File name: Pandora225s1_Cebu_20250227_L2Fit_fout2c2d20220603p1-8.txt File generation date: 20250227T160550.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Ellison Castro Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 225 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora225_OF_v2d20220531.txt Instrument calibration file used: Pandora225s1_CF_v2d20220603.txt Level 1 file used: Pandora225s1_Cebu_20250227_L1_smca1c2d20220603p1-8.txt Full location name: University of San Carlos - Talamban Campus Short location name: Cebu Country of location: Philippines Location latitude [deg]: 10.3551 Location longitude [deg]: 123.9111 Location altitude [m]: 67 Local noon date: 20250227 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 1 for initial instrument deployment First and last pixel inside fitting window: 197 338 Nominal wavelengths inside fitting window [nm]: 305.1070 305.2483 305.3895 305.5307 305.6719 305.8131 305.9543 306.0955 306.2366 306.3778 306.5189 306.6600 306.8012 306.9423 307.0833 307.2244 307.3655 307.5066 307.6476 307.7886 307.9297 308.0707 308.2117 308.3527 308.4936 308.6346 308.7756 308.9165 309.0574 309.1984 309.3393 309.4802 309.6210 309.7619 309.9028 310.0436 310.1845 310.3253 310.4661 310.6069 310.7477 310.8885 311.0293 311.1700 311.3108 311.4515 311.5922 311.7329 311.8737 312.0143 312.1550 312.2957 312.4363 312.5770 312.7176 312.8582 312.9988 313.1394 313.2800 313.4206 313.5612 313.7017 313.8423 313.9828 314.1233 314.2638 314.4043 314.5448 314.6853 314.8257 314.9662 315.1066 315.2470 315.3874 315.5278 315.6682 315.8086 315.9490 316.0893 316.2297 316.3700 316.5103 316.6506 316.7909 316.9312 317.0715 317.2117 317.3520 317.4922 317.6324 317.7727 317.9129 318.0531 318.1932 318.3334 318.4736 318.6137 318.7538 318.8939 319.0341 319.1742 319.3142 319.4543 319.5944 319.7344 319.8745 320.0145 320.1545 320.2945 320.4345 320.5745 320.7145 320.8544 320.9944 321.1343 321.2742 321.4141 321.5540 321.6939 321.8338 321.9736 322.1135 322.2533 322.3932 322.5330 322.6728 322.8126 322.9523 323.0921 323.2319 323.3716 323.5114 323.6511 323.7908 323.9305 324.0702 324.2098 324.3495 324.4892 324.6288 324.7684 324.9080 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250226T223807.0Z 9188.943137 59 1 51.64 2 81.54 100.16 72.13 111.28 0.00 1 0.00 1 0 17 4.373e-01 8.942e-03 1.258e-01 3.510e-03 6.198089e-01 1.950342e-03 6.569660e-03 -6.000000e+00 2.628304e-01 226.22 -2.00 3.06 -2.00 321.40 0.00e+00 2.858164e-03 1.078480e-03 4.581259e-03 -6.000000e+00 1.233938e-02 294.02 -2.00 20.00 -2.00 320.75 0.00e+00 6.392 0.000 302.00 328.00 3 1.1802e-01 7.4731e-03 7.2381e-02 -6.0000e+00 6.4729e-01 1.8571e-01 1.0293e-02 4.2062e-02 -6.0000e+00 7.0034e-01 -2.3867e-01 9.1742e-03 1.8379e-02 -6.0000e+00 