File name: Pandora260s1_CameronLA_20241112_L2Fit_fout2c6d20240924p1-8.txt File generation date: 20241220T115808.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v6d20240924.txt Level 1 file used: Pandora260s1_CameronLA_20241112_L1_smca1c6d20240924p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20241112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: redo SO2 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0223 305.1628 305.3034 305.4439 305.5844 305.7249 305.8654 306.0059 306.1464 306.2868 306.4273 306.5677 306.7081 306.8485 306.9889 307.1293 307.2697 307.4101 307.5505 307.6908 307.8311 307.9715 308.1118 308.2521 308.3924 308.5327 308.6729 308.8132 308.9534 309.0937 309.2339 309.3741 309.5143 309.6545 309.7947 309.9349 310.0750 310.2152 310.3553 310.4954 310.6355 310.7756 310.9157 311.0558 311.1959 311.3359 311.4760 311.6160 311.7560 311.8961 312.0361 312.1760 312.3160 312.4560 312.5960 312.7359 312.8758 313.0158 313.1557 313.2956 313.4355 313.5753 313.7152 313.8550 313.9949 314.1347 314.2745 314.4144 314.5542 314.6939 314.8337 314.9735 315.1132 315.2530 315.3927 315.5324 315.6721 315.8118 315.9515 316.0912 316.2308 316.3705 316.5101 316.6498 316.7894 316.9290 317.0686 317.2082 317.3477 317.4873 317.6268 317.7664 317.9059 318.0454 318.1849 318.3244 318.4639 318.6034 318.7428 318.8823 319.0217 319.1611 319.3005 319.4399 319.5793 319.7187 319.8581 319.9974 320.1367 320.2761 320.4154 320.5547 320.6940 320.8333 320.9726 321.1118 321.2511 321.3903 321.5295 321.6688 321.8080 321.9471 322.0863 322.2255 322.3647 322.5038 322.6429 322.7821 322.9212 323.0603 323.1994 323.3384 323.4775 323.6166 323.7556 323.8946 324.0337 324.1727 324.3117 324.4506 324.5896 324.7286 324.8675 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241112T131634.3Z 9082.553175 151 1 54.17 2 82.57 115.60 140.83 317.37 0.00 1 0.00 1 0 17 5.395e-01 1.153e-02 2.338e-01 3.137e-03 6.778378e-01 1.765152e-03 7.972949e-03 -6.000000e+00 3.147616e-01 225.18 -2.00 3.24 -2.00 321.26 0.00e+00 2.374621e-03 9.228632e-04 6.141231e-03 -6.000000e+00 1.616641e-02 288.83 -2.00 20.00 -2.00 320.67 0.00e+00 7.155 0.004 302.00 328.00 3 7.0633e-01 6.2960e-03 8.3963e-02 -6.0000e+00 7.8202e-01 -1.3477e-03 9.3717e-03 5.2320e-02 -6.0000e+00 8.5291e-01 -5.3259e-02 1.0112e-02 2.2436e-02 -6.0000e+00 5.0101e-01 1.1161e-02 4.7395e-03 5.7754e-03 -6.0000e+00 2.1802e-01 1.2568e-04 -8.9385e-05 8.7205e-05 1.0089e-04 -6.0000e+00 1.4898e-02 -4.0623e-04 0.0000e+00 12 8 8 10 0 0 3.93 24.92 0.71 -0.00041 -0.00108 108 11 1 5 0 501.520 33.50 20.01 24.92 22.01 0.8 900.71 900000 -213156 -254568 900000 -183878 900000 900000 900000 900000 -136688 -113452 900000 -165442 900000 -80276 12031 900000 900000 153764 900000 900000 148961 -17889 17087 -41798 -25819 146921 900000 900000 900000 10303 136724 -28831 -32659 -29079 -60489 193263 -223 24619 67534 8479 21618 -7831 7616 468 27406 2614 -1363 31773 30940 4269 -5125 -4545 10201 12913 12489 -7878 9716 -4011 2089 949 1409 4196 4570 4248 4529 9955 -2625 1544 1172 -2087 -2412 1020 -934 757 -2313 -3660 -8806 -6046 -950 -5377 1612 -157 -1521 -706 -350 -1433 1364 1657 1339 818 300 -302 1315 -413 -402 -163 2940 372 -171 -1417 -547 -1833 -2734 97 -1673 -1083 -1150 366 699 1276 911 922 -117 887 -554 475 -594 652 256 442 557 685 1381 -559 58 -1060 -833 338 74 -898 -835 -507 -615 -621 -108 66 1118 582 -37 -49 -135 61 900000 -1418 -2894 900000 -969 900000 900000 900000 900000 -792 -554 900000 -1917 900000 -686 51 900000 900000 469 900000 900000 454 -180 135 -663 -378 448 900000 900000 900000 135 625 -827 -1116 -949 -2583 707 -7 713 1586 421 1035 -540 472 32 1463 185 -104 1851 1944 391 -591 -581 1245 1670 1710 -1389 1467 -680 325 151 242 804 1011 1047 1115 2268 -696 422 375 -720 -895 372 -335 248 -770 -1126 -2807 -2030 -329 -2330 759 -85 -900 -442 -235 -1037 1003 1134 988 572 197 -190 810 -283 -294 -139 2832 387 -187 -1510 -574 -1738 -2484 92 -1741 -1176 -1236 421 898 1717 1353 1416 -178 1284 -770 642 -842 969 407 716 873 1032 2013 -800 86 -1534 -1188 490 124 -1590 -1613 -1035 -1243 -1351 -236 149 2562 1369 -85 -108 -298 126 SS 20241112T132707.7Z 9082.560506 154 1 54.41 2 80.52 117.06 142.22 320.74 0.00 1 0.00 1 0 17 2.632e-01 8.152e-03 1.256e-01 1.340e-03 5.798754e-01 6.883733e-04 6.413096e-03 -6.000000e+00 1.470714e-01 225.18 -2.00 3.24 -2.00 320.32 0.00e+00 9.746531e-04 2.642404e-04 2.354386e-03 -6.000000e+00 6.679353e-03 288.83 -2.00 20.00 -2.00 319.62 0.00e+00 5.780 0.002 302.00 328.00 3 5.7537e-01 2.1075e-03 6.4544e-02 -6.0000e+00 3.6282e-01 -6.0141e-02 2.7349e-03 3.1399e-02 -6.0000e+00 3.9309e-01 3.4450e-02 2.6358e-03 1.5183e-02 -6.0000e+00 2.3543e-01 -2.3391e-02 1.3354e-03 4.1851e-03 -6.0000e+00 1.0329e-01 5.6968e-04 6.4665e-05 3.5133e-05 5.1497e-05 -6.0000e+00 6.6386e-03 -6.0110e-04 0.0000e+00 11 9 0 11 32 0 14.85 24.95 0.62 -0.00060 -0.00012 254 27 1 5 0 214.170 33.50 20.00 24.95 22.79 0.7 905.66 -41218 -94415 -98483 151527 -52093 -22039 -37186 -47685 68239 -66336 -78705 82834 -75773 -6754 -21151 3122 91480 52995 -12166 25145 -5168 -10019 -13253 -5275 -23559 -14632 4427 30971 -1273 24518 -9519 4204 -11597 -9695 -15632 -15359 2327 -7583 -1058 3032 1309 -961 -3939 -1466 -2742 4326 -1040 -1067 2233 499 -313 -984 -794 1490 2908 3167 -204 1328 302 103 -687 1096 2213 3781 3285 1197 