File name: Pandora70s1_ChapelHillNC_20231201_L2Fit_fout2c1d20210323p1-8.txt File generation date: 20231202T060048.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 70 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora70_OF_v7d20200416.txt Instrument calibration file used: Pandora70s1_CF_v1d20210323.txt Level 1 file used: Pandora70s1_ChapelHillNC_20231201_L1_smca1c1d20210323p1-8.txt Full location name: Duke Forest, Chapel Hill (NC) Short location name: ChapelHillNC Country of location: USA Location latitude [deg]: 35.9708 Location longitude [deg]: -79.0933 Location altitude [m]: 50 Local noon date: 20231201 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 278 420 Nominal wavelengths inside fitting window [nm]: 305.0320 305.1727 305.3133 305.4539 305.5945 305.7351 305.8756 306.0162 306.1567 306.2973 306.4378 306.5783 306.7188 306.8593 306.9998 307.1402 307.2807 307.4211 307.5615 307.7020 307.8424 307.9828 308.1231 308.2635 308.4039 308.5442 308.6846 308.8249 308.9652 309.1055 309.2458 309.3861 309.5263 309.6666 309.8068 309.9470 310.0873 310.2275 310.3677 310.5078 310.6480 310.7882 310.9283 311.0685 311.2086 311.3487 311.4888 311.6289 311.7690 311.9090 312.0491 312.1891 312.3291 312.4692 312.6092 312.7492 312.8891 313.0291 313.1691 313.3090 313.4490 313.5889 313.7288 313.8687 314.0086 314.1484 314.2883 314.4282 314.5680 314.7078 314.8476 314.9874 315.1272 315.2670 315.4068 315.5465 315.6863 315.8260 315.9657 316.1054 316.2451 316.3848 316.5245 316.6641 316.8038 316.9434 317.0830 317.2226 317.3622 317.5018 317.6414 317.7810 317.9205 318.0601 318.1996 318.3391 318.4786 318.6181 318.7576 318.8970 319.0365 319.1759 319.3153 319.4548 319.5942 319.7336 319.8729 320.0123 320.1517 320.2910 320.4303 320.5696 320.7090 320.8482 320.9875 321.1268 321.2661 321.4053 321.5445 321.6838 321.8230 321.9622 322.1013 322.2405 322.3797 322.5188 322.6580 322.7971 322.9362 323.0753 323.2144 323.3534 323.4925 323.6316 323.7706 323.9096 324.0486 324.1876 324.3266 324.4656 324.6046 324.7435 324.8824 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231201T145137.4Z 8735.619182 301 1 0.91 2 65.88 145.91 77.33 291.53 0.00 1 0.00 1 0 17 1.826e-02 7.368e-03 1.329e-02 4.601e-03 3.004256e-01 2.338153e-03 3.543052e-03 -6.000000e+00 1.050143e-02 223.96 -2.00 3.41 -2.00 317.01 0.00e+00 3.239442e-04 2.898763e-04 6.003275e-05 -6.000000e+00 4.251571e-04 282.49 -2.00 20.00 -2.00 316.72 0.00e+00 2.430 0.000 302.00 328.00 3 2.4315e+00 6.0850e-03 2.8233e-02 -6.0000e+00 2.6070e-02 1.1266e-02 6.7951e-03 1.4730e-02 -6.0000e+00 2.8373e-02 -1.7575e-03 4.1361e-03 7.3780e-03 -6.0000e+00 1.6719e-02 -1.9534e-03 2.0702e-03 2.1655e-03 -6.0000e+00 7.1593e-03 2.9121e-03 6.2630e-04 1.3404e-04 2.5750e-05 -6.0000e+00 