File name: Pandora70s1_ChapelHillNC_20240719_L2Fit_fout2c1d20210323p1-8.txt File generation date: 20240720T053005.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 70 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora70_OF_v7d20200416.txt Instrument calibration file used: Pandora70s1_CF_v1d20210323.txt Level 1 file used: Pandora70s1_ChapelHillNC_20240719_L1_smca1c1d20210323p1-8.txt Full location name: Duke Forest, Chapel Hill (NC) Short location name: ChapelHillNC Country of location: USA Location latitude [deg]: 35.9708 Location longitude [deg]: -79.0933 Location altitude [m]: 50 Local noon date: 20240719 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 278 420 Nominal wavelengths inside fitting window [nm]: 305.0320 305.1727 305.3133 305.4539 305.5945 305.7351 305.8756 306.0162 306.1567 306.2973 306.4378 306.5783 306.7188 306.8593 306.9998 307.1402 307.2807 307.4211 307.5615 307.7020 307.8424 307.9828 308.1231 308.2635 308.4039 308.5442 308.6846 308.8249 308.9652 309.1055 309.2458 309.3861 309.5263 309.6666 309.8068 309.9470 310.0873 310.2275 310.3677 310.5078 310.6480 310.7882 310.9283 311.0685 311.2086 311.3487 311.4888 311.6289 311.7690 311.9090 312.0491 312.1891 312.3291 312.4692 312.6092 312.7492 312.8891 313.0291 313.1691 313.3090 313.4490 313.5889 313.7288 313.8687 314.0086 314.1484 314.2883 314.4282 314.5680 314.7078 314.8476 314.9874 315.1272 315.2670 315.4068 315.5465 315.6863 315.8260 315.9657 316.1054 316.2451 316.3848 316.5245 316.6641 316.8038 316.9434 317.0830 317.2226 317.3622 317.5018 317.6414 317.7810 317.9205 318.0601 318.1996 318.3391 318.4786 318.6181 318.7576 318.8970 319.0365 319.1759 319.3153 319.4548 319.5942 319.7336 319.8729 320.0123 320.1517 320.2910 320.4303 320.5696 320.7090 320.8482 320.9875 321.1268 321.2661 321.4053 321.5445 321.6838 321.8230 321.9622 322.1013 322.2405 322.3797 322.5188 322.6580 322.7971 322.9362 323.0753 323.2144 323.3534 323.4925 323.6316 323.7706 323.9096 324.0486 324.1876 324.3266 324.4656 324.6046 324.7435 324.8824 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240719T151424.6Z 8966.635007 9 1 53.96 2 31.92 109.90 170.51 319.74 0.00 1 0.00 1 0 17 6.872e-03 5.765e-03 1.412e-04 1.022e-04 1.675840e-01 5.424993e-05 1.993844e-03 -6.000000e+00 4.072797e-03 232.28 -2.00 3.41 -2.00 314.60 0.00e+00 1.532616e-04 3.886609e-06 1.352926e-05 -6.000000e+00 1.597133e-04 292.01 -2.00 20.00 -2.00 314.36 0.00e+00 1.177 0.000 302.00 328.00 3 5.4336e-01 1.4045e-04 1.4587e-02 -6.0000e+00 1.0308e-02 -3.4474e-03 1.5465e-04 8.5191e-03 -6.0000e+00 1.1150e-02 -1.2438e-03 8.8165e-05 4.1599e-03 -6.0000e+00 6.5316e-03 -2.4799e-03 3.8107e-05 1.1597e-03 -6.0000e+00 2.7251e-03 8.1110e-02 -2.0195e-05 2.9479e-06 1.6194e-05 -6.0000e+00 