File name: Pandora70s1_ChapelHillNC_20250403_L2Fit_fout2c1d20210323p1-8.txt File generation date: 20250404T052601.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 70 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora70_OF_v7d20200416.txt Instrument calibration file used: Pandora70s1_CF_v1d20210323.txt Level 1 file used: Pandora70s1_ChapelHillNC_20250403_L1_smca1c1d20210323p1-8.txt Full location name: Duke Forest, Chapel Hill (NC) Short location name: ChapelHillNC Country of location: USA Location latitude [deg]: 35.9708 Location longitude [deg]: -79.0933 Location altitude [m]: 50 Local noon date: 20250403 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 278 420 Nominal wavelengths inside fitting window [nm]: 305.0320 305.1727 305.3133 305.4539 305.5945 305.7351 305.8756 306.0162 306.1567 306.2973 306.4378 306.5783 306.7188 306.8593 306.9998 307.1402 307.2807 307.4211 307.5615 307.7020 307.8424 307.9828 308.1231 308.2635 308.4039 308.5442 308.6846 308.8249 308.9652 309.1055 309.2458 309.3861 309.5263 309.6666 309.8068 309.9470 310.0873 310.2275 310.3677 310.5078 310.6480 310.7882 310.9283 311.0685 311.2086 311.3487 311.4888 311.6289 311.7690 311.9090 312.0491 312.1891 312.3291 312.4692 312.6092 312.7492 312.8891 313.0291 313.1691 313.3090 313.4490 313.5889 313.7288 313.8687 314.0086 314.1484 314.2883 314.4282 314.5680 314.7078 314.8476 314.9874 315.1272 315.2670 315.4068 315.5465 315.6863 315.8260 315.9657 316.1054 316.2451 316.3848 316.5245 316.6641 316.8038 316.9434 317.0830 317.2226 317.3622 317.5018 317.6414 317.7810 317.9205 318.0601 318.1996 318.3391 318.4786 318.6181 318.7576 318.8970 319.0365 319.1759 319.3153 319.4548 319.5942 319.7336 319.8729 320.0123 320.1517 320.2910 320.4303 320.5696 320.7090 320.8482 320.9875 321.1268 321.2661 321.4053 321.5445 321.6838 321.8230 321.9622 322.1013 322.2405 322.3797 322.5188 322.6580 322.7971 322.9362 323.0753 323.2144 323.3534 323.4925 323.6316 323.7706 323.9096 324.0486 324.1876 324.3266 324.4656 324.6046 324.7435 324.8824 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250403T130042.8Z 9224.542162 92 1 49.20 2 66.38 100.80 103.94 39.30 0.00 1 0.00 1 0 25 1.570e-02 5.442e-03 3.732e-03 9.741e-04 3.190054e-01 5.019432e-04 3.739211e-03 -6.000000e+00 9.177194e-03 228.20 -2.00 3.41 -2.00 317.57 0.00e+00 4.930092e-04 7.048408e-05 7.535313e-05 -6.000000e+00 3.656125e-04 282.36 -2.00 20.00 -2.00 317.27 0.00e+00 2.477 0.000 302.00 328.00 3 3.4090e+00 1.3268e-03 2.9434e-02 -6.0000e+00 2.3003e-02 9.4955e-03 1.4784e-03 1.6010e-02 -6.0000e+00 2.4957e-02 -8.8113e-03 9.3683e-04 7.9524e-03 -6.0000e+00 1.4659e-02 -2.2757e-03 4.8081e-04 2.3024e-03 -6.0000e+00 6.2254e-03 1.0110e-03 -3.5188e-04 2.8627e-05 2.6460e-05 -6.0000e+00 