File name: Pandora70s1_ChapelHillNC_20230701_L2Fit_fout2c1d20210323p1-8.txt File generation date: 20230706T010645.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 70 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora70_OF_v7d20200416.txt Instrument calibration file used: Pandora70s1_CF_v1d20210323.txt Level 1 file used: Pandora70s1_ChapelHillNC_20230701_L1_smca1c1d20210323p1-8.txt Full location name: Duke Forest, Chapel Hill (NC) Short location name: ChapelHillNC Country of location: USA Location latitude [deg]: 35.9708 Location longitude [deg]: -79.0933 Location altitude [m]: 50 Local noon date: 20230701 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 278 420 Nominal wavelengths inside fitting window [nm]: 305.0320 305.1727 305.3133 305.4539 305.5945 305.7351 305.8756 306.0162 306.1567 306.2973 306.4378 306.5783 306.7188 306.8593 306.9998 307.1402 307.2807 307.4211 307.5615 307.7020 307.8424 307.9828 308.1231 308.2635 308.4039 308.5442 308.6846 308.8249 308.9652 309.1055 309.2458 309.3861 309.5263 309.6666 309.8068 309.9470 310.0873 310.2275 310.3677 310.5078 310.6480 310.7882 310.9283 311.0685 311.2086 311.3487 311.4888 311.6289 311.7690 311.9090 312.0491 312.1891 312.3291 312.4692 312.6092 312.7492 312.8891 313.0291 313.1691 313.3090 313.4490 313.5889 313.7288 313.8687 314.0086 314.1484 314.2883 314.4282 314.5680 314.7078 314.8476 314.9874 315.1272 315.2670 315.4068 315.5465 315.6863 315.8260 315.9657 316.1054 316.2451 316.3848 316.5245 316.6641 316.8038 316.9434 317.0830 317.2226 317.3622 317.5018 317.6414 317.7810 317.9205 318.0601 318.1996 318.3391 318.4786 318.6181 318.7576 318.8970 319.0365 319.1759 319.3153 319.4548 319.5942 319.7336 319.8729 320.0123 320.1517 320.2910 320.4303 320.5696 320.7090 320.8482 320.9875 321.1268 321.2661 321.4053 321.5445 321.6838 321.8230 321.9622 322.1013 322.2405 322.3797 322.5188 322.6580 322.7971 322.9362 323.0753 323.2144 323.3534 323.4925 323.6316 323.7706 323.9096 324.0486 324.1876 324.3266 324.4656 324.6046 324.7435 324.8824 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230701T134741.1Z 8582.574782 224 1 49.06 2 47.40 90.51 157.23 289.32 0.00 1 0.00 1 0 17 7.410e-03 5.517e-03 1.672e-03 9.332e-04 2.005237e-01 4.900953e-04 2.362973e-03 -6.000000e+00 4.396772e-03 232.59 -2.00 3.41 -2.00 315.70 0.00e+00 1.360779e-04 4.336143e-05 2.444105e-05 -6.000000e+00 1.722402e-04 290.67 -2.00 20.00 -2.00 315.41 0.00e+00 1.475 0.000 302.00 328.00 3 4.4030e+00 1.2811e-03 1.7978e-02 -6.0000e+00 1.1136e-02 2.5487e-02 1.4154e-03 1.0209e-02 -6.0000e+00 1.2044e-02 8.1911e-04 8.1279e-04 4.9769e-03 -6.0000e+00 7.0532e-03 -4.2626e-03 3.6684e-04 1.3890e-03 -6.0000e+00 2.9407e-03 1.1836e-03 -7.5725e-05 2.7159e-05 1.8008e-05 -6.0000e+00 