File name: Pandora184s1_CapeElizabethME_20241212_L2Fit_fout2c4d20221222p1-8.txt File generation date: 20250113T184602.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 184 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora184_OF_v5d20201127.txt Instrument calibration file used: Pandora184s1_CF_v4d20221222.txt Level 1 file used: Pandora184s1_CapeElizabethME_20241212_L1_smca1c4d20221222p1-8.txt Full location name: CEPTL - Cape Elizabeth Two Lights (State Park) Maine Short location name: CapeElizabethME Country of location: United States Location latitude [deg]: 43.5610 Location longitude [deg]: -70.2073 Location altitude [m]: 24 Local noon date: 20241212 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0587 305.1998 305.3408 305.4818 305.6228 305.7638 305.9048 306.0458 306.1867 306.3277 306.4686 306.6095 306.7505 306.8914 307.0323 307.1732 307.3140 307.4549 307.5958 307.7366 307.8774 308.0183 308.1591 308.2999 308.4407 308.5814 308.7222 308.8630 309.0037 309.1445 309.2852 309.4259 309.5666 309.7073 309.8480 309.9887 310.1293 310.2700 310.4106 310.5513 310.6919 310.8325 310.9731 311.1137 311.2543 311.3948 311.5354 311.6759 311.8165 311.9570 312.0975 312.2380 312.3785 312.5190 312.6595 312.7999 312.9404 313.0808 313.2212 313.3616 313.5021 313.6424 313.7828 313.9232 314.0636 314.2039 314.3443 314.4846 314.6249 314.7652 314.9055 315.0458 315.1861 315.3263 315.4666 315.6068 315.7471 315.8873 316.0275 316.1677 316.3079 316.4481 316.5882 316.7284 316.8685 317.0087 317.1488 317.2889 317.4290 317.5691 317.7092 317.8492 317.9893 318.1293 318.2694 318.4094 318.5494 318.6894 318.8294 318.9694 319.1093 319.2493 319.3892 319.5292 319.6691 319.8090 319.9489 320.0888 320.2287 320.3686 320.5084 320.6483 320.7881 320.9279 321.0677 321.2075 321.3473 321.4871 321.6269 321.7666 321.9064 322.0461 322.1858 322.3255 322.4652 322.6049 322.7446 322.8843 323.0239 323.1636 323.3032 323.4428 323.5824 323.7220 323.8616 324.0012 324.1408 324.2803 324.4199 324.5594 324.6989 324.8384 324.9779 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241212T124616.6Z 9112.532136 219 1 46.72 2 84.78 129.14 116.93 342.99 0.00 1 0.00 1 0 25 7.172e-01 6.408e-02 5.247e-01 5.241e-02 9.544345e-01 3.049003e-02 1.097759e-02 -6.000000e+00 4.208363e-01 222.32 -2.00 3.57 -2.00 322.19 0.00e+00 -1.533642e-02 1.272389e-02 1.939497e-02 -6.000000e+00 2.069195e-02 275.13 -2.00 20.00 -2.00 321.70 0.00e+00 9.531 0.017 302.00 328.00 3 -6.2079e-02 1.0610e-01 1.6371e-01 -6.0000e+00 1.0417e+00 1.9410e+00 1.2463e-01 1.6870e-01 -6.0000e+00 1.1469e+00 -2.0336e+00 7.4110e-02 4.4202e-02 -6.0000e+00 6.7096e-01 6.7827e-01 4.1374e-02 1.8254e-02 -6.0000e+00 2.7896e-01 1.5107e-05 1.4240e-03 1.4625e-03 1.0795e-04 -6.0000e+00 2.1974e-02 -1.8928e-02 2.9447e-05 12 8 8 10 0 0 52.83 22.47 1.11 -0.01893 -0.00823 32 9 1 5 0 1459.930 26.62 20.01 22.47 9.84 29.2 1033.87 123162 -2955 182580 4016 5274 -70944 -63702 35035 900000 70622 900000 -26154 -72392 -59078 -16638 63556 773 -35561 162645 24264 92210 30656 900000 128272 25963 297516 900000 900000 -27451 259418 900000 142387 32641 900000 900000 900000 98376 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2277 4424 5253 7562 8329 7312 5423 2153 6803 -5208 -17405 3317 -388 -1096 2648 6684 7047 5686 10334 6936 11529 -3132 5192 -8693 -3259 -800 6338 -7684 4145 -9921 3177 4004 4261 -8817 896 -9993 -6026 -14544 704 -10557 -10653 -3235 4367 -3023 5052 5805 6938 -11100 681 -2534 4597 5 -2117 7036 3136 8584 4345 8486 3495 5074 -2067 3842 3036 3857 -6883 -4006 -6409 4121 -285 2888 -9023 9363 -3906 8353 -4069 -2151 -3083 SS 20241212T125916.8Z 9112.541167 