File name: Pandora70s1_ChapelHillNC_20240124_L2Fit_fout2c1d20210323p1-8.txt File generation date: 20240129T200306.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 70 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora70_OF_v7d20200416.txt Instrument calibration file used: Pandora70s1_CF_v1d20210323.txt Level 1 file used: Pandora70s1_ChapelHillNC_20240124_L1_smca1c1d20210323p1-8.txt Full location name: Duke Forest, Chapel Hill (NC) Short location name: ChapelHillNC Country of location: USA Location latitude [deg]: 35.9708 Location longitude [deg]: -79.0933 Location altitude [m]: 50 Local noon date: 20240124 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 278 420 Nominal wavelengths inside fitting window [nm]: 305.0320 305.1727 305.3133 305.4539 305.5945 305.7351 305.8756 306.0162 306.1567 306.2973 306.4378 306.5783 306.7188 306.8593 306.9998 307.1402 307.2807 307.4211 307.5615 307.7020 307.8424 307.9828 308.1231 308.2635 308.4039 308.5442 308.6846 308.8249 308.9652 309.1055 309.2458 309.3861 309.5263 309.6666 309.8068 309.9470 310.0873 310.2275 310.3677 310.5078 310.6480 310.7882 310.9283 311.0685 311.2086 311.3487 311.4888 311.6289 311.7690 311.9090 312.0491 312.1891 312.3291 312.4692 312.6092 312.7492 312.8891 313.0291 313.1691 313.3090 313.4490 313.5889 313.7288 313.8687 314.0086 314.1484 314.2883 314.4282 314.5680 314.7078 314.8476 314.9874 315.1272 315.2670 315.4068 315.5465 315.6863 315.8260 315.9657 316.1054 316.2451 316.3848 316.5245 316.6641 316.8038 316.9434 317.0830 317.2226 317.3622 317.5018 317.6414 317.7810 317.9205 318.0601 318.1996 318.3391 318.4786 318.6181 318.7576 318.8970 319.0365 319.1759 319.3153 319.4548 319.5942 319.7336 319.8729 320.0123 320.1517 320.2910 320.4303 320.5696 320.7090 320.8482 320.9875 321.1268 321.2661 321.4053 321.5445 321.6838 321.8230 321.9622 322.1013 322.2405 322.3797 322.5188 322.6580 322.7971 322.9362 323.0753 323.2144 323.3534 323.4925 323.6316 323.7706 323.9096 324.0486 324.1876 324.3266 324.4656 324.6046 324.7435 324.8824 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240124T144526.4Z 8789.614889 308 1 49.19 2 67.32 138.10 112.76 332.90 0.00 1 0.00 1 0 17 2.317e-02 5.520e-03 4.781e-03 1.272e-03 3.185281e-01 6.486229e-04 3.772919e-03 -6.000000e+00 1.336473e-02 224.50 -2.00 3.41 -2.00 317.47 0.00e+00 2.472523e-04 9.016945e-05 7.404825e-05 -6.000000e+00 5.397050e-04 279.38 -2.00 20.00 -2.00 317.18 0.00e+00 2.573 0.000 302.00 328.00 3 3.8776e+00 1.6998e-03 2.9957e-02 -6.0000e+00 3.3219e-02 3.5068e-02 1.8989e-03 1.5768e-02 -6.0000e+00 3.6129e-02 -3.0584e-03 1.2030e-03 7.9173e-03 -6.0000e+00 2.1281e-02 -4.1620e-03 6.2052e-04 2.3330e-03 -6.0000e+00 9.1134e-03 5.7590e-04 -5.1197e-04 3.7315e-05 2.7210e-05 -6.0000e+00 