File name: Pandora70s1_ChapelHillNC_20240820_L2Fit_fout2c1d20210323p1-8.txt File generation date: 20240821T052434.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 70 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora70_OF_v7d20200416.txt Instrument calibration file used: Pandora70s1_CF_v1d20210323.txt Level 1 file used: Pandora70s1_ChapelHillNC_20240820_L1_smca1c1d20210323p1-8.txt Full location name: Duke Forest, Chapel Hill (NC) Short location name: ChapelHillNC Country of location: USA Location latitude [deg]: 35.9708 Location longitude [deg]: -79.0933 Location altitude [m]: 50 Local noon date: 20240820 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 278 420 Nominal wavelengths inside fitting window [nm]: 305.0320 305.1727 305.3133 305.4539 305.5945 305.7351 305.8756 306.0162 306.1567 306.2973 306.4378 306.5783 306.7188 306.8593 306.9998 307.1402 307.2807 307.4211 307.5615 307.7020 307.8424 307.9828 308.1231 308.2635 308.4039 308.5442 308.6846 308.8249 308.9652 309.1055 309.2458 309.3861 309.5263 309.6666 309.8068 309.9470 310.0873 310.2275 310.3677 310.5078 310.6480 310.7882 310.9283 311.0685 311.2086 311.3487 311.4888 311.6289 311.7690 311.9090 312.0491 312.1891 312.3291 312.4692 312.6092 312.7492 312.8891 313.0291 313.1691 313.3090 313.4490 313.5889 313.7288 313.8687 314.0086 314.1484 314.2883 314.4282 314.5680 314.7078 314.8476 314.9874 315.1272 315.2670 315.4068 315.5465 315.6863 315.8260 315.9657 316.1054 316.2451 316.3848 316.5245 316.6641 316.8038 316.9434 317.0830 317.2226 317.3622 317.5018 317.6414 317.7810 317.9205 318.0601 318.1996 318.3391 318.4786 318.6181 318.7576 318.8970 319.0365 319.1759 319.3153 319.4548 319.5942 319.7336 319.8729 320.0123 320.1517 320.2910 320.4303 320.5696 320.7090 320.8482 320.9875 321.1268 321.2661 321.4053 321.5445 321.6838 321.8230 321.9622 322.1013 322.2405 322.3797 322.5188 322.6580 322.7971 322.9362 323.0753 323.2144 323.3534 323.4925 323.6316 323.7706 323.9096 324.0486 324.1876 324.3266 324.4656 324.6046 324.7435 324.8824 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240820T181712.9Z 8998.761955 7 1 29.40 2 27.19 212.16 153.56 1.12 0.00 1 0.00 1 0 17 6.804e-03 5.675e-03 2.411e-04 1.683e-04 1.659271e-01 8.877868e-05 1.983094e-03 -6.000000e+00 4.014408e-03 231.05 -2.00 3.41 -2.00 314.76 0.00e+00 1.473158e-04 6.569048e-06 1.424110e-05 -6.000000e+00 1.581337e-04 292.20 -2.00 20.00 -2.00 314.52 0.00e+00 1.124 0.000 302.00 328.00 3 9.1894e-01 2.2958e-04 1.4076e-02 -6.0000e+00 1.0130e-02 3.6988e-03 2.5318e-04 8.4004e-03 -6.0000e+00 1.0968e-02 1.2571e-03 1.4445e-04 4.1207e-03 -6.0000e+00 6.4309e-03 -2.8213e-03 6.2972e-05 1.1558e-03 -6.0000e+00 2.6898e-03 5.8747e-02 3.7713e-05 4.8599e-06 1.6055e-05 -6.0000e+00 