222 1 46.84 2 82.99 131.54 117.48 346.24 0.00 1 0.00 1 0 25 5.767e-01 1.854e-02 4.048e-01 1.142e-02 8.810251e-01 6.999372e-03 1.050222e-02 -6.000000e+00 3.430657e-01 222.32 -2.00 3.57 -2.00 322.39 0.00e+00 1.204641e-02 4.280721e-03 6.206142e-03 -6.000000e+00 1.870680e-02 275.13 -2.00 20.00 -2.00 321.98 0.00e+00 7.526 0.008 302.00 328.00 3 3.0163e-01 2.7879e-02 9.0946e-02 -6.0000e+00 8.5138e-01 5.8700e-01 4.6140e-02 5.2730e-02 -6.0000e+00 9.3733e-01 -7.2803e-01 5.2801e-02 3.2827e-02 -6.0000e+00 5.5097e-01 2.6535e-01 2.3314e-02 1.5944e-02 -6.0000e+00 2.3437e-01 9.6722e-05 -4.5813e-04 3.5496e-04 3.4162e-04 -6.0000e+00 1.7795e-02 -1.8290e-02 -6.2202e-05 12 8 8 10 0 0 18.55 22.46 0.62 -0.01829 -0.02173 95 26 1 5 0 492.970 26.62 20.00 22.46 10.48 29.2 1039.32 900000 -251765 900000 900000 900000 -324213 900000 900000 900000 -71147 900000 -237748 900000 900000 900000 -74433 900000 900000 900000 900000 63017 169788 900000 900000 900000 900000 109398 108316 1551 15181 -45872 -14942 -74411 72041 -88870 4538 -82425 73649 -192 58929 -36844 21005 101 30257 -42908 110062 -19248 77677 -42341 107336 -10633 55890 3168 68418 15576 46895 7584 36020 -12844 51886 33630 35274 -2226 45653 21616 35761 8388 22497 10761 25866 8141 23857 9189 14640 3262 4741 -765 -9551 -2956 -2319 7026 -2586 3507 -2572 2320 106 3758 -4060 5586 -1489 -1413 -6821 112 -12666 506 -4681 1921 -2163 3381 -3132 1147 -3912 -798 -3342 -283 -3037 -811 -457 3017 1100 1235 -894 823 -454 -1015 -2079 -805 -353 2256 -95 1068 2271 1038 1874 -1065 704 -1590 -374 359 587 -1063 299 26 -2 -259 -251 93 988 126 512 -911 130 -1032 900000 -2794 900000 900000 900000 -6596 900000 900000 900000 -790 900000 -2858 900000 900000 900000 -826 900000 900000 900000 900000 699 1884 900000 900000 900000 900000 1214 1202 17 168 -648 -196 -2102 799 -3048 60 -2744 817 -4 773 -1413 487 3 702 -2121 1221 -816 1332 -2606 1624 -590 1804 192 2347 959 2176 528 1853 -1037 2146 1730 1993 -213 3132 2050 2995 939 2547 1390 3617 1491 3865 1683 2356 528 679 -110 -1590 -538 -512 1692 -795 1125 -936 855 42 1510 -1807 2244 -618 -551 -2664 40 -5594 227 -2649 1211 -1654 2694 -2694 886 -2835 -507 -2148 -187 -2188 -610 -374 2692 1156 1473 -1180 1097 -604 -1313 -2651 -1030 -472 3097 -136 1478 2954 1311 2277 -1293 817 -1874 -471 522 988 -2046 618 58 -5 -664 -677 254 2714 346 1328 -2230 293 -2292 SS 20241212T131249.2Z 9112.550570 225 1 46.88 2 81.19 134.11 117.92 349.67 0.00 1 0.00 1 0 25 6.594e-01 1.264e-02 2.391e-01 4.402e-03 7.800530e-01 2.439289e-03 9.391041e-03 -6.000000e+00 3.754157e-01 222.32 -2.00 3.57 -2.00 321.98 0.00e+00 1.198348e-02 1.348737e-03 4.238528e-03 -6.000000e+00 1.642258e-02 275.13 -2.00 20.00 -2.00 321.53 0.00e+00 6.178 0.004 302.00 328.00 3 2.6536e-01 8.8997e-03 7.4953e-02 -6.0000e+00 9.2320e-01 3.4347e-01 1.3489e-02 4.4364e-02 -6.0000e+00 1.0075e+00 -4.3802e-01 1.5098e-02 2.9847e-02 -6.0000e+00 6.0029e-01 1.6822e-01 6.9242e-03 1.6431e-02 -6.0000e+00 2.5360e-01 3.9697e-04 -6.7404e-04 1.2722e-04 2.7398e-04 -6.0000e+00 1.8730e-02 -2.0405e-02 2.5408e-05 12 9 8 11 8 0 21.99 22.51 0.40 -0.02041 -0.02547 208 58 1 5 0 225.340 26.73 19.97 22.51 11.15 29.2 1043.90 -253823 -260031 -220711 -235791 -131702 -274665 -225888 -187723 -209738 -193736 -144330 -101218 -113700 -91976 -67965 -35144 -82896 -83687 -49861 -44874 -26492 -28291 -27786 5973 -46173 -48903 4395 -8772 -42559 -55174 -278 -4180 -15269 -1223 -27701 -37070 -20789 -13467 -802 8081 -12932 5267 -448 22752 993 3997 -1561 15745 7343 9563 10649 11852 7779 15149 14936 4275 1773 3619 -2027 2181 10288 6511 9811 4173 11700 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