4.4084e-04 -3.4853e-02 -1.3312e-05 10 0 0 10 0 0 98.87 23.12 0.14 -0.03485 -0.03750 115 25 1 8 0 427.800 20.02 23.12 29.25 27.45 27.05 33.4 1030.40 900000 573 -5727 11705 -3996 -6398 2897 -1798 -550 -1287 -482 -2889 -1755 -2539 -1307 1250 -936 1609 -590 1333 360 1081 902 573 -348 -128 387 -1647 -114 -872 1042 -2031 2074 1381 -1570 -1225 -2128 -1455 -1020 -1 -842 -675 -514 -1015 -588 -282 -231 -764 -432 -676 937 447 634 1108 443 677 810 442 564 594 899 1020 1260 1684 426 -213 277 -332 464 494 322 383 199 531 -148 198 -179 -82 -620 -154 -684 -660 -1434 -1664 -1061 -890 -677 -27 418 56 175 472 203 410 838 379 327 848 294 -226 -165 -583 -762 82 -55 -1126 -682 -709 -581 195 74 -102 41 76 22 186 336 456 168 176 -363 -244 118 -2 1182 437 56 625 878 297 223 -76 135 -218 210 77 -315 360 27 -363 -259 -306 -442 900000 48 -544 946 -340 -518 223 -157 -52 -134 -51 -318 -209 -349 -203 214 -176 310 -121 280 79 235 199 133 -86 -32 101 -430 -28 -206 254 -545 578 415 -478 -355 -647 -488 -388 0 -412 -348 -273 -554 -321 -154 -126 -414 -231 -362 510 259 385 701 294 457 554 306 388 403 614 723 944 1336 353 -173 213 -251 352 399 282 352 187 491 -133 167 -141 -61 -464 -122 -593 -619 -1439 -1738 -1143 -1006 -794 -32 508 68 204 522 214 415 849 406 375 1043 385 -303 -216 -737 -919 95 -67 -1439 -896 -960 -813 281 111 -158 63 115 31 258 455 621 236 259 -550 -370 178 -3 1690 608 76 831 1190 423 329 -116 211 -347 342 130 -545 631 48 -645 -450 -522 -742 SS 20250403T134457.6Z 9224.572889 116 1 1.09 2 57.71 108.50 98.09 46.64 0.00 1 0.00 1 0 17 2.002e-02 9.813e-03 1.554e-02 7.693e-03 2.385578e-01 3.998142e-03 2.857055e-03 -6.000000e+00 1.170566e-02 228.20 -2.00 3.41 -2.00 316.15 0.00e+00 3.045394e-05 3.934574e-04 3.295691e-05 -6.000000e+00 4.662441e-04 282.36 -2.00 20.00 -2.00 315.86 0.00e+00 1.865 0.000 302.00 328.00 3 3.8267e+00 1.0390e-02 2.2134e-02 -6.0000e+00 2.9342e-02 8.9828e-03 1.1525e-02 1.2007e-02 -6.0000e+00 3.1830e-02 -3.7007e-03 6.7163e-03 5.9303e-03 -6.0000e+00 1.8696e-02 6.7339e-04 3.1587e-03 1.6932e-03 -6.0000e+00 7.9421e-03 1.3673e-03 -4.3128e-04 2.2446e-04 2.1598e-05 -6.0000e+00 5.6207e-04 -3.6098e-02 2.4298e-05 12 9 9 12 1 1 999.00 23.12 0.54 -0.03610 -0.03934 1 20 1 8 0 542.280 20.01 23.12 30.53 27.45 27.05 33.9 1040.01 900000 6675 -8745 1143 -1606 -7773 4870 -6038 5710 256 -2968 -5032 -247 -1792 762 1744 -1111 4620 -2045 1288 -2779 1313 -550 1506 4110 231 -557 -1718 972 272 3112 -3073 4397 407 -178 -1549 -2582 478 -3423 912 -1098 -19 -1014 321 -148 611 -391 618 -2505 -2403 2607 1701 201 1588 1165 1644 374 -459 -361 2280 -492 680 1796 1602 -1333 292 1250 -1294 1454 651 276 -335 -263 441 -510 -207 -1247 890 1689 -207 -2441 -1001 -2070 -1919 -817 -516 -422 373 -43 -633 591 70 43 -708 1110 -196 -964 1567 -683 -29 953 459 -1082 540 133 -1386 -585 3 -306 75 1039 835 423 147 -342 -21 -344 825 -583 -224 -209 -275 -419 -315 168 990 1430 400 1257 153 1167 -698 -611 -638 97 310 -16 965 170 -419 -363 166 -1445 900000 1240 -1937 230 -302 -1426 819 -1196 1121 57 -688 -1176 -59 -478 220 549 -377 1537 -738 466 -1061 486 -207 581 1614 96 -238 -727 379 102 1171 -1265 1797 180 -78 -655 -1136 224 -1847 542 -723 -13 -712 227 -105 431 -276 426 -1733 -1645 1753 1202 149 1207 917 1308 304 -378 -295 1812 -401 567 1558 1460 -1267 267 1080 -1102 1216 576 263 -335 -268 444 -502 -193 -1095 732 1359 -177 -2269 -987 -2169 -2077 -907 -598 -506 458 -53 -790 709 80 47 -740 1141 -212 -1110 1893 -881 -38 1210 566 -1291 625 159 -1752 -757 5 -418 105 1498 1233 625 212 -473 -28 -442 1059 -776 -311 -299 -395 -599 -446 230 1307 1837 506 1603 203 1591 -989 -880 -928 143 475 -25 1529 275 -678 -576 259 -2237 SS 20250403T134947.4Z 9224.576243 119 1 6.05 2 56.79 109.41 97.40 47.40 0.00 1 0.00 1 0 17 9.368e-03 6.009e-03 4.613e-03 2.331e-03 2.349459e-01 1.210198e-03 2.800358e-03 -6.000000e+00 5.477011e-03 228.20 -2.00 3.41 -2.00 316.09 0.00e+00 1.738998e-04 1.179072e-04 3.234240e-05 -6.000000e+00 2.181800e-04 282.36 -2.00 20.00 -2.00 315.79 0.00e+00 1.820 0.000 302.00 328.00 3 3.8141e+00 3.1424e-03 2.1638e-02 -6.0000e+00 1.3729e-02 1.0107e-02 3.4856e-03 1.1786e-02 -6.0000e+00 1.4894e-02 -3.7900e-03 2.0287e-03 5.8210e-03 -6.0000e+00 8.7485e-03 -1.6810e-03 9.5146e-04 1.6625e-03 -6.0000e+00 3.7156e-03 1.4567e-03 -2.7816e-04 6.8013e-05 2.1146e-05 -6.0000e+00 2.6306e-04 -3.5160e-02 2.1627e-06 12 1 1 12 1 1 99.89 23.13 0.23 -0.03516 -0.03725 11 21 1 8 0 503.100 19.97 23.13 30.84 27.45 27.05 33.8 1041.77 900000 -1691 -1397 4554 -3629 -2085 272 1828 519 -174 -845 -2507 -1428 -1795 699 -798 -732 1042 910 603 594 224 83 450 1518 660 264 589 -447 754 440 235 1327 1078 -1135 -1033 -1540 -1539 -664 -392 -735 -1207 -786 -995 -760 71 -352 -899 -106 -162 294 355 507 833 354 585 928 378 795 659 911 911 1650 1594 499 -358 25 -683 83 825 -44 410 459 268 358 67 293 -668 -148 -210 -1370 -474 -1521 -1788 -1187 -996 -806 59 325 -185 -27 381 284 170 1072 434 508 918 418 -134 -44 -507 -957 -165 -178 -687 -766 -533 -1033 358 426 179 -16 146 101 -58 558 259 7 230 -279 -206 197 222 -15 686 508 906 463 480 179 150 131 -12 158 -30 -213 482 -122 -608 -319 -105 -613 900000 -348 -301 920 -716 -376 49 350 110 -40 -197 -589 -353 -491 207 -263 -253 364 328 224 226 85 32 178 619 278 114 248 -179 287 172 96 564 483 -508 -442 -682 -745 -357 -238 -488 -838 -556 -717 -546 51 -251 -631 -73 -110 202 255 378 641 282 471 754 311 647 532 739 763 1440 1460 471 -330 22 -581 70 732 -43 410 467 271 351 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