1337 1115 329 -629 -738 -699 -329 -209 1198 889 -45 -477 -1000 -1601 -1152 -452 -1647 -980 -721 -222 709 869 1179 572 384 -109 -425 100 -93 348 220 -5 185 952 826 217 320 -638 -22 279 -215 -180 -478 -429 -510 -129 50 -176 668 598 73 -41 -247 -640 -499 -430 -676 -520 -632 -255 -488 -770 -235 -399 -349 -478 -1312 -609 -426 -476 162 188 -355 -18 -124 -459 -255 -179 -588 -554 -241 117 -242 -27 -367 -188 -515 -498 -940 -1137 -551 -725 -379 12 -41 57 -242 31 218 207 -71 -64 0 247 192 301 69 819 957 545 603 661 89 8 260 602 1120 1572 1273 355 129 -625 199 638 661 1039 493 693 94 -628 -792 -2111 -1558 -1310 -1603 -696 -1655 -1919 -1033 -332 358 911 1480 1370 1138 313 -566 -687 -654 -330 -228 1472 1167 -58 -626 -1212 -1852 -1283 -540 -2040 -1262 -937 -307 1020 1324 1841 911 618 -166 -636 146 -141 531 359 -8 304 1510 1276 338 478 -923 -32 425 -354 -312 -854 -769 -953 -248 100 -362 1389 1271 153 -83 -490 -1213 SS 20241021T132208.8Z 9060.557046 255 1 54.31 2 77.61 110.53 47.52 282.44 0.00 1 0.00 1 0 25 8.418e-02 8.113e-03 9.690e-03 6.547e-04 4.789860e-01 3.300908e-04 5.281217e-03 -6.000000e+00 4.725253e-02 226.55 -2.00 3.24 -2.00 319.25 0.00e+00 7.845514e-04 8.764396e-05 1.138381e-03 -6.000000e+00 2.153806e-03 290.78 -2.00 20.00 -2.00 318.44 0.00e+00 4.526 0.001 302.00 328.00 3 5.7784e-01 9.2789e-04 5.0616e-02 -6.0000e+00 1.1685e-01 -4.3540e-02 1.0943e-03 2.3758e-02 -6.0000e+00 1.2647e-01 4.0328e-03 8.4984e-04 1.1560e-02 -6.0000e+00 7.5755e-02 -6.7665e-03 4.5451e-04 3.2200e-03 -6.0000e+00 3.3172e-02 2.0450e-03 1.0001e-04 1.7427e-05 3.3824e-05 -6.0000e+00 2.1244e-03 3.3570e-03 0.0000e+00 11 8 0 10 0 0 9.17 24.71 0.50 0.00336 0.00411 520 55 1 5 0 104.430 33.25 20.01 24.71 21.47 0.8 898.63 -27478 -34250 -30200 -13986 -27380 -18335 -36242 -25476 -16565 -24362 -29485 -19221 -25075 -16619 -10518 -5593 -857 1374 -4111 -1007 -1604 -5309 -3958 239 -4307 -3635 -1586 -1813 -3747 -1657 -3406 -1799 -1581 -2168 -7493 -7484 -4544 -3674 -839 359 461 397 0 956 475 1584 207 109 -170 88 892 881 1345 1978 1482 1858 1255 920 -74 -18 316 1044 1774 3169 2400 488 178 -1341 23 1050 822 1121 882 891 172 -810 -1484 -3098 -2532 -1954 -1925 -1229 -1746 -2028 -925 -242 254 698 1334 1410 1024 533 -514 -727 -799 -422 -265 1047 789 -158 -619 -981 -1648 -1068 -560 -1453 -955 -737 -270 537 939 983 709 423 70 -412 -44 -166 345 413 230 196 922 829 222 383 -722 -57 381 -11 -118 -409 -221 -616 -108 94 -243 677 558 3 -85 -346 -672 -463 -728 -671 -263 -528 -308 -782 -566 -389 -686 -900 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