1888 -1315 65 894 340 440 756 1276 318 -881 -2136 -3553 -3281 -2116 -2117 -406 -1490 -1646 -951 -342 191 819 1875 1501 1903 493 -884 -304 -1082 -247 -95 1413 738 -222 -832 -975 -1316 -1327 -264 -1592 -1001 -612 -292 750 1111 1022 742 355 155 -516 -8 -171 316 394 21 270 787 819 -91 98 -938 -474 259 -198 -496 -547 -433 -612 -264 140 -132 806 688 101 -36 -183 -343 -162 -765 -927 198 -286 -86 -185 -305 161 -676 -957 217 -1198 -69 -315 45 622 589 -286 437 -128 -263 -372 -152 -905 -557 146 773 -42 644 -409 189 -717 -667 -1122 -1048 144 -611 -99 337 173 -141 -578 -219 -420 697 -165 -173 365 87 -61 -218 -194 391 813 926 -65 423 95 32 -216 366 827 1455 1390 511 769 -558 29 458 185 256 447 724 170 -465 -1036 -1693 -1655 -1239 -1353 -294 -1140 -1345 -822 -297 175 779 1797 1422 1692 441 -756 -254 -978 -238 -98 1665 931 -294 -1062 -1145 -1478 -1428 -303 -1878 -1229 -798 -385 1084 1695 1608 1198 561 244 -770 -12 -257 502 635 35 436 1287 1304 -140 145 -1425 -704 394 -327 -867 -1033 -817 -1213 -534 302 -285 1756 1533 224 -78 -382 -711 SS 20241112T133544.6Z 9082.566488 159 1 54.33 2 78.87 118.29 143.27 323.65 0.00 1 0.00 1 0 17 1.131e-01 8.220e-03 1.808e-02 8.228e-04 5.159499e-01 4.152826e-04 5.671583e-03 -6.000000e+00 6.318744e-02 225.18 -2.00 3.24 -2.00 319.60 0.00e+00 7.938419e-04 1.250337e-04 1.340840e-03 -6.000000e+00 2.869768e-03 288.83 -2.00 20.00 -2.00 318.85 0.00e+00 4.995 0.001 302.00 328.00 3 4.8127e-01 1.1917e-03 5.5585e-02 -6.0000e+00 1.5588e-01 -3.6561e-02 1.4348e-03 2.5745e-02 -6.0000e+00 1.6889e-01 7.6747e-03 1.2071e-03 1.2641e-02 -6.0000e+00 1.0115e-01 -9.9635e-03 6.4078e-04 3.5728e-03 -6.0000e+00 4.4374e-02 1.3825e-03 4.8825e-05 2.1676e-05 3.8002e-05 -6.0000e+00 2.8523e-03 -3.4349e-04 0.0000e+00 11 8 0 10 0 0 2.28 24.92 0.50 -0.00034 0.00002 411 43 1 5 0 132.170 33.50 20.02 24.92 23.30 0.7 909.67 -55704 -36849 -44375 -14809 -32925 -35680 -32765 -40589 -23619 -26017 -40200 -18591 -36641 -11450 -12223 -3834 7807 5196 -6025 1175 -3054 -3846 -5988 -6152 -8810 -3284 -2592 -491 -7929 484 -5913 -2222 -2376 -4902 -9527 -10525 -4459 -5622 -1275 595 -668 706 -661 763 -68 1788 -109 -398 408 -94 308 706 883 1997 1749 2455 777 1320 -159 201 63 1480 1806 3327 2439 668 530 -1201 -58 1071 1011 1044 887 1080 383 -847 -1839 -3287 -3222 -1922 -2190 -1024 -1624 -2130 -1098 -276 353 730 1460 1491 1226 387 -542 -567 -825 -576 -38 1116 991 -44 -390 -1001 -1452 -1275 -418 -1708 -1009 -816 -208 670 874 1018 650 359 61 -507 -4 -149 228 273 118 110 883 861 171 474 -729 -59 322 -96 -195 -505 -282 -569 -64 67 -251 791 539 70 -83 -327 -543 -737 -482 -687 -171 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