File name: Pandora31s1_CharlesCityVA_20230718_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20230720T103621.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20230718_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20230718 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230718T113159.5Z 8599.480549 85 1 49.33 2 74.21 75.34 80.35 67.50 0.00 1 0.00 1 0 17 2.236e-01 2.111e-02 6.644e-02 4.070e-03 4.698863e-01 2.102863e-03 5.111569e-03 -6.000000e+00 1.297654e-01 232.51 -2.00 3.44 -2.00 319.70 0.00e+00 9.561779e-04 5.359019e-04 2.268628e-04 -6.000000e+00 5.556562e-03 291.53 -2.00 20.00 -2.00 319.36 0.00e+00 3.609 0.001 302.00 328.00 3 5.0005e+00 5.8501e-03 4.3446e-02 -6.0000e+00 3.2938e-01 5.9212e-02 6.7804e-03 2.3887e-02 -6.0000e+00 3.5876e-01 -7.1219e-02 5.7424e-03 1.1956e-02 -6.0000e+00 2.0933e-01 3.1102e-02 3.0475e-03 3.4980e-03 -6.0000e+00 8.5777e-02 5.5402e-05 5.2791e-04 1.2029e-04 3.5899e-05 -6.0000e+00 6.1815e-03 1.4402e-02 1.4941e-04 12 9 8 11 32 0 99.87 23.45 0.57 0.01440 0.01837 15 3 1 5 0 3288.240 25.47 20.00 23.45 33.63 35.0 1036.85 257 -3434 3830 -62213 -34753 10749 43919 20949 900000 900000 -93549 -25384 -63289 -35143 73632 74835 -71493 47864 105500 971 -45022 -1116 22405 -1769 -6767 63750 -46894 24345 -33132 16264 26386 17913 -17036 13141 -1360 16871 -3898 -5037 26716 7210 9096 12797 7939 -275 19745 -6147 -3201 5284 12939 15201 -2312 17934 3973 -709 1800 6685 -2381 1696 2634 160 4579 3366 3950 4526 383 2738 -2606 555 -1573 1680 -7297 976 -4403 2665 -2731 -1799 233 -3553 -708 -1991 1848 -1474 -648 125 -2786 -238 850 852 995 -2581 157 1028 683 -3127 -2073 -78 -734 -866 -456 483 -2277 1697 -5 1558 -563 -2548 363 1526 -273 623 -448 -842 235 1119 103 734 1288 -88 601 418 15 1235 1196 -2123 1117 -949 960 1707 716 391 -552 273 -1444 -814 1003 -80 944 -375 241 -535 412 658 -2251 4 -65 68 -1901 -770 161 533 359 900000 900000 -5616 -920 -3956 -2023 1772 1976 -8055 1880 2529 65 -4667 -78 1336 -143 -604 3027 -6164 1565 -3636 1220 2046 1695 -2438 1408 -160 1753 -561 -874 4126 1516 2021 2876 1922 -72 4376 -1738 -883 1368 3197 3911 -760 5305 1425 -280 721 2638 -1030 698 1059 66 1923 1559 1994 2405 208 1393 -1366 294 -936 1079 -5348 681 -3141 1705 -1690 -1014 123 -1984 -428 -1375 1376 -1225 -564 113 -2733 -240 881 894 1033 -2640 148 910 587 -2859 -2046 -84 -870 -1110 -600 616 -2798 1892 -6 1760 -683 -3250 472 2060 -395 955 -723 -1377 374 1695 150 1040 1846 -132 942 672 24 1929 1828 -3222 1607 -1343 1319 2425 1100 639 -949 480 -2638 -1539 1952 -161 1919 -777 495 -1074 796 1232 -4274 SS 20230718T114155.4Z 8599.487446 88 1 51.11 2 72.30 76.71 78.58 68.83 0.00 1 0.00 1 0 17 1.059e-01 8.022e-03 2.893e-02 1.973e-03 4.384486e-01 1.007492e-03 4.917451e-03 -6.000000e+00 6.136678e-02 232.51 -2.00 3.44 -2.00 319.13 0.00e+00 8.367721e-04 2.206798e-04 1.761104e-04 -6.000000e+00 2.433785e-03 291.53 -2.00 20.00 -2.00 318.79 0.00e+00 3.242 0.001 302.00 328.00 3 4.1907e+00 2.7651e-03 3.9624e-02 -6.0000e+00 1.5534e-01 1.2583e-02 3.1498e-03 2.2445e-02 -6.0000e+00 1.6907e-01 1.6968e-02 2.4959e-03 1.1124e-02 -6.0000e+00 9.9026e-02 -1.5828e-02 1.3382e-03 3.1858e-03 -6.0000e+00 4.0552e-02 1.8390e-04 -7.1528e-05 5.7331e-05 3.3269e-05 -6.0000e+00 2.9108e-03 1.3827e-02 1.5268e-04 11 8 