1.9012e-04 -2.0826e-02 5.5036e-05 10 0 0 10 0 0 99.99 22.84 0.22 -0.02083 -0.02054 2642 576 2 8 0 10.210 20.00 22.84 35.21 27.05 26.83 32.9 1042.08 -514 -710 -597 -1559 -1964 -1149 -653 357 1049 268 -501 -409 -139 -626 515 69 -191 201 473 746 837 381 1261 676 418 509 322 -200 18 1015 1236 1011 1855 503 -1206 -694 -1466 -1216 -498 -400 -1101 -808 -838 -998 -552 -473 -641 -550 -552 -365 631 388 778 959 686 579 923 401 510 471 810 895 1041 1268 342 -195 -2 -588 389 547 99 187 92 354 38 40 38 -284 -82 -272 -977 -773 -1655 -1554 -1083 -909 -741 -271 160 -64 -19 506 130 580 829 455 460 858 258 -281 -130 -509 -570 313 -86 -903 -580 -555 -477 268 181 80 31 176 -16 243 422 241 224 277 -378 -121 26 103 237 646 219 981 907 500 478 -1 -64 -71 173 39 -347 261 -175 -351 -275 -427 -502 -167 -253 -220 -557 -669 -355 -206 120 359 99 -187 -149 -54 -268 225 33 -96 102 246 399 456 207 680 358 230 288 186 -112 10 511 630 536 1023 277 -692 -371 -833 -726 -323 -291 -904 -656 -700 -850 -465 -395 -527 -460 -444 -285 496 323 639 823 615 526 845 353 465 425 738 814 1012 1249 346 -196 -2 -535 349 507 98 198 99 376 39 39 35 -240 -71 -239 -916 -798 -1779 -1668 -1224 -1057 -913 -332 200 -79 -23 582 143 586 867 486 513 1009 317 -352 -162 -602 -658 350 -103 -1128 -723 -725 -623 363 258 113 45 236 -21 300 497 289 283 362 -506 -163 34 139 302 810 263 1174 1110 619 620 -1 -85 -95 241 55 -495 380 -263 -524 -398 -628 -720 SS 20240820T181742.3Z 8998.762295 7 2 28.91 2 27.24 212.40 153.56 1.38 0.00 1 0.00 1 0 17 6.880e-03 5.779e-03 1.741e-04 1.262e-04 1.662032e-01 6.678338e-05 1.988372e-03 -6.000000e+00 4.059506e-03 231.05 -2.00 3.41 -2.00 314.57 0.00e+00 1.403052e-04 4.760725e-06 1.332051e-05 -6.000000e+00 1.599101e-04 292.20 -2.00 20.00 -2.00 314.32 0.00e+00 1.124 0.000 302.00 328.00 3 4.1993e-01 1.7246e-04 1.4089e-02 -6.0000e+00 1.0243e-02 7.6137e-04 1.9006e-04 8.4155e-03 -6.0000e+00 1.1091e-02 9.9578e-04 1.0846e-04 4.1295e-03 -6.0000e+00 6.5032e-03 -2.6133e-03 4.7033e-05 1.1582e-03 -6.0000e+00 2.7200e-03 9.6765e-02 3.6418e-05 3.6374e-06 1.6249e-05 -6.0000e+00 1.9226e-04 -2.0795e-02 5.6117e-05 10 0 0 10 0 0 99.89 22.84 0.24 -0.02079 -0.02052 2642 576 2 8 0 10.210 20.03 22.84 35.11 27.05 26.83 32.9 1042.08 -515 -653 -597 -1592 -2028 -1084 -633 414 1132 240 -463 -351 -80 -652 512 46 -172 248 456 777 847 450 1266 628 385 514 289 -219 -48 1072 1310 1054 1935 515 -1202 -605 -1463 -1128 -485 -466 -1086 -838 -833 -1024 -575 -490 -669 -579 -560 -335 641 346 821 943 694 588 939 396 519 487 835 909 1034 1241 302 -235 -12 -600 393 552 93 161 56 317 29 78 85 -248 -22 -201 -928 -724 -1655 -1530 -1116 -903 -753 -283 129 -96 -29 532 158 637 882 459 478 879 231 -276 -129 -483 -556 332 -90 -927 -587 -554 -518 252 133 51 -9 162 -4 