File name: Pandora260s1_CameronLA_20250128_L2Fit_fout2c6d20240924p1-8.txt File generation date: 20250129T062945.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Mark Phelps Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 260 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora260_OF_v3d20230316.txt Instrument calibration file used: Pandora260s1_CF_v6d20240924.txt Level 1 file used: Pandora260s1_CameronLA_20250128_L1_smca1c6d20240924p1-8.txt Full location name: South Cameron High School, US Dept of Interior BOEM Monitoring Site Short location name: CameronLA Country of location: United States Location latitude [deg]: 29.7881 Location longitude [deg]: -93.1072 Location altitude [m]: 3 Local noon date: 20250128 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: redo SO2 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0223 305.1628 305.3034 305.4439 305.5844 305.7249 305.8654 306.0059 306.1464 306.2868 306.4273 306.5677 306.7081 306.8485 306.9889 307.1293 307.2697 307.4101 307.5505 307.6908 307.8311 307.9715 308.1118 308.2521 308.3924 308.5327 308.6729 308.8132 308.9534 309.0937 309.2339 309.3741 309.5143 309.6545 309.7947 309.9349 310.0750 310.2152 310.3553 310.4954 310.6355 310.7756 310.9157 311.0558 311.1959 311.3359 311.4760 311.6160 311.7560 311.8961 312.0361 312.1760 312.3160 312.4560 312.5960 312.7359 312.8758 313.0158 313.1557 313.2956 313.4355 313.5753 313.7152 313.8550 313.9949 314.1347 314.2745 314.4144 314.5542 314.6939 314.8337 314.9735 315.1132 315.2530 315.3927 315.5324 315.6721 315.8118 315.9515 316.0912 316.2308 316.3705 316.5101 316.6498 316.7894 316.9290 317.0686 317.2082 317.3477 317.4873 317.6268 317.7664 317.9059 318.0454 318.1849 318.3244 318.4639 318.6034 318.7428 318.8823 319.0217 319.1611 319.3005 319.4399 319.5793 319.7187 319.8581 319.9974 320.1367 320.2761 320.4154 320.5547 320.6940 320.8333 320.9726 321.1118 321.2511 321.3903 321.5295 321.6688 321.8080 321.9471 322.0863 322.2255 322.3647 322.5038 322.6429 322.7821 322.9212 323.0603 323.1994 323.3384 323.4775 323.6166 323.7556 323.8946 324.0337 324.1727 324.3117 324.4506 324.5896 324.7286 324.8675 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250128T164606.1Z 9159.698682 178 1 54.58 2 53.45 150.18 57.25 163.76 0.00 1 0.00 1 0 17 1.430e-02 9.388e-03 2.961e-03 1.582e-03 2.012290e-01 7.885090e-04 2.279975e-03 -6.000000e+00 7.971230e-03 224.71 -2.00 3.24 -2.00 315.84 0.00e+00 6.382000e-04 8.167098e-05 1.299390e-04 -6.000000e+00 3.568211e-04 284.93 -2.00 20.00 -2.00 315.16 0.00e+00 1.675 0.000 302.00 328.00 3 5.2862e+00 2.0251e-03 1.9143e-02 -6.0000e+00 1.9671e-02 1.2833e-02 2.2587e-03 9.4200e-03 -6.0000e+00 2.1336e-02 1.2504e-02 1.3093e-03 4.6478e-03 -6.0000e+00 1.2752e-02 -1.0038e-02 6.1978e-04 1.3523e-03 -6.0000e+00 5.5772e-03 4.0356e-04 1.7353e-04 4.2439e-05 1.4742e-05 -6.0000e+00 3.6057e-04 1.0682e-03 0.0000e+00 12 9 9 12 32 32 99.98 24.76 0.50 0.00107 0.00237 30 3 1 5 0 1819.030 33.50 20.00 24.76 20.61 0.8 888.42 -1400 -2042 -1833 -2735 -4958 614 2558 -556 54 -1516 -4080 -2986 -2980 413 -1677 524 3305 1625 91 3375 2410 -130 532 1833 -644 883 1364 2689 256 2936 1067 651 1 -654 -4344 -3856 -2019 -1323 -992 197 -592 -400 -780 -687 -283 1609 -864 207 -1794 540 158 652 -451 1595 1545 559 469 1114 -250 49 324 735 1387 2572 1474 -167 1177 -1971 32 1085 216 754 644 835 475 -891 -797 -2833 -2269 -1650 -2365 -886 -1324 -2365 -1112 -563 -441 481 940 1080 581 181 -1062 -1216 -272 -188 536 1480 851 89 -518 -441 -937 -1173 100 -1269 -879 -603 -543 564 908 1120 682 634 407 -262 191 -362 607 441 -61 474 759 819 896 296 -674 -261 603 -67 -535 -708 -256 -602 -556 175 -407 701 369 -80 120 -444 -527 -304 -495 -458 -659 -1061 114 481 -120 13 -397 -1079 -761 -828 126 -592 184 1174 599 35 1307 970 -53 214 766 -290 407 636 1174 105 1107 423 276 0 -320 -2078 -1700 -926 -688 -567 123 -415 -293 -591 -529 -216 1203 -653 149 -1278 367 110 488 -360 1221 1229 454 389 924 -206 40 265 635 1290 2383 1421 -152 1018 -1657 26 1002 213 782 681 861 466 -860 -683 -2429 -1903 -1415 -2306 -884 -1440 -2544 -1248 -643 -535 604 1197 1352 684 207 -1179 -1244 -278 -209 615 1761 1115 119 -662 -522 -1088 -1345 124 -1617 -1162 -788 -739 799 1292 1642 984 903 561 -332 232 -453 799 598 -88 681 1068 1118 1221 386 -840 -327 780 -89 -749 -975 -355 -852 -827 261 -636 1108 600 -130 187 -677 -776 SS 20250128T191321.0Z 9159.800937 274 1 54.58 2 49.13 195.12 58.54 202.20 0.00 1 0.00 1 0 17 1.177e-02 8.766e-03 1.967e-03 1.244e-03 1.870780e-01 6.228253e-04 2.125703e-03 -6.000000e+00 6.564238e-03 224.71 -2.00 3.24 -2.00 315.23 0.00e+00 4.490640e-04 5.709651e-05 6.077116e-05 -6.000000e+00 2.938299e-04 284.93 -2.00 20.00 -2.00 314.61 0.00e+00 1.525 0.000 302.00 328.00 3 5.0438e+00 1.5898e-03 1.7537e-02 -6.0000e+00 1.6199e-02 3.0591e-02 1.7697e-03 8.7732e-03 -6.0000e+00 1.7570e-02 3.3178e-03 1.0187e-03 4.3243e-03 -6.0000e+00 1.0501e-02 -7.2310e-03 4.6926e-04 1.2466e-03 -6.0000e+00 4.5929e-03 6.0967e-04 4.7487e-05 3.3168e-05 1.4741e-05 -6.0000e+00 2.9691e-04 8.3793e-04 0.0000e+00 11 8 0 10 0 0 99.99 24.98 0.65 0.00084 0.00119 32 3 1 5 0 1705.390 33.50 19.99 24.98 21.12 0.8 891.96 1414 -1871 -1298 -1594 -4244 -2017 577 -884 668 -1210 -2789 -1705 -1751 364 -126 511 1131 1487 586 2464 1803 -243 699 1250 474 409 754 2074 -189 1817 851 588 802 53 -3747 -3759 -2201 -2060 -687 66 -516 -572 -691 -735 -148 919 -439 -167 -136 275 402 661 -108 1216 1139 909 437 888 -345 392 310 898 1588 2180 1451 -254 346 -1946 -198 644 455 609 465 723 439 -622 -776 -2618 -2210 -1650 -2111 -1039 -1689 -2039 -1067 -682 -246 113 1049 977 1193 235 -914 -201 -387 -257 491 1345 1027 115 -331 -459 -944 -1024 -406 -1173 -1115 -568 -448 538 747 1010 745 429 236 -486 64 -564 489 329 384 254 472 817 858 500 -598 -16 470 60 -298 -437 -280 -509 -82 157 -23 758 345 -33 -237 -479 -932 380 -573 -407 -478 -1235 -525 151 -259 199 -393 -903 -529 -588 135 -49 218 496 660 271 1151 872 -118 335 624 250 208 388 1074 -91 811 393 288 419 27 -2044 -1894 -1155 -1142 -418 47 -389 -450 -561 -606 -120 738 -351 -128 -101 197 296 518 -90 984 957 773 380 774 -298 331 265 808 1451 2124 1462 -242 312 -1684 -169 612 460 618 481 729 445 -580 -682 -2270 -1869 -1434 -2077 -1056 -1775 -2235 -1222 -800 -306 139 1304 1198 1434 273 -972 -206 -398 -271 567 1622 1292 148 -406 -549 -1103 -1179 -481 -1438 -1422 -754 -590 736 1080 1437 1087 588 311 -617 77 -704 641 447 526 351 639 1121 1113 649 -743 -20 571 79 -392 -597 -385 -713 -115 233 -33 1137 533 -52 -354 -728 -1374 SS 20250128T192254.3Z 9159.807573 281 1 54.19 2 49.72 198.01 59.32 204.49 0.00 1 0.00 1 0 17 1.220e-02 8.739e-03 1.911e-03 1.181e-03 1.905165e-01 5.900437e-04 2.159597e-03 -6.000000e+00 6.803787e-03 224.71 -2.00 3.24 -2.00 315.34 0.00e+00 5.674991e-04 5.515661e-05 5.119982e-05 -6.000000e+00 3.045232e-04 284.93 -2.00 20.00 -2.00 314.70 0.00e+00 1.544 0.000 302.00 328.00 3 4.8925e+00 1.5054e-03 1.7777e-02 -6.0000e+00 1.6791e-02 3.3669e-02 1.6761e-03 8.9397e-03 -6.0000e+00 1.8210e-02 3.2850e-06 9.6811e-04 4.4053e-03 -6.0000e+00 1.0884e-02 -5.9728e-03 4.4855e-04 1.2903e-03 -6.0000e+00 4.7611e-03 6.9144e-04 8.5553e-05 3.1351e-05 1.4709e-05 -6.0000e+00 3.0768e-04 -3.2259e-04 0.0000e+00 11 8 0 10 0 0 99.98 24.98 0.45 -0.00032 0.00032 72 8 1 5 0 752.570 33.50 20.00 24.98 20.73 0.8 887.39 1753 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