File name: Pandora70s1_ChapelHillNC_20240518_L2Fit_fwvt1c1d20210323p1-8.txt File generation date: 20240519T052435.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 70 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora70_OF_v7d20200416.txt Instrument calibration file used: Pandora70s1_CF_v1d20210323.txt Level 1 file used: Pandora70s1_ChapelHillNC_20240518_L1_smca1c1d20210323p1-8.txt Full location name: Duke Forest, Chapel Hill (NC) Short location name: ChapelHillNC Country of location: USA Location latitude [deg]: 35.9708 Location longitude [deg]: -79.0933 Location altitude [m]: 50 Local noon date: 20240518 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1704 1854 Nominal wavelengths inside fitting window [nm]: 492.0608 492.1813 492.3018 492.4223 492.5428 492.6632 492.7836 492.9041 493.0245 493.1448 493.2652 493.3856 493.5059 493.6262 493.7465 493.8668 493.9870 494.1073 494.2275 494.3477 494.4679 494.5881 494.7083 494.8285 494.9486 495.0687 495.1888 495.3089 495.4290 495.5490 495.6690 495.7891 495.9091 496.0291 496.1490 496.2690 496.3889 496.5088 496.6287 496.7486 496.8685 496.9884 497.1082 497.2280 497.3478 497.4676 497.5874 497.7071 497.8269 497.9466 498.0663 498.1860 498.3057 498.4253 498.5450 498.6646 498.7842 498.9038 499.0234 499.1429 499.2624 499.3820 499.5015 499.6210 499.7404 499.8599 499.9793 500.0988 500.2182 500.3376 500.4569 500.5763 500.6956 500.8150 500.9343 501.0536 501.1728 501.2921 501.4113 501.5306 501.6498 501.7690 501.8881 502.0073 502.1264 502.2456 502.3647 502.4838 502.6028 502.7219 502.8409 502.9600 503.0790 503.1980 503.3169 503.4359 503.5548 503.6737 503.7927 503.9115 504.0304 504.1493 504.2681 504.3869 504.5057 504.6245 504.7433 504.8621 504.9808 505.0995 505.2182 505.3369 505.4556 505.5742 505.6929 505.8115 505.9301 506.0487 506.1672 506.2858 506.4043 506.5229 506.6414 506.7598 506.8783 506.9968 507.1152 507.2336 507.3520 507.4704 507.5888 507.7071 507.8254 507.9437 508.0620 508.1803 508.2986 508.4168 508.5351 508.6533 508.7715 508.8896 509.0078 509.1259 509.2441 509.3622 509.4803 509.5983 509.7164 509.8344 509.9524 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240518T122212.2Z 8904.515419 169 1 6.47 2 64.84 83.12 140.10 331.09 0.00 1 0.00 1 0 15 2.340e-03 2.333e-03 1.129e-04 1.128e-04 4.431068e+03 7.071102e+00 3.076244e+02 -6.000000e+00 1.303962e+02 286.76 -2.00 20.00 -2.00 505.27 0.00e+00 4.447856e-04 3.112978e-06 3.312673e-05 -6.000000e+00 6.583411e-05 286.76 -2.00 20.00 -2.00 500.45 0.00e+00 1.483554e-01 2.215034e-03 3.033938e-02 -6.000000e+00 4.612026e-02 231.49 -2.00 3.41 -2.00 502.04 0.00e+00 2.337 0.000 489.00 513.00 1 1.4766e+00 1.6986e-04 4.2827e-03 -6.0000e+00 3.5374e-03 -8.3190e-03 4.3811e-05 