278 435 232 230 264 -414 -131 16 88 254 661 276 1032 976 533 494 3 -52 -54 171 46 -344 247 -196 -399 -289 -441 -509 -190 -246 -233 -602 -728 -353 -210 147 439 94 -183 -136 -32 -296 238 24 -92 134 238 416 462 245 684 357 227 311 179 -131 -26 574 712 595 1070 304 -691 -344 -834 -720 -338 -347 -868 -700 -716 -898 -498 -422 -566 -472 -462 -268 516 281 695 834 611 525 845 361 466 432 748 855 996 1219 306 -233 -11 -537 347 529 92 169 60 336 30 75 77 -216 -18 -182 -902 -742 -1776 -1648 -1266 -1061 -902 -352 164 -120 -34 615 174 670 915 489 536 1044 289 -350 -156 -576 -645 373 -104 -1127 -743 -708 -690 335 186 71 -13 215 -5 346 518 281 284 338 -546 -174 22 116 329 807 334 1242 1156 668 623 4 -67 -71 234 65 -487 356 -292 -592 -415 -619 -720 SS 20240820T182255.6Z 8998.765922 9 1 53.84 2 27.83 214.85 153.49 4.12 0.00 1 0.00 1 0 17 6.873e-03 5.784e-03 1.342e-04 9.725e-05 1.668481e-01 5.132183e-05 1.995738e-03 -6.000000e+00 4.055566e-03 231.05 -2.00 3.41 -2.00 314.57 0.00e+00 1.408877e-04 3.669032e-06 1.344599e-05 -6.000000e+00 1.597530e-04 292.20 -2.00 20.00 -2.00 314.32 0.00e+00 1.130 0.000 302.00 328.00 3 4.8807e-01 1.3257e-04 1.4156e-02 -6.0000e+00 1.0233e-02 1.0532e-03 1.4623e-04 8.4491e-03 -6.0000e+00 1.1080e-02 1.1069e-03 8.3413e-05 4.1437e-03 -6.0000e+00 6.4968e-03 -2.7785e-03 3.6095e-05 1.1608e-03 -6.0000e+00 2.7174e-03 8.9732e-02 2.6704e-05 2.8048e-06 1.6511e-05 -6.0000e+00 1.9207e-04 -2.0881e-02 5.6744e-05 10 0 0 10 0 0 99.93 22.86 0.26 -0.02088 -0.02068 4337 946 2 8 0 11.330 19.98 22.86 35.41 27.05 26.83 33.1 1046.60 -490 -683 -611 -1586 -1941 -1137 -622 431 1094 265 -534 -368 -85 -615 497 68 -171 230 473 807 843 448 1291 635 436 463 280 -193 -55 1047 1294 1051 1849 520 -1234 -666 -1491 -1193 -485 -446 -1112 -819 -855 -1022 -568 -480 -643 -574 -555 -358 622 361 781 972 662 608 916 403 543 499 846 892 1037 1255 295 -214 -33 -598 353 553 74 153 39 303 39 75 98 -249 -29 -222 -916 -758 -1666 -1541 -1116 -906 -778 -306 151 -81 -20 523 178 633 897 461 469 879 236 -286 -141 -476 -545 330 -84 -938 -587 -549 -518 262 147 70 19 172 5 272 432 253 227 262 -408 -142 9 70 277 662 262 1026 970 518 496 35 -67 -62 165 22 -336 252 -190 -393 -278 -444 -497 -181 -259 -239 -603 -700 -372 -207 154 427 105 -213 -143 -35 -281 233 35 -87 118 249 435 464 245 703 363 259 282 165 -116 -30 566 709 564 1032 309 -716 -360 -857 -725 -324 -334 -898 -691 -742 -863 -497 -417 -550 -473 -439 -289 506 296 668 829 589 548 834 371 492 447 766 848 1009 1245 302 -214 -32 -541 315 513 74 163 41 325 40 73 89 -219 -25 -194 -861 -752 -1807 -1679 -1231 -1075 -943 -385 187 -99 -23 587 190 646 902 497 533 1057 299 -354 -174 -575 -615 375 -98 -1154 -752 -710 -675 354 201 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