5.1221e-04 -2.5861e-02 1.8716e-04 12 9 1 12 9 1 -216.47 22.23 0.15 -0.02586 -0.02115 3 48 4 8 0 224.860 20.00 22.23 18.92 26.51 26.21 28.5 941.42 900000 -346 -7478 4098 -8188 -2705 -8576 3288 -878 -3332 -45 -4679 1316 -4336 4012 -1930 -219 -1923 3857 -3 -1544 229 782 2796 -2569 3828 -1091 1004 -2151 1440 -150 -86 2694 1387 -427 -922 356 -2098 317 -1896 -136 -438 -1291 -581 -2185 1735 -807 -289 -602 323 938 -626 2256 1442 1646 854 904 217 1976 273 789 677 642 2192 -23 449 -1085 -355 18 459 -153 -76 381 -285 160 424 -3 -912 403 -1091 -734 -565 -2150 -1330 -2120 -862 -668 -92 276 255 -34 1140 307 -312 1251 327 571 697 -195 147 -115 -552 -479 379 -372 -598 -1170 -233 85 -68 467 -557 515 -510 24 491 327 655 -164 33 -519 1 -109 223 370 528 22 1099 1359 567 209 -213 151 -301 493 40 -171 374 191 -296 -403 -661 -710 900000 -41 -994 487 -988 -291 -1005 376 -115 -482 -6 -705 206 -804 784 -442 -53 -488 971 -1 -431 63 217 799 -799 1170 -356 315 -653 414 -46 -28 905 499 -153 -318 127 -839 140 -974 -75 -255 -777 -354 -1350 1045 -493 -174 -360 191 569 -403 1488 995 1176 623 669 162 1448 200 582 518 517 1845 -20 382 -892 -284 14 391 -141 -73 370 -275 149 372 -2 -724 316 -915 -663 -547 -2224 -1415 -2342 -988 -792 -112 339 310 -40 1269 327 -322 1288 355 661 861 -255 195 -149 -692 -574 444 -452 -760 -1533 -313 118 -96 691 -849 779 -756 34 666 434 877 -227 47 -769 1 -161 323 519 719 29 1432 1807 789 301 -317 229 -462 775 66 -284 629 327 -504 -673 -1085 -1147 SS 20231201T152121.3Z 8735.639830 316 1 49.25 2 62.81 152.77 82.71 295.26 0.00 1 0.00 1 0 17 9.902e-02 8.602e-03 1.753e-02 3.803e-03 2.756056e-01 1.917028e-03 3.264449e-03 -6.000000e+00 5.692587e-02 223.96 -2.00 3.41 -2.00 317.84 0.00e+00 3.942090e-04 2.900689e-04 6.768988e-05 -6.000000e+00 2.300976e-03 282.48 -2.00 20.00 -2.00 317.54 0.00e+00 2.177 0.000 302.00 328.00 3 5.7490e+00 5.0459e-03 2.5524e-02 -6.0000e+00 1.4131e-01 2.9798e-02 5.6561e-03 1.3619e-02 -6.0000e+00 1.5375e-01 9.1904e-03 3.6359e-03 6.8706e-03 -6.0000e+00 9.0630e-02 -9.9453e-03 1.8798e-03 2.0427e-03 -6.0000e+00 3.8502e-02 1.3712e-04 -9.4802e-05 1.1376e-04 2.3887e-05 -6.0000e+00 2.7618e-03 -2.7220e-02 -3.0772e-06 11 8 0 10 0 0 99.99 22.28 0.63 -0.02722 -0.02793 92 20 1 8 0 535.250 19.95 22.28 19.52 26.51 26.32 28.5 945.10 8654 -915 -16098 106219 -4228 -1722 34611 3191 -6426 -1319 -439 -1612 4761 -8374 2643 49 362 3879 -3579 -1970 267 2987 987 1091 -223 3797 -1664 -1016 -2578 817 208 -13980 824 2557 955 -661 2509 -143 -620 -1545 -206 -1426 134 -190 -1628 588 -630 -453 -63 -248 498 1248 -49 1077 285 537 182 -142 1223 37 808 2804 1733 882 634 -130 94 94 310 826 659 -340 799 1623 -483 -558 564 -777 398 289 -1113 -749 -2575 -1640 -1566 -516 -162 735 -354 29 212 85 800 -135 980 