File name: Pandora260s1_CameronLA_20250113_L2Fit_fout2c6d20240924p1-8.txt File generation date: 20250114T062521.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v6d20240924.txt Level 1 file used: Pandora260s1_CameronLA_20250113_L1_smca1c6d20240924p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20250113 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: redo SO2 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0223 305.1628 305.3034 305.4439 305.5844 305.7249 305.8654 306.0059 306.1464 306.2868 306.4273 306.5677 306.7081 306.8485 306.9889 307.1293 307.2697 307.4101 307.5505 307.6908 307.8311 307.9715 308.1118 308.2521 308.3924 308.5327 308.6729 308.8132 308.9534 309.0937 309.2339 309.3741 309.5143 309.6545 309.7947 309.9349 310.0750 310.2152 310.3553 310.4954 310.6355 310.7756 310.9157 311.0558 311.1959 311.3359 311.4760 311.6160 311.7560 311.8961 312.0361 312.1760 312.3160 312.4560 312.5960 312.7359 312.8758 313.0158 313.1557 313.2956 313.4355 313.5753 313.7152 313.8550 313.9949 314.1347 314.2745 314.4144 314.5542 314.6939 314.8337 314.9735 315.1132 315.2530 315.3927 315.5324 315.6721 315.8118 315.9515 316.0912 316.2308 316.3705 316.5101 316.6498 316.7894 316.9290 317.0686 317.2082 317.3477 317.4873 317.6268 317.7664 317.9059 318.0454 318.1849 318.3244 318.4639 318.6034 318.7428 318.8823 319.0217 319.1611 319.3005 319.4399 319.5793 319.7187 319.8581 319.9974 320.1367 320.2761 320.4154 320.5547 320.6940 320.8333 320.9726 321.1118 321.2511 321.3903 321.5295 321.6688 321.8080 321.9471 322.0863 322.2255 322.3647 322.5038 322.6429 322.7821 322.9212 323.0603 323.1994 323.3384 323.4775 323.6166 323.7556 323.8946 324.0337 324.1727 324.3117 324.4506 324.5896 324.7286 324.8675 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250113T154521.8Z 9144.656503 348 1 54.26 2 63.42 139.07 114.76 324.85 0.00 1 0.00 1 0 17 1.656e-02 8.121e-03 4.687e-03 1.216e-03 2.841920e-01 6.000336e-04 3.179298e-03 -6.000000e+00 9.219045e-03 224.35 -2.00 3.24 -2.00 317.59 0.00e+00 5.878593e-04 9.465004e-05 2.921513e-04 -6.000000e+00 4.135208e-04 285.11 -2.00 20.00 -2.00 316.84 0.00e+00 2.222 0.000 302.00 328.00 3 3.8785e+00 1.5816e-03 2.5845e-02 -6.0000e+00 2.2731e-02 1.4132e-03 1.7863e-03 1.3362e-02 -6.0000e+00 2.4659e-02 1.0347e-02 1.1141e-03 6.6289e-03 -6.0000e+00 1.4744e-02 -1.0694e-02 5.7648e-04 1.9206e-03 -6.0000e+00 6.4553e-03 8.4233e-04 6.4677e-05 3.3180e-05 1.9247e-05 -6.0000e+00 4.1748e-04 3.0396e-04 0.0000e+00 11 8 0 10 0 0 100.00 24.58 0.66 0.00030 0.00079 728 76 1 5 0 74.530 33.50 20.01 24.58 17.21 1.0 863.61 -1717 -4687 -4089 -792 -6158 305 -481 -2120 986 -4611 -5143 -2211 -4647 -391 -3178 538 723 3351 -99 3925 1464 -503 -963 3040 -571 -784 1446 1427 -174 1712 304 1001 786 -897 -5078 -5533 -3173 -2355 -655 259 -543 -358 -395 -364 -249 1087 -877 -382 409 -132 391 676 125 1570 761 1012 543 475 -83 399 114 1387 1391 2745 1388 173 374 -1625 -153 1107 346 727 801 1013 536 -374 -937 -2147 -2256 -1701 -1894 -1207 -2011 -1978 -1088 -714 -324 629 1094 1019 1133 424 -701 -323 -538 -416 189 1090 785 72 -371 -628 -1329 -1272 -324 -1536 -944 -672 -321 547 1016 904 658 254 256 -441 -78 -367 354 504 151 143 731 768 93 516 -764 -137 574 34 -316 -286 -233 -242 -84 254 -191 564 496 -19 -192 -379 -818 -140 -445 -405 -73 -529 23 -38 -189 97 -518 -579 -240 -579 -54 -526 97 139 650 -21 826 326 -113 -219 704 -146 -210 388 366 -42 388 74 263 227 -284 -1593 -1622 -966 -742 -244 115 -273 -190 -217 -204 -139 601 -491 -208 217 -70 215 401 72 954 488 660 365 322 -56 260 75 963 1056 2239 1196 142 281 -1187 -112 907 297 661 741 911 458 -317 -711 -1527 -1604 -1343 -1707 -1115 -2046 -2103 -1212 -795 -382 767 1354 1242 1293 480 -731 -313 -533 -453 212 1352 1076 95 -499 -783 -1527 -1428 -392 -2026 -1289 -897 -448 804 1596 1391 1004 393 364 -622 -106 -511 485 745 234 223 1104 1127 130 735 -1047 -179 781 47 -470 -444 -369 -392 -134 431 -338 1012 913 -34 -339 -646 -1349 SS 20250113T162714.6Z 9144.685586 376 1 2.04 2 58.04 148.39 119.27 333.51 0.00 1 0.00 1 0 17 1.260e-02 8.586e-03 6.073e-03 3.366e-03 2.425130e-01 1.678299e-03 2.730009e-03 -6.000000e+00 7.020973e-03 224.35 -2.00 3.24 -2.00 315.76 0.00e+00 7.476737e-04 1.717851e-04 1.325326e-04 -6.000000e+00 3.146684e-04 285.11 -2.00 20.00 -2.00 315.09 0.00e+00 1.882 0.000 302.00 328.00 3 3.2012e+00 4.2979e-03 2.1881e-02 -6.0000e+00 1.7312e-02 1.6927e-02 4.7938e-03 1.1280e-02 -6.0000e+00 1.8774e-02 4.4287e-03 2.7760e-03 5.5741e-03 -6.0000e+00 1.1225e-02 -8.3085e-03 1.3112e-03 1.6356e-03 -6.0000e+00 4.9206e-03 2.4568e-03 9.8453e-04 8.9464e-05 1.7731e-05 -6.0000e+00 3.1753e-04 -7.2586e-03 0.0000e+00 12 9 1 12 33 1 99.63 24.62 0.48 -0.00726 0.00014 4 14 1 5 0 407.200 33.25 20.00 24.62 17.80 1.0 868.39 3149 287 -844 -853 -3658 -1520 -2213 -3512 -1086 -393 -726 -4239 -2607 -1221 -708 449 -81 605 192 2207 2449 -379 533 859 1277 621 1462 936 -573 -279 459 776 840 960 -3619 -5260 -1432 -2104 -426 1018 -447 95 -701 41 422 690 -568 -402 -18 -295 566 930 460 1922 204 915 842 12 336 -277 234 1401 1357 2537 1393 -160 409 -1580 271 422 -70 695 935 433 305 -729 -665 -2041 -2319 -1899 -1623 -1087 -1210 -2216 -1142 -167 -288 206 1168 650 871 -87 -1043 -115 -807 -464 -225 1096 608 160 -689 -369 -1093 -993 -599 -1540 -653 -754 -336 869 1097 1019 862 371 486 -115 -106 