0 10 0 0 76.09 23.44 0.31 0.01383 0.01329 38 7 1 5 0 1344.600 25.47 20.00 23.44 33.68 35.0 1037.14 -707 3582 7194 7333 -2006 36691 12933 25278 32356 85977 -35808 -9940 -23733 -10533 21238 6795 -23246 3943 19770 -2115 -13384 7211 1523 -3587 -106 10281 -13615 5572 -9381 6888 5906 5253 -6414 3881 -2699 -1405 -3269 -2020 2354 304 62 640 990 -2253 3793 -4128 -5589 -4123 2663 3675 -786 4517 1177 199 347 2137 -1547 1249 150 2440 -1764 1787 1410 1659 869 1331 -357 480 12 95 -1850 -89 -1072 829 -558 246 -65 -460 -217 -598 -236 -851 -1070 -491 -1442 -42 82 798 797 -211 907 1255 1140 -456 429 496 386 -308 -176 204 -706 -574 347 120 -1115 -1080 -499 -150 -451 240 -387 -297 -234 195 454 515 685 301 104 -566 -146 144 200 -548 538 5 855 1112 601 375 -80 32 -378 -18 139 -197 387 -30 -622 85 -223 240 -436 -15 82 160 151 -42 562 277 548 723 1207 -1635 -406 -1324 -621 1088 441 -2141 303 1384 -189 -1344 609 144 -384 -12 1064 -1728 566 -1085 738 720 722 -1069 587 -416 -223 -600 -435 578 86 19 203 322 -760 1228 -1441 -1977 -1454 903 1302 -313 1845 526 94 169 1057 -798 624 74 1200 -940 1000 858 1060 552 805 -215 295 8 70 -1465 -71 -845 617 -392 159 -40 -289 -148 -456 -198 -770 -1015 -483 -1505 -46 91 895 887 -228 920 1204 1059 -438 440 554 468 -402 -237 267 -885 -677 396 142 -1398 -1399 -667 -208 -658 368 -618 -478 -370 296 657 728 979 446 160 -901 -231 224 305 -818 775 7 1176 1574 906 597 -133 54 -658 -32 260 -378 752 -60 -1221 163 -415 434 -790 SS 20230718T114851.8Z 8599.492266 92 1 51.10 2 70.95 77.66 77.33 69.75 0.00 1 0.00 1 0 17 3.416e-02 5.891e-03 1.180e-02 1.343e-03 4.101109e-01 6.844565e-04 4.638369e-03 -6.000000e+00 1.979565e-02 232.51 -2.00 3.44 -2.00 318.73 0.00e+00 3.920840e-04 1.328106e-04 1.425643e-04 -6.000000e+00 7.850378e-04 291.53 -2.00 20.00 -2.00 318.39 0.00e+00 3.027 0.000 302.00 328.00 3 3.7424e+00 1.8637e-03 3.7009e-02 -6.0000e+00 5.0108e-02 7.7779e-03 2.1036e-03 2.0958e-02 -6.0000e+00 5.4538e-02 7.4826e-03 1.5343e-03 1.0315e-02 -6.0000e+00 3.1943e-02 -9.7411e-03 8.1538e-04 2.9191e-03 -6.0000e+00 1.3082e-02 3.6965e-04 4.4139e-05 3.8979e-05 3.0688e-05 -6.0000e+00 9.3892e-04 1.3274e-02 1.5050e-04 10 0 0 10 0 0 33.97 23.43 0.31 0.01327 0.01361 67 12 1 5 0 762.500 25.47 19.99 23.43 33.62 35.1 1036.91 -1859 -420 -2664 -7088 -2622 -546 7342 1378 12426 17108 -16007 -2418 -12560 -5923 6138 5244 -13322 1502 5702 -2455 -8442 2616 1289 -2327 -1028 2287 -8370 -426 -3290 2707 3560 2202 -1072 -1591 -2231 -878 -2769 -791 1519 -44 -621 -90 -825 -972 1252 -1780 -2760 -1465 438 1976 498 2086 1062 143 725 1379 -136 574 604 1547 -360 1726 1734 1263 496 446 -42 931 159 612 -878 190 -524 457 -301 174 22 -601 -4 -701 -279 -1539 -1338 -839 -1126 -580 3 318 323 -35 531 908 743 166 294 674 400 -29 -293 49 -718 -58 258 -408 -924 -1056 -534 -160 -78 86 -138 -237 -40 174 281 465 599 149 41 -447 -269 52 199 -87 620 173 964 838 654 321 136 -137 -114 -111 83 -67 341 -169 -563 10 -220 119 -457 -61 -15 -95 -243 -81 -17 240 54 482 657 -863 -130 -875 -459 492 465 -1492 157 601 -290 -1064 303 160 -322 -148 331 -1308 -59 -460 382 556 386 -210 -310 -420 -170 -616 -203 451 -15 -225 -34 -320 -380 485 -710 -1105 -583 174 812 223 981 533 76 393 763 -77 320 333 851 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