1.9208e-04 -2.1238e-02 4.7409e-05 10 0 0 10 0 0 99.15 22.87 0.25 -0.02124 -0.02139 3568 778 2 8 0 13.780 20.03 22.87 38.30 27.15 26.83 33.2 1073.04 -361 -626 -547 -1445 -1961 -1053 -618 545 1050 358 -534 -352 -110 -652 508 17 -178 156 474 763 838 476 1313 687 469 545 296 -158 -84 1039 1261 1000 1880 483 -1286 -764 -1488 -1287 -495 -463 -1099 -876 -881 -1060 -633 -498 -678 -561 -585 -393 580 372 774 926 664 582 920 391 528 518 895 935 1110 1310 388 -165 9 -559 358 556 96 151 62 290 52 45 85 -316 -77 -229 -939 -744 -1657 -1532 -1088 -860 -746 -253 142 -56 -8 526 170 611 853 432 469 863 250 -292 -139 -488 -569 322 -90 -931 -621 -576 -550 237 116 56 -7 167 7 271 465 289 282 299 -342 -119 37 83 231 647 213 983 924 487 447 -10 -96 -83 185 28 -314 271 -147 -386 -265 -421 -494 -134 -238 -215 -552 -711 -346 -207 195 384 142 -214 -138 -46 -281 239 9 -91 81 251 415 465 263 721 396 265 317 176 -90 -46 567 657 542 1061 291 -756 -419 -866 -793 -334 -352 -898 -715 -740 -908 -537 -419 -561 -468 -470 -307 456 310 641 802 600 510 814 350 466 472 824 866 1054 1322 387 -162 9 -516 325 526 97 157 66 305 54 43 80 -271 -67 -205 -902 -754 -1765 -1642 -1227 -1006 -892 -313 180 -70 -10 606 186 640 880 459 525 1025 313 -372 -169 -583 -660 362 -105 -1136 -789 -741 -739 317 158 79 -10 224 9 327 556 351 350 387 -455 -160 49 111 303 798 260 1148 1104 616 571 -13 -125 -110 248 39 -452 397 -216 -563 -387 -600 -710 SS 20240719T152045.5Z 8966.639416 12 1 36.67 2 30.71 111.58 171.24 326.69 0.00 1 0.00 1 0 17 6.822e-03 5.609e-03 8.696e-04 5.925e-04 1.661376e-01 3.136632e-04 1.970532e-03 -6.000000e+00 4.043571e-03 232.28 -2.00 3.41 -2.00 314.88 0.00e+00 1.588000e-04 2.348842e-05 1.523122e-05 -6.000000e+00 1.585589e-04 292.01 -2.00 20.00 -2.00 314.61 0.00e+00 1.163 0.000 302.00 328.00 3 3.6050e+00 8.1381e-04 1.4422e-02 -6.0000e+00 1.0234e-02 1.9692e-02 8.9729e-04 8.4406e-03 -6.0000e+00 1.1070e-02 4.0053e-04 5.1231e-04 4.1236e-03 -6.0000e+00 6.4846e-03 -3.4558e-03 2.2353e-04 1.1519e-03 -6.0000e+00 2.7056e-03 3.8285e-03 7.2942e-07 1.7118e-05 1.5893e-05 -6.0000e+00 1.9069e-04 -2.1432e-02 5.5047e-05 12 1 1 12 1 1 100.00 22.88 0.21 -0.02143 -0.02143 252 77 1 8 0 139.400 19.97 22.88 38.70 27.15 26.83 32.7 1073.37 -338 -543 -956 -396 -1982 -1046 -532 721 1017 413 -500 -626 436 -970 343 -105 -289 -24 278 739 819 750 1169 722 345 427 219 -191 -61 1114 1298 551 2055 431 -1189 -875 -1352 -1634 -395 -523 -1032 -822 -828 -986 -577 -555 -663 -624 -592 -461 588 357 844 955 705 574 963 391 582 477 991 925 1069 1385 307 -173 -45 -693 289 648 167 209 166 434 111 -48 116 -328 -191 -387 -997 -658 -1645 -1462 -1088 -842 -729 -176 116 59 48 469 197 347 762 394 487 845 319 -168 -171 -458 -570 213 -196 -881 -683 -557 -472 286 203 33 