6.5005e-04 -3.7737e-02 -1.9465e-05 10 0 0 10 0 0 99.90 22.40 0.15 -0.03774 -0.04158 57 12 1 8 0 862.900 19.98 22.40 20.44 26.62 26.41 29.3 965.05 900000 2636 -8910 20270 -2054 -7067 6545 -221 -53 -1684 873 -5300 -1439 -4614 -1446 -782 -1550 1888 -741 783 -82 1760 191 733 132 -22 219 -1112 147 -242 1301 -4181 1080 796 -928 -655 -824 -464 -636 -550 -1315 -892 -415 -768 -214 -23 102 -970 -319 -621 1096 544 899 1093 570 604 733 656 821 562 629 1489 1197 1409 -307 -99 340 -518 491 438 153 120 315 664 61 210 -175 103 -373 200 -816 -717 -1744 -1802 -1101 -758 -704 -232 207 -77 87 616 285 366 556 589 202 908 379 -146 -210 -478 -566 44 2 -1146 -622 -539 -410 271 142 -175 60 231 -145 90 475 283 183 121 -303 -111 -54 57 468 475 256 627 777 343 464 118 -167 -37 197 65 -242 260 -50 -246 -269 -228 -554 900000 224 -897 1563 -177 -593 500 -19 -5 -182 95 -616 -177 -665 -232 -141 -302 374 -157 170 -18 392 44 175 33 -6 59 -298 37 -59 325 -1173 311 246 -289 -194 -254 -158 -246 -247 -661 -471 -225 -428 -119 -13 57 -536 -174 -339 607 321 554 704 384 415 511 462 572 388 437 1066 908 1134 -259 -81 266 -398 377 358 135 111 299 622 56 179 -140 78 -281 160 -712 -677 -1766 -1897 -1194 -860 -830 -279 253 -93 102 686 302 373 567 632 233 1118 497 -196 -275 -606 -685 52 2 -1464 -815 -728 -573 390 213 -272 93 350 -211 125 640 385 256 177 -457 -168 -81 84 668 657 346 829 1045 484 680 180 -260 -58 317 108 -415 451 -89 -433 -464 -385 -920 SS 20240124T160159.3Z 8789.668048 354 1 3.23 2 58.85 156.04 117.59 350.22 0.00 1 0.00 1 0 17 7.993e-03 5.725e-03 3.944e-03 2.112e-03 2.369629e-01 1.086349e-03 2.855375e-03 -6.000000e+00 4.610359e-03 224.50 -2.00 3.41 -2.00 315.89 0.00e+00 1.731950e-04 1.027737e-04 3.056109e-05 -6.000000e+00 1.861642e-04 279.38 -2.00 20.00 -2.00 315.61 0.00e+00 1.926 0.000 302.00 328.00 3 2.8638e+00 2.7939e-03 2.2384e-02 -6.0000e+00 1.1459e-02 2.0314e-02 3.1065e-03 1.1725e-02 -6.0000e+00 1.2463e-02 -2.6904e-03 1.8053e-03 5.8499e-03 -6.0000e+00 7.3409e-03 -8.5026e-04 8.4617e-04 1.6985e-03 -6.0000e+00 3.1439e-03 3.4011e-03 -4.0021e-04 6.1497e-05 2.1982e-05 -6.0000e+00 2.2421e-04 -3.7454e-02 2.5028e-05 12 1 1 12 1 1 6.59 22.42 0.21 -0.03745 -0.04046 10 41 4 8 0 265.070 20.00 22.42 22.91 26.73 26.41 29.6 982.57 900000 46 -2928 -228 -2530 -1017 -1982 487 -358 -214 546 -1217 438 -435 1820 -714 -720 16 740 1446 549 143 973 1094 -365 488 -89 -44 -153 536 1778 307 2166 1155 -962 -1540 -1623 -1346 -931 -303 -519 -749 -1191 -686 -552 -107 -1028 -654 -746 -166 849 337 715 970 369 605 763 324 634 648 654 1296 907 1556 685 -171 -27 -427 107 337 226 48 320 181 124 121 292 -344 -465 -242 -857 -406 -1645 -1631 -869 -866 -966 -205 141 -301 -23 443 468 531 1012 342 674 898 287 -309 -95 -687 -359 217 -67 -820 -452 -811 -699 460 64 -263 121 312 -53 -64 740 298 447 -3 -297 35 -113 -11 234 514 217 800 931 485 307 68 33 -143 305 -204 -471 335 -23 -232 -299 -268 -488 900000 10 -685 -52 -535 -200 -394 102 -83 -53 137 -307 114 -125 570 -250 -265 6 283 561 220 58 389 452 -158 217 -41 -20 -64 216 729 132 957 544 -453 -692 -750 -678 -517 -188 -351 -527 -862 -506 -406 -78 -750 -468 -526 -116 599 247 544 760 299 495 632 270 525 533 537 1098 807 1439 653 -159 -24 -368 92 302 217 48 328 183 123 114 257 -292 -385 -210 -800 -401 -1734 -1766 -968 -1005 -1164 -252 176 -374 -28 505 506 552 1044 370 769 1083 367 -403 -121 -846 -427 250 -80 -1024 -580 -1070 -947 638 92 -386 177 443 -73 -84 935 382 588 -4 -420 50 -160 -15 317 672 278 1004 1183 639 417 95 47 -205 444 -309 -729 525 -36 -368 -469 -412 -742 SS 20240124T161224.6Z 8789.675284 360 1 30.70 2 58.04 158.76 117.91 352.71 0.00 1 0.00 1 0 17 1.204e-02 6.258e-03 4.641e-03 2.185e-03 2.328016e-01 1.119967e-03 2.794288e-03 -6.000000e+00 6.950274e-03 224.50 -2.00 3.41 -2.00 316.25 0.00e+00 2.535985e-04 1.150783e-04 3.481558e-05 -6.000000e+00 2.805958e-04 279.38 -2.00 20.00 -2.00 315.97 0.00e+00 1.882 0.000 302.00 328.00 3 5.1886e+00 2.8920e-03 2.1913e-02 -6.0000e+00 1.7275e-02 4.2163e-02 3.2185e-03 1.1518e-02 -6.0000e+00 1.8786e-02 -4.4982e-04 1.8898e-03 5.7518e-03 -6.0000e+00 1.1065e-02 -4.0316e-03 9.0333e-04 1.6755e-03 -6.0000e+00 4.7402e-03 3.4584e-04 9.8866e-06 6.3930e-05 2.1112e-05 -6.0000e+00 3.3784e-04 -3.8375e-02 8.4124e-05 12 1 1 12 1 1 99.98 22.43 0.14 -0.03837 -0.03830 17 6 1 8 0 1704.650 20.00 22.43 23.65 26.73 26.41 29.7 987.56 900000 1929 -2901 -4296 1331 -3828 6768 -405 2339 519 1114 -2178 -632 -2517 -835 1437 -279 2824 67 1437 -755 868 675 708 963 559 922 -547 611 -1821 621 -3726 1475 241 -482 -686 -1240 -70 -937 -544 -1655 -1060 313 -1031 -474 -382 -561 -753 -145 -993 849 104 621 1036 375 683 506 660 556 211 771 1546 1370 1655 -299 85 809 -386 629 -118 310 193 421 1124 -3 168 -72 -836 -83 -349 -680 -922 -1546 -1960 -981 -1194 -277 -100 -288 -156 303 416 77 -126 489 1340 74 985 926 -145 -139 -74 -865 -239 -199 -1200 -234 -436 -434 418 252 -26 250 -85 -121 123 225 319 -13 241 -525 -189 30 81 442 627 236 472 819 351 348 -145 8 -232 63 459 -523 281 65 -252 -176 -219 -530 900000 352 -580 -860 230 -637 1046 -72 443 108 235 -467 -142 -639 -232 433 -90 914 23 500 -273 310 242 264 373 223 376 -221 229 -665 228 -1480 591 103 -204 -276 -518 -32 -483 -319 -1080 -720 216 -731 -335 -269 -393 -519 -97 -664 569 74 454 783 295 544 408 536 447 169 617 1273 1189 1508 -283 78 697 -324 523 -105 295 193 429 1130 -3 156 -62 -684 -66 -294 -618 -904 -1614 -2125 -1093 -1397 -335 -123 -364 -196 366 477 83 -130 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