32 234 591 450 110 953 830 424 681 -599 177 492 -67 65 -644 -419 -366 -66 -84 -117 325 565 -232 -180 -385 -828 658 69 -214 -208 -801 -324 -492 -812 -277 -107 -196 -1169 -779 -385 -237 167 -32 243 76 881 1005 -158 220 373 582 280 666 434 -247 -114 195 354 391 477 -1784 -2443 -678 -1083 -244 654 -311 69 -507 30 306 500 -411 -296 -13 -208 409 688 362 1505 169 766 691 10 273 -232 198 1189 1204 2314 1331 -146 364 -1359 231 389 -67 707 967 439 304 -694 -587 -1753 -1977 -1712 -1528 -1090 -1276 -2377 -1280 -194 -344 256 1418 806 1043 -100 -1131 -119 -849 -513 -257 1331 789 207 -877 -447 -1265 -1164 -734 -1930 -845 -993 -447 1206 1576 1479 1234 518 659 -148 -136 41 315 806 628 155 1337 1132 566 891 -777 219 631 -90 90 -908 -600 -533 -98 -130 -181 515 890 -365 -280 -597 -1243 SS 20250113T163042.7Z 9144.687995 379 1 27.29 2 57.65 149.23 119.59 334.28 0.00 1 0.00 1 0 17 2.398e-02 1.049e-02 7.866e-03 2.990e-03 2.439369e-01 1.483125e-03 2.742132e-03 -6.000000e+00 1.335642e-02 224.35 -2.00 3.24 -2.00 316.72 0.00e+00 1.082554e-04 1.881725e-04 1.873552e-04 -6.000000e+00 5.989954e-04 285.11 -2.00 20.00 -2.00 315.99 0.00e+00 1.862 0.000 302.00 328.00 3 5.4327e+00 3.8516e-03 2.1783e-02 -6.0000e+00 3.2933e-02 2.5976e-02 4.3210e-03 1.1419e-02 -6.0000e+00 3.5723e-02 2.2151e-02 2.5705e-03 5.6464e-03 -6.0000e+00 2.1359e-02 -1.6831e-02 1.2738e-03 1.6224e-03 -6.0000e+00 9.3543e-03 2.6590e-04 2.6981e-04 8.0887e-05 1.7320e-05 -6.0000e+00 6.0461e-04 -1.5784e-03 0.0000e+00 12 9 9 12 33 33 99.99 24.63 1.41 -0.00158 0.00045 20 4 1 5 0 1299.260 33.25 20.00 24.63 17.98 1.0 870.23 6734 -1435 -4755 1158 -6381 14440 6992 1129 2576 2127 -1031 102 -618 907 -2841 -1258 5623 -5471 -1488 3384 2915 -2089 -274 2966 -1577 1158 3061 -4350 -120 8277 1481 2491 235 -1776 -5434 -4153 525 -3147 1108 1031 -949 -148 -1654 -1449 -1147 -3055 -1141 -360 606 1339 -321 248 -466 1138 3049 1371 456 1696 153 -857 714 220 1430 2362 1587 263 1322 -1485 -321 1211 -360 885 1075 1290 -234 -790 -1211 -2651 -2074 -820 -1802 -207 -1088 -1942 -2457 -354 -142 741 1069 821 2284 -67 -787 306 525 -1499 674 1594 831 -412 -1058 -265 -836 -1643 492 -1453 -1408 -490 -927 682 583 1163 750 127 497 -505 775 -121 -809 324 411 139 465 752 272 389 -640 -395 784 269 -575 -879 -243 -396 -502 239 20 691 468 8 119 -351 -558 858 -222 -793 175 -910 1541 836 160 408 366 -182 18 -117 195 -659 -323 1413 -1581 -431 966 863 -644 -83 920 -542 405 1073 -1564 -38 2289 456 818 86 -707 -2123 -1486 190 -1354 548 560 -590 -96 -1124 -924 -785 -1969 -772 -235 381 822 -207 172 -318 806 2210 1027 353 1305 117 -650 540 177 1236 2032 1424 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