File name: Pandora260s1_CameronLA_20250117_L2Fit_fout2c6d20240924p1-8.txt File generation date: 20250118T063128.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v6d20240924.txt Level 1 file used: Pandora260s1_CameronLA_20250117_L1_smca1c6d20240924p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20250117 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: redo SO2 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0223 305.1628 305.3034 305.4439 305.5844 305.7249 305.8654 306.0059 306.1464 306.2868 306.4273 306.5677 306.7081 306.8485 306.9889 307.1293 307.2697 307.4101 307.5505 307.6908 307.8311 307.9715 308.1118 308.2521 308.3924 308.5327 308.6729 308.8132 308.9534 309.0937 309.2339 309.3741 309.5143 309.6545 309.7947 309.9349 310.0750 310.2152 310.3553 310.4954 310.6355 310.7756 310.9157 311.0558 311.1959 311.3359 311.4760 311.6160 311.7560 311.8961 312.0361 312.1760 312.3160 312.4560 312.5960 312.7359 312.8758 313.0158 313.1557 313.2956 313.4355 313.5753 313.7152 313.8550 313.9949 314.1347 314.2745 314.4144 314.5542 314.6939 314.8337 314.9735 315.1132 315.2530 315.3927 315.5324 315.6721 315.8118 315.9515 316.0912 316.2308 316.3705 316.5101 316.6498 316.7894 316.9290 317.0686 317.2082 317.3477 317.4873 317.6268 317.7664 317.9059 318.0454 318.1849 318.3244 318.4639 318.6034 318.7428 318.8823 319.0217 319.1611 319.3005 319.4399 319.5793 319.7187 319.8581 319.9974 320.1367 320.2761 320.4154 320.5547 320.6940 320.8333 320.9726 321.1118 321.2511 321.3903 321.5295 321.6688 321.8080 321.9471 322.0863 322.2255 322.3647 322.5038 322.6429 322.7821 322.9212 323.0603 323.1994 323.3384 323.4775 323.6166 323.7556 323.8946 324.0337 324.1727 324.3117 324.4506 324.5896 324.7286 324.8675 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250117T144245.6Z 9148.613028 295 1 54.67 2 73.06 126.75 79.19 273.41 0.00 1 0.00 1 0 17 7.821e-02 8.803e-03 2.195e-02 1.833e-03 3.994131e-01 9.083744e-04 4.388420e-03 -6.000000e+00 4.355066e-02 224.40 -2.00 3.24 -2.00 318.78 0.00e+00 2.779405e-04 2.058292e-04 5.282847e-04 -6.000000e+00 1.952477e-03 285.00 -2.00 20.00 -2.00 318.05 0.00e+00 3.380 0.000 302.00 328.00 3 3.6010e+00 2.4812e-03 3.8567e-02 -6.0000e+00 1.0740e-01 -2.4600e-02 2.8694e-03 1.9067e-02 -6.0000e+00 1.1652e-01 3.6772e-02 2.1235e-03 9.4663e-03 -6.0000e+00 6.9658e-02 -2.5115e-02 1.1463e-03 2.7288e-03 -6.0000e+00 3.0482e-02 3.1423e-04 1.0644e-05 4.9652e-05 2.6235e-05 -6.0000e+00 1.9725e-03 2.1794e-03 0.0000e+00 12 9 1 12 32 32 99.97 24.33 0.65 0.00218 0.00226 73 8 1 5 0 748.760 33.25 20.00 24.33 16.40 1.0 858.37 26331 -19838 -31032 6527 -22265 36945 47520 -8138 3827 -9879 -7101 2942 -14457 5472 -13358 -5289 11611 13315 -5229 14076 6538 -3031 -5985 7222 -5333 -5094 4226 9599 2426 17660 -1564 3387 -2764 -2851 -7418 -6555 221 -2864 847 1628 -700 -614 -1550 -1281 -1163 2999 -1541 -603 3230 1422 -538 146 -1555 1082 2353 153 -696 1487 -761 222 -106 -166 1402 2468 1410 522 1551 -2334 -751 1017 274 1103 505 802 429 -1164 -703 -3339 -2726 -1478 -2230 -398 -1372 -1909 -867 -392 -92 695 1260 872 2253 52 -1021 425 85 123 755 1438 741 -9 -690 -525 -1150 -1540 -153 -1460 -879 -635 -487 467 701 620 660 247 132 -370 328 -580 407 394 272 168 502 467 98 507 -881 -220 479 -48 -534 -667 -488 -467 -381 163 18 826 361 -34 126 -198 -289 480 -667 -1254 179 -724 627 773 -263 127 -413 -294 114 -773 290 -1022 -437 884 1064 -538 1258 657 -334 -692 794 -720 -729 570 1186 301 1856 -218 509 -497 -564 -1478 -1219 41 -581 