7.4606e-04 -6.0000e+00 9.1983e-04 3.1351e-01 7.8896e-04 1.0628e-05 3.6969e-05 -6.0000e+00 2.2957e-04 -2.0892e-02 5.0920e-05 10 0 0 10 0 0 99.88 22.77 1.88 -0.02089 -0.01542 923 201 2 2 0 6.330 19.98 22.77 29.09 26.94 26.73 31.1 1027.44 -375 -238 -125 -57 180 418 479 352 385 391 350 121 -34 34 -64 -100 25 112 79 102 214 231 205 266 239 278 331 -19 -230 -125 -279 -444 -196 14 -195 -99 58 -33 -214 -234 -175 -226 -92 10 64 30 83 128 -44 -227 -303 -409 -514 -422 -242 -174 -99 75 119 207 279 304 280 317 290 185 140 -4 -165 -249 -176 -211 -195 -81 -92 -176 -179 -133 -370 -348 -316 -417 -397 -154 -143 -260 -230 -146 -173 -244 -119 54 112 36 172 296 112 -120 -208 -308 -504 -440 -230 -138 -183 -124 -27 -84 -64 -22 -56 -40 147 226 283 415 504 363 273 274 122 119 171 157 120 167 257 220 232 264 82 12 60 -149 -250 -38 25 -101 127 237 174 204 302 266 207 106 -78 -206 -208 -314 -349 -363 -233 -123 -58 183 433 498 370 404 405 359 125 -34 35 -65 -102 26 116 82 106 224 242 214 278 251 293 348 -20 -238 -127 -279 -447 -200 14 -204 -104 60 -35 -221 -240 -178 -231 -96 10 67 31 86 132 -45 -228 -300 -402 -499 -410 -240 -175 -100 77 120 213 286 307 285 323 294 185 140 -4 -164 -244 -170 -206 -192 -81 -91 -174 -177 -130 -356 -337 -307 -402 -386 -150 -139 -257 -228 -145 -172 -242 -117 53 113 36 172 291 110 -117 -197 -290 -472 -417 -219 -134 -182 -123 -26 -84 -63 -21 -55 -40 147 227 283 416 508 369 276 274 122 117 167 153 118 164 253 216 228 258 80 12 58 -142 -237 -36 25 -99 124 233 173 202 300 265 207 105 -78 -203 -203 -303 -338 SQ 20240518T122219.0Z 8904.515498 169 2 6.42 2 64.81 83.14 140.11 331.12 0.00 1 0.00 1 0 15 2.306e-03 2.302e-03 1.478e-04 1.476e-04 4.449789e+03 9.290566e+00 3.085902e+02 -6.000000e+00 1.285236e+02 286.76 -2.00 20.00 -2.00 505.27 0.00e+00 4.380700e-04 4.070581e-06 3.310587e-05 -6.000000e+00 6.488749e-05 286.76 -2.00 20.00 -2.00 500.44 0.00e+00 1.447597e-01 2.901397e-03 3.051067e-02 -6.000000e+00 4.545443e-02 231.49 -2.00 3.41 -2.00 502.03 0.00e+00 2.335 0.000 489.00 513.00 1 1.9943e+00 2.2242e-04 4.2879e-03 -6.0000e+00 3.4864e-03 -5.8464e-03 5.7394e-05 7.4966e-04 -6.0000e+00 9.0647e-04 1.8693e-01 6.1366e-04 1.3920e-05 3.6657e-05 -6.0000e+00 2.2627e-04 -2.1955e-02 6.3705e-05 10 0 0 10 0 0 99.94 22.77 1.90 -0.02195 -0.01770 923 201 2 2 0 6.330 19.98 22.77 29.09 26.94 26.73 31.2 1027.44 -349 -231 -128 -85 197 445 476 361 373 388 311 106 -1 50 -49 -90 57 126 90 101 197 213 180 251 190 284 288 3 -223 -122 -289 -441 -218 22 -194 -119 76 -23 -203 -209 -180 -200 -104 15 52 39 93 100 -38 -240 -293 -392 -521 -429 -253 -192 -77 79 115 242 253 292 306 312 308 145 147 -23 -194 -251 -195 -191 -211 -99 -103 -168 -151 -105 -346 -321 -330 -421 -398 -162 -114 -267 -243 -167 -183 -234 -101 52 105 33 185 290 88 -94 -233 -317 -479 -430 -222 -127 -171 -142 -61 -90 -24 -22 -90 -2 125 196 316 418 498 367 280 277 136 111 160 151 97 148 288 232 229 255 75 -47 59 -127 -200 -30 19 -112 109 203 197 191 299 239 219 91 -50 -209 -228 -259 -327 -339 -226 -126 -85 202 457 498 382 394 405 321 108 -1 50 -49 -91 59 129 95 106 206 224 189 263 200 300 303 3 -232 -123 -292 -448 -219 23 -204 -124 79 -24 -210 -214 -184 -206 -108 15 53 41 96 102 -39 -241 -292 -388 -510 -421 -248 -194 -78 81 119 249 259 300 310 317 310 148 147 -23 -190 -247 -190 -186 -208 -97 -102 -166 -148 -102 -334 -307 -316 -408 -389 -159 -111 -264 -241 -165 -181 -232 -101 51 105 34 185 284 86 -90 -221 -295 -452 -402 -213 -124 -169 -142 -61 -89 -24 -22 -88 -2 124 196 318 422 505 368 280 280 135 109 157 149 94 144 280 226 222 247 72 -46 56 -121 -188 -29 18 -109 107 202 194 189 297 239 220 92 -49 -207 -221 -247 -314 SQ 20240518T122225.7Z 8904.515575 169 3 6.40 2 64.79 83.15 140.12 331.16 0.00 1 0.00 1 0 15 2.474e-03 2.464e-03 2.571e-04 2.566e-04 4.416452e+03 1.618448e+01 3.042379e+02 -6.000000e+00 1.378665e+02 286.76 -2.00 20.00 -2.00 505.27 0.00e+00 4.608021e-04 7.086533e-06 3.338795e-05 -6.000000e+00 6.960229e-05 286.76 -2.00 20.00 -2.00 500.42 0.00e+00 1.362797e-01 5.054411e-03 3.077744e-02 -6.000000e+00 4.875362e-02 231.49 -2.00 3.41 -2.00 502.02 0.00e+00 2.333 0.000 489.00 513.00 1 2.9930e+00 3.8765e-04 4.2967e-03 -6.0000e+00 3.7395e-03 -6.0643e-03 9.9909e-05 7.4995e-04 -6.0000e+00 9.7214e-04 6.8900e-02 5.2857e-04 2.4210e-05 3.5393e-05 -6.0000e+00 2.4272e-04 -2.2487e-02 7.5319e-05 10 0 0 10 0 0 99.99 22.77 1.84 -0.02249 -0.01882 923 201 2 2 0 6.330 19.98 22.77 29.09 26.94 26.73 31.2 1027.90 -474 -299 -261 -122 173 389 478 344 347 374 302 70 -44 -37 -117 -154 114 131 99 123 227 280 263 243 225 325 333 27 -178 -143 -337 -459 -216 18 -164 -83 85 16 -208 -217 -152 -202 -56 19 73 70 151 122 -13 -287 -362 -399 -517 -463 -237 -184 -101 150 134 241 334 366 315 365 285 212 157 -39 -159 -248 -235 -207 -222 -78 -91 -169 -150 -117 -374 -368 -362 -458 -364 -144 -139 -227 -265 -187 -230 -272 -111 34 128 83 223 315 135 -94 -287 -325 -503 -413 -268 -162 -178 -64 -24 -88 -76 2 -100 17 126 195 334 441 536 391 283 311 155 88 136 193 131 148 269 254 225 246 47 -6 5 -147 -272 -27 39 -96 109 214 198 211 308 231 234 35 -61 -259 -291 -399 -360 -459 -291 -262 -123 179 400 500 365 367 391 312 72 -46 -37 -118 -157 118 133 104 131 242 300 274 254 236 341 349 28 -185 -144 -334 -457 -218 19 -171 -87 89 17 -213 -226 -158 -206 -57 20 77 74 158 127 -13 -296 -361 -387 -496 -445 -232 -186 -102 153 137 246 340 374 323 375 292 214 156 -38 -155 -244 -229 -203 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