2.0716e-04 -2.1454e-02 1.8472e-05 10 0 0 10 0 0 99.96 22.71 0.18 -0.02145 -0.02202 131 29 1 8 0 374.470 20.01 22.71 34.98 26.94 26.73 28.4 1058.62 -679 -612 -1576 2206 -1595 -2441 1197 899 1425 507 -402 -993 64 -644 66 110 -448 316 -702 573 897 452 1168 424 583 477 549 -124 -137 832 1291 -114 1688 671 -1453 -319 -1624 -1066 -584 -310 -1048 -862 -972 -1135 -448 -622 -754 -954 -559 -580 366 307 503 1093 528 795 627 422 512 338 804 933 1133 1423 494 -146 95 -545 536 568 277 424 112 663 -27 233 -31 -622 -99 -170 -1016 -711 -1679 -1564 -974 -786 -508 -5 318 179 243 632 69 552 784 451 539 881 269 -227 -246 -503 -589 118 -338 -1020 -630 -607 -515 181 189 25 -84 155 -175 199 261 255 164 156 -384 -65 44 65 192 586 233 819 694 370 459 -21 4 34 147 222 -322 335 -33 -391 -177 -332 -518 -155 -152 -409 540 -365 -523 255 207 356 136 -110 -268 18 -202 23 41 -175 125 -287 239 379 191 494 187 266 223 262 -57 -59 344 543 -50 768 322 -688 -143 -768 -551 -338 -203 -752 -641 -738 -876 -343 -476 -572 -709 -405 -415 264 232 391 877 438 666 532 360 433 284 680 816 1038 1362 484 -138 84 -471 460 518 272 434 117 683 -27 220 -27 -519 -81 -147 -949 -709 -1777 -1710 -1098 -928 -622 -7 405 226 295 724 74 569 803 484 616 1071 345 -295 -312 -614 -691 136 -406 -1290 -816 -810 -706 254 274 37 -124 220 -235 254 325 321 214 213 -543 -93 62 90 257 758 294 1005 867 480 612 -29 5 48 212 331 -493 520 -52 -615 -273 -505 -776 SS 20230701T135242.1Z 8582.578265 226 1 50.38 2 46.38 91.26 158.13 290.81 0.00 1 0.00 1 0 17 6.751e-03 5.423e-03 1.175e-03 6.667e-04 1.971103e-01 3.505998e-04 2.328292e-03 -6.000000e+00 4.005614e-03 232.59 -2.00 3.41 -2.00 315.65 0.00e+00 1.113991e-04 3.065236e-05 2.328134e-05 -6.000000e+00 1.569008e-04 290.67 -2.00 20.00 -2.00 315.36 0.00e+00 1.447 0.000 302.00 328.00 3 3.7659e+00 9.1599e-04 1.7659e-02 -6.0000e+00 1.0145e-02 1.9696e-02 1.0121e-03 1.0046e-02 -6.0000e+00 1.0972e-02 -2.3071e-04 5.8057e-04 4.8968e-03 -6.0000e+00 6.4256e-03 -3.6361e-03 2.6141e-04 1.3654e-03 -6.0000e+00 2.6792e-03 2.3208e-03 -2.4535e-06 1.9341e-05 1.7732e-05 -6.0000e+00 1.8871e-04 -2.1586e-02 3.9070e-05 10 0 0 10 0 0 99.96 22.72 0.15 -0.02159 -0.02160 276 60 1 8 0 176.750 20.01 22.72 35.11 27.05 26.73 28.5 1060.66 -304 -577 -1239 54 -1865 -1568 164 931 1468 454 -477 -750 5 -746 453 3 -378 214 142 605 756 377 1120 385 498 577 428 -79 -94 835 1321 277 1707 370 -1229 -543 -1422 -1076 -502 -519 -1125 -923 -930 -1042 -846 -479 -756 -790 -607 -472 636 223 577 951 677 667 854 356 469 389 837 965 1079 1338 455 -115 93 -412 613 780 265 309 128 541 129 11 15 -442 -91 -314 -988 -802 -1700 -1518 -1012 -768 -550 -76 378 53 152 485 126 558 733 421 418 834 265 -302 -178 -536 -606 175 -155 -935 -652 -567 -512 245 217 163 28 147 -25 