File name: Pandora225s1_Cebu_20250623_L2Fit_fwvt1c2d20220603p1-8.txt File generation date: 20250623T155610.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Ellison Castro Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 225 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora225_OF_v2d20220531.txt Instrument calibration file used: Pandora225s1_CF_v2d20220603.txt Level 1 file used: Pandora225s1_Cebu_20250623_L1_smca1c2d20220603p1-8.txt Full location name: University of San Carlos - Talamban Campus Short location name: Cebu Country of location: Philippines Location latitude [deg]: 10.3551 Location longitude [deg]: 123.9111 Location altitude [m]: 67 Local noon date: 20250623 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 1 for initial instrument deployment First and last pixel inside fitting window: 1613 1762 Nominal wavelengths inside fitting window [nm]: 492.0330 492.1544 492.2759 492.3973 492.5187 492.6401 492.7615 492.8828 493.0042 493.1255 493.2468 493.3681 493.4894 493.6106 493.7319 493.8531 493.9743 494.0955 494.2167 494.3378 494.4590 494.5801 494.7012 494.8223 494.9434 495.0644 495.1855 495.3065 495.4275 495.5485 495.6695 495.7904 495.9114 496.0323 496.1532 496.2741 496.3950 496.5158 496.6366 496.7575 496.8783 496.9991 497.1198 497.2406 497.3613 497.4820 497.6027 497.7234 497.8441 497.9647 498.0854 498.2060 498.3266 498.4472 498.5677 498.6883 498.8088 498.9293 499.0498 499.1703 499.2908 499.4112 499.5317 499.6521 499.7725 499.8928 500.0132 500.1335 500.2539 500.3742 500.4945 500.6148 500.7350 500.8553 500.9755 501.0957 501.2159 501.3361 501.4562 501.5763 501.6965 501.8166 501.9367 502.0567 502.1768 502.2968 502.4168 502.5368 502.6568 502.7768 502.8968 503.0167 503.1366 503.2565 503.3764 503.4963 503.6161 503.7359 503.8558 503.9756 504.0953 504.2151 504.3348 504.4546 504.5743 504.6940 504.8137 504.9333 505.0530 505.1726 505.2922 505.4118 505.5314 505.6509 505.7705 505.8900 506.0095 506.1290 506.2484 506.3679 506.4873 506.6068 506.7262 506.8455 506.9649 507.0843 507.2036 507.3229 507.4422 507.5615 507.6808 507.8000 507.9192 508.0385 508.1576 508.2768 508.3960 508.5151 508.6343 508.7534 508.8725 508.9915 509.1106 509.2296 509.3487 509.4677 509.5867 509.7056 509.8246 509.9435 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20250622T224656.5Z 9304.949265 509 1 34.15 2 72.15 68.55 38.40 63.91 0.00 1 0.00 1 0 22 3.880e-03 3.844e-03 1.059e-03 1.056e-03 1.143577e+04 7.344017e+01 7.448323e+02 -6.000000e+00 2.158310e+02 294.71 -2.00 20.00 -2.00 505.30 0.00e+00 7.763493e-04 2.947192e-05 6.030606e-05 -6.000000e+00 1.104270e-04 294.71 -2.00 20.00 -2.00 500.41 0.00e+00 3.580225e-01 2.040137e-02 6.302108e-02 -6.000000e+00 7.453029e-02 227.80 -2.00 3.06 -2.00 502.01 0.00e+00 3.218 0.000 489.00 513.00 1 6.7042e+00 1.5662e-03 7.1835e-03 -6.0000e+00 5.7319e-03 2.4054e-04 4.0228e-04 1.5651e-03 -6.0000e+00 1.4930e-03 1.4430e-03 1.1575e-03 8.4423e-05 6.6511e-05 -6.0000e+00 3.3198e-04 -3.2238e-03 2.9739e-04 11 8 0 10 0 0 7.84 26.44 0.76 -0.00322 0.00480 11 2 1 4 0 3104.140 28.94 20.00 26.44 35.35 2.0 1014.16 -850 -728 -284 99 448 406 586 551 300 445 201 -211 -489 -586 -435 -373 -70 -23 123 114 128 37 311 209 324 560 690 -227 -450 -647 -501 -550 159 -89 370 220 364 -157 19 -15 -129 241 70 530 412 560 453 249 25 -448 -684 -1001 -793 -611 -81 -9 307 13 207 272 330 396 380 183 333 296 38 -230 -101 -537 -338 -337 -77 -122 21 -210 -251 -202 -480 -458 -488 -443 -385 -232 -24 -150 -183 -275 -20 -41 438 382 467 584 432 319 41 -383 -932 -726 -727 -294 -80 -12 192 44 -170 -376 -337 -54 -102 95 120 157 449 713 412 373 566 168 149 5 149 296 179 141 234 