4.2083e-01 8.7118e-02 4.2917e-03 4.2512e-03 -6.0000e+00 1.7990e-01 5.0021e-04 1.1086e-04 1.1014e-04 1.0112e-04 -6.0000e+00 1.3689e-02 1.4013e-02 1.0990e-04 11 8 0 10 0 0 65.53 26.37 0.38 0.01401 0.01485 173 27 1 5 0 298.470 28.94 20.00 26.37 32.14 1.9 1000.91 -166268 -153256 -155608 -155102 -169097 -89377 -64874 -128046 -152228 -157839 -145169 -55684 -73707 -46168 -55107 -53093 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-193 -876 -390 -902 -662 -964 -1317 -513 -399 130 425 1034 357 -87 -40 -611 -797 -767 -491 -366 -68 -594 -600 -324 -1346 -1610 -815 -280 -1861 -936 -811 -22 438 704 324 636 510 -272 213 212 342 219 407 546 772 753 987 589 -268 -95 648 1062 310 -98 -285 -963 14 -78 -171 67 389 995 -677 -244 -702 -729 SS 20250226T225031.8Z 9188.951757 64 1 51.76 2 78.54 100.81 69.36 112.17 0.00 1 0.00 1 0 17 1.924e-01 5.525e-03 2.620e-02 1.094e-03 4.972972e-01 5.929839e-04 5.175507e-03 -6.000000e+00 1.156009e-01 226.22 -2.00 3.06 -2.00 320.55 0.00e+00 2.142422e-03 2.437000e-04 1.790457e-03 -6.000000e+00 5.427427e-03 294.02 -2.00 20.00 -2.00 319.76 0.00e+00 4.863 0.000 302.00 328.00 3 -1.3319e-01 1.9285e-03 5.3174e-02 -6.0000e+00 2.8470e-01 5.1441e-02 2.4499e-03 2.4812e-02 -6.0000e+00 3.0804e-01 -6.2450e-02 2.0346e-03 1.2321e-02 -6.0000e+00 1.8510e-01 1.4922e-02 1.0139e-03 3.4660e-03 -6.0000e+00 7.9123e-02 3.0718e-03 1.5659e-04 3.5324e-05 5.9979e-05 -6.0000e+00 6.0214e-03 1.3804e-02 7.9120e-05 10 0 0 10 0 0 46.85 26.38 0.36 0.01380 0.01498 513 81 1 5 0 100.880 28.94 20.00 26.38 32.97 1.8 1007.02 -82572 -57083 -60481 -55047 -79388 -59053 -71720 -63565 -40659 -65565 -42358 -51039 -27689 -27408 -18671 -11196 -16390 -8346 -15193 -411 -16440 -9280 -6072 -10856 -7627 -7158 -7823 -12677 -5879 -11106 -3681 -7371 -4076 -3708 -5641 -5690 -6697 507 -505 2035 -360 1049 844 1176 1787 1168 2062 -1163 1850 1273 2452 2172 2597 1656 789 1468 471 1192 196 720 1515 2509 2088 1901 1234 318 947 769 2163 1176 1284 795 139 436 -549 -289 -1270 -992 -923 -971 -1237 -1435 -1613 -1039 -406 -75 527 232 680 296 356 -434 -402 -27 -275 114 119 67 -460 -543 -734 -816 -230 -600 -981 -974 -465 -284 613 466 322 229 73 130 -152 380 312 298 111 -105 57 63 405 133 472 -135 479 655 185 26 -351 -477 -230 32 4 -29 287 114 -17 20 -139 -475 -1169 -692 -774 -641 -1124 -693 -1050 -968 -540 -1189 -657 -995 -521 -630 -467 -295 -501 -254 -526 -13 -614 -330 -221 -491 -356 -341 -372 -622 -273 -591 -208 -494 -287 -264 -406 -430 -584 49 -59 267 -53 161 134 190 292 194 345 -206 331 245 513 499 641 438 220 419 137 341 56 209 467 848 780 753 491 124 365 315 979 597 694 438 75 219 -254 -123 -528 -434 -457 -556 -806 -1032 -1248 -853 -353 -63 455 203 578 263 296 -342 -314 -23 -257 110 129 79 -559 -635 -794 -822 -228 -628 -1100 -1155 -583 -383 895 