202 468 -235 -220 -587 -498 -452 1132 -611 -236 1220 555 -209 62 -728 530 1206 83 -392 830 -425 120 -58 -97 830 1602 981 351 963 -1471 -483 734 210 891 417 641 323 -867 -468 -2150 -1786 -1089 -1776 -352 -1263 -1858 -886 -431 -101 785 1439 983 2507 55 -996 416 81 131 849 1815 985 -12 -909 -675 -1353 -1765 -188 -1836 -1147 -873 -707 684 1058 991 1056 380 199 -520 470 -816 601 625 426 259 796 719 145 754 -1265 -304 700 -74 -844 -1116 -841 -830 -682 310 34 1574 707 -65 234 -371 -518 SS 20250117T145658.8Z 9148.622903 304 1 54.28 2 70.63 129.14 82.21 275.03 0.00 1 0.00 1 0 17 5.327e-02 9.186e-03 1.172e-02 1.799e-03 3.531071e-01 8.895594e-04 3.925149e-03 -6.000000e+00 2.966600e-02 224.40 -2.00 3.24 -2.00 318.18 0.00e+00 5.939403e-04 1.678463e-04 4.596028e-04 -6.000000e+00 1.329900e-03 285.00 -2.00 20.00 -2.00 317.43 0.00e+00 2.980 0.000 302.00 328.00 3 4.0244e+00 2.3826e-03 3.4009e-02 -6.0000e+00 7.3157e-02 -2.4426e-03 2.7120e-03 1.6756e-02 -6.0000e+00 7.9365e-02 2.3844e-02 1.8209e-03 8.3091e-03 -6.0000e+00 4.7448e-02 -1.8570e-02 9.7102e-04 2.4001e-03 -6.0000e+00 2.0766e-02 3.1763e-04 9.2523e-05 4.8922e-05 2.3925e-05 -6.0000e+00 1.3434e-03 1.2054e-03 0.0000e+00 11 9 0 11 32 0 99.93 24.36 0.67 0.00121 0.00190 34 4 1 5 0 1596.190 33.25 20.01 24.36 17.21 1.0 864.48 24154 -15008 -20894 -2324 -12499 22406 30256 -10286 2234 -5417 -10813 -666 -9137 1234 -5501 -1213 5748 10244 -2823 6826 3945 -70 -2664 5233 -4477 -2383 1985 8210 1408 9286 -1846 2148 -1640 -1895 -7357 -5939 1499 -2511 -338 -310 -1180 465 -1984 -978 35 -683 -842 -105 -2635 1057 27 -52 -1356 2026 2775 -8 -428 1777 -558 451 451 607 1873 2768 1704 843 2092 -1682 147 1662 500 543 438 933 347 -936 -672 -3466 -2610 -1405 -2412 -663 -1260 -2184 -976 -339 -122 613 882 739 2083 -72 -877 369 -199 -102 716 642 950 -109 -901 -538 -1009 -1488 -152 -1472 -870 -429 -949 675 722 668 617 458 51 -277 177 -432 441 274 142 28 681 708 539 397 -668 -272 624 302 -408 -642 -429 -308 -272 163 -71 784 387 -10 -70 -223 -681 848 -895 -1408 -127 -671 794 1046 -603 132 -378 -804 -45 -778 113 -636 -155 741 1334 -404 1023 632 -12 -417 894 -823 -453 372 1391 261 1556 -340 423 -374 -472 -1853 -1381 346 -697 -111 -113 -492 203 -925 -463 16 -325 -401 -49 -1258 489 14 -28 -736 1136 1628 -5 -274 1125 -354 278 281 402 1256 2024 1326 630 1426 -1153 102 1290 414 479 393 810 286 -755 -484 -2402 -1818 -1093 -2032 -617 -1217 -2235 -1045 -366 -140 728 1063 878 2288 -78 -887 371 -195 -111 817 780 1273 -151 -1198 -657 -1194 -1724 -189 -1881 -1152 -596 -1323 993 1094 1064 981 694 76 -381 248 -624 634 426 218 43 1062 1072 777 579 -936 -366 882 446 -651 -1029 -703 -519 -461 294 -128 1420 720 -19 -124 -398 -1173 SS 20250117T151046.8Z 9148.632486 314 1 8.26 2 68.35 131.58 85.14 276.62 0.00 1 0.00 1 0 17 1.566e-02 8.390e-03 4.173e-03 1.432e-03 3.201564e-01 7.111997e-04 3.570253e-03 -6.000000e+00 8.721968e-03 224.40 -2.00 3.24 -2.00 317.02 0.00e+00 9.499773e-04 9.709650e-05 2.281162e-04 -6.000000e+00 3.909935e-04 285.00 -2.00 20.00 -2.00 316.29 0.00e+00 2.685 0.000 302.00 328.00 3 2.1901e+00 1.8530e-03 3.0618e-02 -6.0000e+00 2.1509e-02 2.2880e-03 2.0814e-03 1.4974e-02 -6.0000e+00 2.3334e-02 -7.5577e-04 1.2512e-03 7.4075e-03 -6.0000e+00 1.3950e-02 -4.4085e-03 6.2883e-04 2.1881e-03 -6.0000e+00 6.1055e-03 2.7756e-03 4.8081e-05 3.8222e-05 2.2064e-05 -6.0000e+00 3.9495e-04 1.0754e-03 0.0000e+00 12 9 1 12 1 1 98.96 24.38 0.47 0.00108 0.00144 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