File name: Pandora31s1_CharlesCityVA_20230707_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20230709T202133.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20230707_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20230707 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230707T104726.2Z 8588.449609 209 1 49.66 2 81.45 68.06 55.29 212.28 0.00 1 0.00 1 0 25 5.814e-01 3.847e-02 2.024e-01 8.197e-03 7.184435e-01 4.844860e-03 7.222324e-03 -6.000000e+00 3.566053e-01 232.66 -2.00 3.44 -2.00 321.55 0.00e+00 -2.946796e-03 1.927031e-03 7.342332e-04 -6.000000e+00 1.777870e-02 290.72 -2.00 20.00 -2.00 321.18 0.00e+00 6.331 0.004 302.00 328.00 3 3.2007e+00 1.4739e-02 7.3537e-02 -6.0000e+00 9.1663e-01 5.6700e-01 1.9797e-02 3.7533e-02 -6.0000e+00 1.0058e+00 -7.9017e-01 2.1205e-02 2.0042e-02 -6.0000e+00 5.7955e-01 3.0699e-01 1.0462e-02 6.4791e-03 -6.0000e+00 2.4200e-01 1.8900e-05 1.3978e-03 2.5679e-04 7.4816e-05 -6.0000e+00 1.7629e-02 1.9812e-02 1.3064e-04 12 9 8 11 32 0 5.83 23.49 0.67 0.01981 0.03032 20 4 1 5 0 2482.570 25.90 20.00 23.49 33.66 35.1 1041.60 900000 900000 900000 -136769 -48546 900000 900000 900000 900000 900000 -154053 900000 -136610 23843 900000 900000 900000 900000 900000 125704 -93057 900000 900000 68766 97344 900000 -86863 900000 900000 900000 131931 900000 -7149 61848 35757 900000 -19368 75789 900000 217557 71260 329098 93732 13671 900000 28338 -7493 -319 101885 133176 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434 -466 2094 -8884 -1114 2846 -1465 -8318 -4663 -1669 -1725 -2904 -952 -506 -5268 4621 1432 685 -1246 -8229 2017 3628 -1041 238 -2566 -2934 -3666 3649 -1872 3100 4155 -126 2795 3480 1721 -837 4703 -4699 4726 -1139 2115 5249 6759 -48 -844 -734 -3350 -3281 2541 -2717 4196 2708 -5308 4147 -4146 5447 -7480 SS 20230707T110136.7Z 8588.459452 214 1 50.96 2 78.82 70.03 56.77 215.95 0.00 1 0.00 1 0 17 3.401e-01 7.291e-03 1.357e-01 2.445e-03 6.245827e-01 1.340814e-03 6.628487e-03 -6.000000e+00 2.049898e-01 232.66 -2.00 3.44 -2.00 320.82 0.00e+00 1.499853e-03 4.727616e-04 4.839932e-04 -6.000000e+00 9.638021e-03 290.72 -2.00 20.00 -2.00 320.48 0.00e+00 4.974 0.002 302.00 328.00 3 2.6663e+00 3.9010e-03 5.9510e-02 -6.0000e+00 5.2307e-01 -4.1162e-02 5.1822e-03 3.2740e-02 -6.0000e+00 5.7336e-01 3.3994e-02 5.9852e-03 1.7224e-02 -6.0000e+00 3.2425e-01 -2.2839e-02 3.0261e-03 5.3491e-03 -6.0000e+00 1.3456e-01 1.3793e-04 -2.1237e-04 7.2871e-05 5.8999e-05 -6.0000e+00 9.9859e-03 2.0884e-02 7.6279e-05 11 8 0 10 0 0 82.22 23.49 0.37 0.02088 0.01929 81 15 1 5 0 629.030 25.90 20.00 23.49 34.47 35.1 1045.43 257860 900000 900000 900000 900000 900000 900000 900000 900000 900000 -84175 900000 -47929 -4255 900000 79280 -80202 38710 157351 -2183 -50952 98553 11611 744 7793 91370 -57353 12989 -28708 30935 40616 25546 -15414 3555 -423 14193 -7924 728 10002 747 3794 8338 3190 -4132 11675 -3857 -10021 -6506 4613 8143 -4575 7451 1253 -2524 -967 2641 -4039 2376 1335 2315 -3341 2166 2768 3072 321 2855 -1121 616 -1316 -134 -402 -45 -1116 1471 -1726 1196 20 -420 1044 -1593 389 -1119 -869 -620 -681 -133 505 213 1256 -688 853 1074 951 -216 -44 343 404 348 -36 324 -1042 843 405 -219 -1342 -1753 -436 -33 -101 22 -155 -575 -63 247 331 638 737 -13 -91 -404 -225 404 107 -564 533 2 551 910 548 292 -262 -128 -563 -107 127 -301 535 -46 -504 159 -162 456 -266 614 900000 900000 900000 900000 900000 900000 900000 900000 900000 -768 900000 -486 -36 900000 424 -2228 383 528 -36 -1380 662 198 16 164 907 -2337 267 -909 640 918 780 -774 151 -18 568 -453 47 715 67 364 816 342 -484 1211 -474 -1342 -880 595 1113 -787 1264 246 -551 -219 602 -997 547 306 531 -861 592 845 1013 109 928 -381 219 -535 -61 -194 -22 -538 653 -725 451 8 -165 461 -832 226 -726 -598 -449 -525 -107 420 180 1040 -555 641 769 673 -163 -37 322 424 399 -43 376 -1148 850 395 -223 -1456 -1985 -512 -41 -136 31 -237 -903 -98 368 475 897 1057 -19 -142 -644 -354 618 160 -825 753 2 753 1309 861 495 -472 -238 -1090 -217 268 -652 1172 -101 -1113 340 -334 905 -530 SS 20230707T110719.8Z 8588.463424 217 1 50.85 2 77.75 70.82 57.41 217.39 0.00 1 0.00 1 0 17 3.606e-01 6.185e-03 2.292e-01 1.878e-03 5.795426e-01 9.871652e-04 6.251617e-03 -6.000000e+00 2.091491e-01 232.66 -2.00 3.44 -2.00 320.47 0.00e+00 1.353297e-03 3.167840e-04 3.839818e-04 -6.000000e+00 8.985868e-03 290.72 -2.00 20.00 -2.00 320.13 0.00e+00 4.572 0.002 302.00 328.00 3 2.5831e+00 2.8200e-03 5.4810e-02 -6.0000e+00 5.3096e-01 -3.1744e-02 3.5309e-03 3.0129e-02 -6.0000e+00 5.7843e-01 2.0641e-02 3.7860e-03 1.5530e-02 -6.0000e+00 3.3752e-01 -1.6279e-02 1.9617e-03 4.7086e-03 -6.0000e+00 1.3816e-01 2.2876e-04 -5.7055e-05 5.4461e-05 5.1902e-05 -6.0000e+00 9.9719e-03 1.9893e-02 9.2148e-05 10 0 0 10 0 0 -10.54 23.50 0.31 0.01989 0.01946 109 20 1 5 0 466.420 25.79 20.00 23.50 34.87 35.1 1047.61 25324 135717 188961 66821 62896 133556 182696 184105 900000 900000 -74326 -3702 -50100 -17419 69848 30772 -50692 18152 61324 -12125 -38660 22272 18000 -8592 7160 17957 -32730 6085 -11627 17114 7367 10886 -7615 325 -4975 -4620 -4715 -3160 4948 -35 697 637 2167 -4317 6927 -5918 -7632 -4510 2364 3980 -1052 4698 1161 -1448 -379 2132 -2567 1621 156 1935 -1528 1882 2486 2922 1353 1323 535 1456 1078 220 442 -99 -1202 723 -691 -858 -539 -767 -126 -477 -390 -748 -1493 -655 -1379 59 385 314 809 -318 904 1179 1018 -148 30 542 332 -126 -284 -157 -607 517 404 -430 -1057 -1268 -534 151 -155 172 -154 -217 -151 210 451 569 635 204 37 -545 37 50 -9 -421 218 33 932 822 463 5 -178 60 -217 -45 -187 -253 209 -14 -354 279 -138 191 -146 74 248 346 145 137 245 335 337 900000 900000 -1097 -33 -896 -283 579 434 -1696 356 839 -364 -1455 499 459 -297 241 569 -1611 208 -461 614 327 546 -514 20 -318 -313 -374 -287 507 -4 95 92 323 -699 1024 -1017 -1365 -810 417 754 -223 1041 291 -401 -109 624 -803 480 46 566 -495 630 934 1186 558 527 215 616 498 116 251 -58 -688 380 -334 -395 -238 -357 -64 -286 -258 -554 -1146 -530 -1210 52 354 294 742 -280 759 927 784 -123 27 557 377 -155 -365 -196 -700 555 432 -469 -1247 -1518 -673 196 -222 261 -245 -354 -241 329 663 814 931 316 59 -900 61 78 -14 -637 326 47 1308 1196 732 9 -327 112 -426 -90 -391 -552 451 -31 -770 594 -288 379 -289 SS 20230707T111235.8Z 8588.467081 220 1 50.87 2 76.76 71.54 58.02 218.70 0.00 1 0.00 1 0 25 1.290e-01 4.991e-03 6.893e-02 1.413e-03 5.433227e-01 7.316947e-04 5.919459e-03 -6.000000e+00 7.473559e-02 232.66 -2.00 3.44 -2.00 320.16 0.00e+00 1.383977e-03 2.163350e-04 3.176275e-04 -6.000000e+00 2.966603e-03 290.72 -2.00 20.00 -2.00 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