1613 178 -162 844 -215 -189 -150 -518 -131 -1014 -949 -1125 -775 -713 220 216 -37 574 -294 -53 -226 -96 -136 313 460 -226 543 -201 660 -220 1066 158 973 610 503 567 132 85 -475 290 -148 -358 520 196 -56 -272 -533 -712 638 -82 -1742 3816 -368 -137 2054 271 -657 -139 -47 -175 531 -1191 386 8 65 697 -717 -404 55 601 204 237 -51 875 -415 -245 -588 175 47 -3800 210 685 254 -170 657 -43 -216 -641 -95 -701 67 -98 -849 301 -324 -228 -31 -122 251 666 -28 639 178 341 118 -93 784 24 520 1857 1241 683 508 -101 68 66 219 629 555 -306 728 1445 -418 -447 409 -534 268 211 -909 -672 -2532 -1675 -1674 -582 -191 892 -443 35 247 93 810 -131 941 1649 201 -201 1118 -291 -248 -188 -610 -150 -1227 -1218 -1502 -1075 -1030 330 340 -60 926 -461 -78 -313 -128 -184 441 685 -353 842 -310 993 -320 1470 211 1263 816 711 839 204 135 -767 482 -259 -647 952 366 -105 -493 -945 -1237 SS 20231201T152953.8Z 8735.645761 321 1 11.93 2 62.05 154.83 84.22 296.36 0.00 1 0.00 1 0 17 1.060e-02 5.773e-03 7.147e-03 2.768e-03 2.678569e-01 1.404650e-03 3.208160e-03 -6.000000e+00 6.093333e-03 223.96 -2.00 3.41 -2.00 316.70 0.00e+00 1.594613e-04 1.611142e-04 4.704436e-05 -6.000000e+00 2.462827e-04 282.48 -2.00 20.00 -2.00 316.41 0.00e+00 2.123 0.000 302.00 328.00 3 4.4371e+00 3.6423e-03 2.4860e-02 -6.0000e+00 1.5126e-02 2.4705e-02 4.0631e-03 1.3225e-02 -6.0000e+00 1.6458e-02 -3.3347e-03 2.4252e-03 6.6267e-03 -6.0000e+00 9.7009e-03 -2.9832e-03 1.1851e-03 1.9393e-03 -6.0000e+00 4.1213e-03 5.4786e-04 -1.2654e-04 8.0707e-05 2.3824e-05 -6.0000e+00 2.9561e-04 -2.6962e-02 1.6719e-05 12 1 1 12 1 1 99.79 22.28 0.28 -0.02696 -0.02791 9 9 1 8 0 1190.030 20.00 22.28 19.86 26.51 26.32 28.7 948.64 2148 -190 -3427 -3838 -512 -5579 2443 423 -2463 -443 395 -1968 -1785 -1544 -157 -719 -55 785 223 2396 1125 556 73 975 919 1379 1242 -1142 -20 805 1344 -1190 993 -14 -920 -652 -1871 -1253 -512 -627 -1209 -1778 155 -602 -202 -880 73 -495 -979 74 887 -118 -95 1219 631 994 583 -43 1051 207 1137 1117 1156 1847 785 185 -219 -59 807 756 203 224 -28 956 -319 -492 13 -199 92 -421 -765 -1258 -1865 -1406 -836 -1054 -459 36 -253 63 220 242 -206 614 -46 407 274 584 451 -491 -5 -485 -216 246 -355 -840 -721 -242 -569 417 375 144 -146 505 -129 206 191 235 321 -114 -29 -478 -67 -46 379 815 276 937 731 429 357 106 -340 88 226 243 -314 428 -138 -424 -346 -556 -296 275 -28 -538 -596 -70 -743 312 60 -392 -75 67 -343 -336 -325 -37 -187 -15 221 65 712 345 171 23 316 311 479 443 -405 -7 255 439 -418 364 -5 -354 -239 -725 -532 -244 -343 -728 -1122 99 -393 -132 -576 47 -316 -620 46 563 -80 -67 879 473 754 449 -34 806 158 871 886 966 1620 711 163 -184 -48 659 656 191 219 -27 938 -305 -444 11 -159 73 -354 -697 -1235 -1947 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