371 145 -44 224 66 -361 -387 -530 -86 -126 105 36 330 400 252 457 282 299 142 -303 -854 -790 -650 -827 -722 -279 100 466 431 607 576 312 475 212 -221 -503 -594 -439 -380 -72 -25 129 120 134 39 327 221 344 593 726 -238 -456 -659 -505 -560 165 -93 395 235 382 -163 20 -16 -132 249 74 559 439 596 477 259 25 -446 -687 -987 -775 -607 -80 -9 317 14 214 279 340 410 395 190 341 298 38 -226 -98 -536 -336 -325 -74 -120 21 -205 -240 -197 -466 -443 -476 -419 -367 -223 -24 -147 -179 -268 -20 -40 427 379 467 573 411 307 38 -349 -835 -643 -652 -271 -75 -12 193 44 -168 -365 -327 -54 -102 96 122 159 454 699 412 374 559 170 147 4 144 290 176 139 231 363 143 -43 214 62 -339 -362 -501 -83 -120 101 35 326 397 252 458 284 298 140 -292 -809 -773 -616 SO 20250622T224840.4Z 9304.950468 512 1 35.89 2 71.76 68.58 38.03 63.74 0.00 1 0.00 1 0 22 3.439e-03 3.408e-03 1.075e-03 1.072e-03 1.138357e+04 7.460317e+01 7.292740e+02 -6.000000e+00 1.912413e+02 294.71 -2.00 20.00 -2.00 505.30 0.00e+00 8.839458e-04 2.998818e-05 6.631092e-05 -6.000000e+00 9.785370e-05 294.71 -2.00 20.00 -2.00 500.43 0.00e+00 2.860629e-01 2.070252e-02 6.560696e-02 -6.000000e+00 6.600127e-02 227.80 -2.00 3.06 -2.00 502.03 0.00e+00 3.152 0.000 489.00 513.00 1 6.7818e+00 1.5916e-03 7.2958e-03 -6.0000e+00 5.0766e-03 1.9169e-04 4.0707e-04 1.5935e-03 -6.0000e+00 1.3215e-03 1.3529e-03 4.7041e-04 8.5006e-05 6.4806e-05 -6.0000e+00 2.9405e-04 1.0891e-02 2.5011e-04 10 0 0 10 0 0 -6.14 26.44 0.74 0.01089 0.01415 11 2 1 4 0 3262.110 28.94 20.00 26.44 35.33 2.0 1014.19 -673 -443 -76 -99 202 101 448 347 383 78 378 -339 -438 -506 -525 -174 -296 127 -12 77 224 102 287 94 439 382 305 7 -279 -448 -469 -322 22 192 185 411 281 -99 -179 10 96 296 303 187 440 430 491 197 9 -456 -738 -655 -753 -458 -230 5 143 245 465 33 395 389 425 282 233 25 156 -238 -201 -333 -241 -405 -127 20 -125 -23 -152 133 -548 -578 -329 -471 -291 -333 -40 3 -237 -302 -66 -55 -98 280 453 541 355 250 166 -524 -643 -738 -516 -85 -131 -141 60 -45 -281 25 -91 -286 102 22 -4 444 670 562 688 284 485 109 15 162 132 105 265 293 115 419 301 -274 -122 2 -468 -617 -283 -205 -12 28 80 131 630 266 280 396 8 -36 -249 -688 -595 -547 -649 -434 -78 -101 209 106 480 375 412 83 394 -352 -447 -509 -526 -176 -304 133 -13 80 233 107 299 98 462 401 320 7 -291 -451 -469 -324 23 198 196 434 293 -103 -183 10 98 303 314 197 465 454 513 204 9 -470 -736 -639 -731 -452 -234 5 147 252 475 33 403 401 439 290 237 25 154 -232 -201 -329 -238 -404 -128 20 -123 -23 -150 129 -530 -557 -319 -462 -286 -332 -39 3 -230 -292 -64 -53 -95 277 450 527 349 238 154 -474 -571 -650 -459 -78 -127 -138 59 -45 -276 24 -87 -281 101 22 -4 446 673 571 708 283 496 109 14 156 128 102 258 287 112 408 293 -267 -116 2 -437 -575 -266 -198 -11 28 77 129 620 264 280 395 8 -35 -248 -672 -577 -536 SO 20250622T230050.4Z 9304.958916 572 1 33.90 2 68.97 68.73 35.44 62.43 0.00 1 0.00 1 0 22 3.798e-03 3.769e-03 9.459e-04 9.433e-04 9.140112e+03 6.371328e+01 6.055057e+02 -6.000000e+00 2.112787e+02 294.71 -2.00 20.00 -2.00 505.29 0.00e+00 5.637225e-04 2.629470e-05 4.588528e-05 -6.000000e+00 1.081004e-04 294.71 -2.00 20.00 -2.00 500.41 0.00e+00 2.754333e-01 1.818577e-02 5.089124e-02 -6.000000e+00 7.296408e-02 227.80 -2.00 3.06 -2.00 502.02 0.00e+00 2.760 0.000 489.00 513.00 1 6.5246e+00 1.3953e-03 5.9410e-03 -6.0000e+00 5.6114e-03 1.2085e-03 3.5970e-04 1.2681e-03 -6.0000e+00 1.4618e-03 1.8665e-03 1.2736e-03 7.6391e-05 5.5964e-05 -6.0000e+00 3.2500e-04 -1.7735e-03 2.8403e-04 10 0 0 10 0 0 -0.00 26.45 0.67 -0.00177 0.00706 14 2 1 4 0 2421.130 28.94 20.00 26.45 35.42 2.1 1015.87 -917 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