740 538 385 118 200 -222 548 465 471 185 -178 95 102 633 201 681 -190 678 1001 314 48 -689 -897 -455 66 10 -67 667 266 -38 44 -290 -972 SS 20250226T225617.5Z 9188.955758 67 1 51.75 2 77.15 101.13 68.08 112.61 0.00 1 0.00 1 0 17 1.182e-01 4.996e-03 1.387e-02 7.288e-04 4.538229e-01 3.849512e-04 4.628396e-03 -6.000000e+00 7.100436e-02 226.22 -2.00 3.06 -2.00 320.16 0.00e+00 1.473268e-03 1.396580e-04 1.054352e-03 -6.000000e+00 3.333591e-03 294.02 -2.00 20.00 -2.00 319.32 0.00e+00 4.375 0.000 302.00 328.00 3 -2.8622e-01 1.1841e-03 4.7577e-02 -6.0000e+00 1.7487e-01 2.9663e-02 1.4651e-03 2.1212e-02 -6.0000e+00 1.8920e-01 -3.9955e-02 1.1712e-03 1.0557e-02 -6.0000e+00 1.1369e-01 7.1833e-03 5.9707e-04 3.0618e-03 -6.0000e+00 4.8600e-02 5.9627e-03 1.1711e-04 2.3512e-05 4.4235e-05 -6.0000e+00 3.6984e-03 1.3773e-02 8.4838e-05 10 0 0 10 0 0 70.22 26.38 0.35 0.01377 0.01465 761 121 1 5 0 67.990 28.94 20.01 26.38 33.29 1.8 1009.46 -50658 -35653 -37006 -36853 -48522 -41391 -38169 -38502 -29319 -32018 -33761 -28221 -19439 -19484 -9055 -7381 -7746 -4302 -5787 -1930 -4962 -2574 -5024 -3926 -5690 -5757 -6325 -7969 -4776 -5734 -1567 -1875 -889 -5258 -5247 -3945 -3717 19 -1112 -479 -223 143 551 33 902 379 91 384 766 574 1619 1482 1334 1487 1118 1307 597 580 540 1054 1583 2213 1507 1431 742 404 633 494 1866 874 804 439 106 285 -373 -569 686 -947 -857 -1069 -1363 -1436 -1687 -944 -562 -136 341 337 512 363 399 -163 -332 93 143 172 255 233 -400 -459 -722 -746 -135 -408 -1069 -1023 -504 -247 480 381 203 75 49 54 84 312 337 262 99 -144 -23 206 360 122 490 105 469 717 178 134 -274 -445 -183 30 -22 -61 262 104 -37 2 -144 -474 -821 -546 -583 -555 -781 -628 -616 -704 -536 -637 -731 -656 -497 -603 -297 -268 -338 -195 -281 -94 -254 -132 -277 -231 -362 -376 -410 -513 -299 -388 -115 -156 -79 -495 -488 -379 -407 2 -169 -83 -42 28 112 7 188 80 20 83 171 136 416 416 403 475 374 449 209 201 185 367 584 893 670 670 347 183 282 233 969 509 499 277 66 164 -198 -278 319 -467 -476 -683 -987 -1143 -1312 -777 -493 -126 326 326 482 325 332 -140 -283 84 130 177 295 292 -516 -569 -828 -799 -142 -456 -1282 -1296 -673 -353 740 582 325 120 76 86 126 462 515 424 155 -230 -36 317 582 191 728 152 681 1116 280 228 -494 -836 -360 64 -49 -127 560 225 -77 5 -303 -975 SS 20250226T230134.6Z 9188.959428 70 1 51.76 2 75.87 101.42 66.91 113.02 0.00 1 0.00 1 0 17 7.717e-02 4.873e-03 7.850e-03 5.259e-04 4.192032e-01 2.796523e-04 4.360107e-03 -6.000000e+00 4.637566e-02 226.22 -2.00 3.06 -2.00 319.77 0.00e+00 1.145079e-03 8.879916e-05 9.284335e-04 -6.000000e+00 2.177328e-03 294.02 -2.00 20.00 -2.00 318.90 0.00e+00 4.006 0.000 302.00 328.00 3 -4.4401e-01 8.2152e-04 4.3689e-02 -6.0000e+00 1.1421e-01 1.6808e-02 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