83 159 -37 129 400 226 217 340 -351 -80 56 88 122 664 181 914 880 436 460 -66 -60 -85 137 46 -292 267 -118 -338 -265 -333 -495 -110 -193 -330 -140 -627 -300 -155 224 347 153 -187 -228 167 -388 150 -50 -136 -12 136 369 417 380 590 382 190 241 126 -106 -31 558 659 293 1056 237 -637 -466 -715 -973 -255 -378 -842 -664 -688 -834 -483 -462 -542 -518 -473 -358 459 295 687 813 626 517 874 360 527 426 893 833 1029 1349 308 -172 -40 -624 257 593 172 218 178 456 112 -46 105 -274 -163 -337 -922 -670 -1743 -1620 -1212 -1009 -885 -221 149 75 57 531 214 363 784 414 560 1022 402 -216 -210 -556 -647 245 -232 -1081 -874 -714 -631 396 283 47 116 219 -49 156 483 277 269 454 -479 -111 77 116 159 815 222 1072 1055 552 583 -87 -81 -111 186 64 -423 395 -179 -513 -389 -478 -692 SS 20240719T152619.7Z 8966.643283 15 1 2.37 2 29.67 113.14 171.76 333.65 0.00 1 0.00 1 0 17 7.259e-03 6.144e-03 2.210e-03 1.646e-03 1.643077e-01 8.744955e-04 1.961596e-03 -6.000000e+00 4.302037e-03 232.28 -2.00 3.41 -2.00 314.42 0.00e+00 1.600013e-04 6.037676e-05 1.226347e-05 -6.000000e+00 1.687010e-04 292.01 -2.00 20.00 -2.00 314.19 0.00e+00 1.150 0.000 302.00 328.00 3 3.0103e+00 2.2630e-03 1.4277e-02 -6.0000e+00 1.0888e-02 1.6653e-02 2.4901e-03 8.3661e-03 -6.0000e+00 1.1778e-02 -9.2717e-04 1.4193e-03 4.0845e-03 -6.0000e+00 6.8992e-03 -3.1339e-03 6.1091e-04 1.1373e-03 -6.0000e+00 2.8785e-03 7.0629e-03 -6.9874e-05 4.7295e-05 1.6325e-05 -6.0000e+00 2.0289e-04 -2.1525e-02 4.1725e-05 12 1 1 12 1 1 97.48 22.89 0.26 -0.02152 -0.02205 11 55 1 8 0 196.640 20.03 22.89 38.61 27.15 26.83 32.5 1072.54 -993 -100 -894 -457 -2239 -1273 -658 -93 997 -3 -182 -354 151 -553 218 36 68 116 741 1125 553 611 1282 919 -48 810 236 -126 -3 1063 1223 907 2406 781 -1123 -1148 -1268 -1421 -416 -547 -1465 -598 -1325 -747 -432 -588 -856 -614 -840 -459 455 129 783 896 577 730 851 402 821 149 1061 1055 1172 1518 395 -397 -33 -729 375 268 143 135 75 453 -1 115 67 -535 -136 -38 -833 -518 -1553 -1382 -1149 -912 -564 -161 175 -270 89 563 291 871 953 210 485 823 341 -434 -435 -446 -581 469 -312 -1096 -512 -656 -528 62 107 210 137 172 -101 123 552 339 156 267 -534 -248 221 24 362 669 366 903 1035 443 622 -60 -52 -186 235 86 -271 254 -71 -271 -359 -404 -708 -367 -40 -374 -183 -858 -442 -232 -35 385 -1 -76 -146 65 -251 108 18 36 63 412 641 323 354 739 525 -29 492 147 -76 -2 570 665 513 1405 461 -684 -656 -763 -911 -293 -415 -1202 -510 -1121 -639 -366 -517 -742 -511 -704 -373 372 107 674 772 519 664 781 373 749 135 967 969 1152 1523 409 -388 -32 -664 336 251 144 140 80 472 -1 113 61 -471 -116 -34 -785 -516 -1630 -1517 -1282 -1057 -669 -198 220 -337 107 639 313 891 960 228 553 963 420 -545 -523 -523 -661 535 -370 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