112 335 213 125 194 -436 -177 58 77 239 629 61 859 772 449 376 -35 -39 -98 177 34 -257 375 -37 -197 -281 -390 -484 -69 -145 -326 14 -452 -348 37 225 390 123 -131 -203 2 -241 161 1 -148 85 58 254 324 161 478 173 233 278 211 -38 -41 341 550 122 784 182 -591 -244 -679 -577 -294 -341 -793 -683 -709 -812 -654 -367 -572 -578 -452 -344 468 166 448 773 576 548 710 300 389 335 728 837 1004 1266 445 -112 82 -348 539 711 259 322 137 567 129 10 13 -370 -74 -276 -928 -793 -1842 -1644 -1154 -901 -682 -94 476 66 185 564 134 573 746 460 481 1013 337 -391 -221 -656 -723 202 -183 -1202 -838 -762 -692 343 309 238 40 207 -33 145 416 270 160 268 -613 -251 81 105 320 828 78 1037 956 590 497 -49 -55 -135 255 49 -394 586 -57 -315 -436 -589 -712 SS 20230701T140219.1Z 8582.584943 232 1 1.76 2 44.44 92.74 159.84 293.94 0.00 1 0.00 1 0 17 9.242e-03 6.919e-03 6.085e-03 4.073e-03 1.883739e-01 2.155595e-03 2.212044e-03 -6.000000e+00 5.483797e-03 232.59 -2.00 3.41 -2.00 314.99 0.00e+00 2.086188e-04 1.651199e-04 1.802081e-05 -6.000000e+00 2.148037e-04 290.67 -2.00 20.00 -2.00 314.72 0.00e+00 1.399 0.000 302.00 328.00 3 3.7904e+00 5.6012e-03 1.6966e-02 -6.0000e+00 1.3889e-02 1.5200e-02 6.1759e-03 9.5405e-03 -6.0000e+00 1.5021e-02 5.4795e-04 3.5225e-03 4.6445e-03 -6.0000e+00 8.7967e-03 -2.1732e-03 1.5425e-03 1.2928e-03 -6.0000e+00 3.6681e-03 2.4188e-03 9.9204e-05 1.1767e-04 1.7495e-05 -6.0000e+00 2.5835e-04 -2.2419e-02 1.1285e-05 12 9 1 12 1 1 999.00 22.72 0.20 -0.02242 -0.02167 2 20 1 8 0 528.920 20.01 22.72 35.68 27.05 26.73 28.8 1066.64 -650 82 -701 -1341 93 -4205 1452 -170 1605 1011 -1536 -471 -1072 -774 -1194 971 -1089 1198 -1339 1206 2150 -643 2067 -162 258 -35 1690 -1489 1189 670 1410 707 1780 1396 -966 -52 -1326 -415 240 138 -1011 -486 -773 -1262 -1263 -517 -828 -1193 -370 -929 -3 -127 203 2086 793 1049 265 824 -32 141 561 792 1724 1110 1289 -226 -469 -838 797 880 -366 623 -71 648 -177 232 16 -1083 -461 -155 -1461 -770 -1762 -1819 -1011 -135 -706 -130 -344 275 62 859 412 663 739 1074 304 938 -59 -413 -257 -133 -1115 238 -158 -448 -723 -920 -378 582 27 -395 13 268 413 624 362 288 293 -140 -531 -47 598 412 365 187 -161 500 1047 450 166 137 -205 -232 494 -154 25 74 -519 -748 78 -5 -371 -199 27 -238 -447 28 -1228 416 -52 526 352 -547 -164 -395 -307 -514 441 -518 570 -661 599 1077 -327 1038 -85 139 -19 932 -817 605 330 702 364 944 769 -527 -27 -723 -243 154 99 -784 -387 -628 -1042 -1040 -423 -673 -952 -288 -716 -2 -102 168 1755 690 918 235 732 -28 124 497 722 1628 1093 1285 -220 -433 -752 709 824 -368 646 -75 676 -180 224 15 -943 -395 -138 -1399 -779 -1878 -1993 -1138 -157 -854 -160 -431 341 74 979 447 688 763 1151 345 1124 -74 -525 -318 -159 -1297 272 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