File name: Pandora31s1_CharlesCityVA_20230719_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20230721T124752.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20230719_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20230719 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230719T130530.9Z 8600.545497 144 1 51.07 2 55.96 88.60 73.87 76.79 0.00 1 0.00 1 0 17 2.882e-02 1.008e-02 7.026e-03 2.492e-03 2.503561e-01 1.270934e-03 2.843059e-03 -6.000000e+00 1.669979e-02 232.47 -2.00 3.44 -2.00 317.04 0.00e+00 5.995493e-04 1.542074e-04 4.928985e-05 -6.000000e+00 6.623130e-04 291.56 -2.00 20.00 -2.00 316.69 0.00e+00 1.781 0.000 302.00 328.00 3 6.2335e+00 3.3736e-03 2.1968e-02 -6.0000e+00 4.2268e-02 1.9139e-02 3.7673e-03 1.2596e-02 -6.0000e+00 4.6006e-02 1.6217e-02 2.2401e-03 6.1288e-03 -6.0000e+00 2.6947e-02 -1.3666e-02 1.0721e-03 1.6985e-03 -6.0000e+00 1.1036e-02 1.2815e-04 6.8736e-04 7.2817e-05 1.8665e-05 -6.0000e+00 7.9216e-04 1.5174e-02 2.1913e-04 12 8 8 10 0 0 99.97 23.26 0.73 0.01517 0.02034 24 4 1 5 0 2127.490 25.39 20.00 23.26 34.97 35.1 1044.03 -2004 1915 4587 -4653 -2666 2427 12565 3493 9275 12212 -7731 -4574 -5600 -3742 4853 3862 -11457 2229 6478 -1098 -5041 3332 1635 -55 -1294 5115 -7183 2502 -3826 3765 3129 2593 -2894 681 -985 622 -2226 -1656 2306 -611 -281 396 -930 -1691 1328 -2147 -5165 -2132 1336 2809 -1317 3869 1489 -326 501 1237 -306 1309 758 1512 -991 2050 1373 1256 578 1098 -389 965 49 502 -1717 597 -1363 1213 -960 52 -563 -1260 -189 -981 662 -675 -1002 -762 -1203 195 395 300 1060 -961 298 535 277 -1333 -1196 273 104 13 48 214 -900 796 181 177 -798 -1557 47 573 268 156 -276 -563 -109 462 -338 586 549 -50 237 -3 -94 592 420 -493 455 -116 716 1152 803 -192 -400 -383 -557 -371 655 -320 919 42 -499 454 -304 530 -1360 -266 257 589 -590 -307 272 1407 474 1286 1663 -1259 -780 -1091 -812 1083 921 -3229 579 1675 -313 -1489 917 475 -17 -422 1606 -2434 732 -1138 1073 958 854 -1056 235 -328 212 -866 -743 1156 -346 -167 240 -581 -1065 817 -1349 -3259 -1291 779 1659 -847 2509 1027 -236 367 914 -230 964 555 1110 -773 1659 1182 1111 497 881 -303 750 41 460 -1678 584 -1335 1124 -849 42 -430 -956 -152 -867 627 -685 -1058 -835 -1393 234 487 376 1308 -1158 336 564 277 -1355 -1283 311 128 18 64 277 -1116 927 209 213 -1015 -2056 63 794 386 234 -425 -864 -162 646 -451 755 716 -68 338 -4 -139 867 604 -690 613 -152 908 1485 1088 -273 -585 -567 -840 -576 1049 -530 1537 72 -850 755 -497 844 -2182 SS 20230719T134114.6Z 8600.570308 170 1 50.02 2 48.87 94.16 67.12 81.66 0.00 1 0.00 1 0 17 1.672e-02 8.105e-03 3.684e-03 1.902e-03 2.140183e-01 9.769335e-04 2.462432e-03 -6.000000e+00 9.686604e-03 232.47 -2.00 3.44 -2.00 316.06 0.00e+00 2.010779e-04 9.396791e-05 3.022141e-05 -6.000000e+00 3.842041e-04 291.56 -2.00 20.00 -2.00 315.72 0.00e+00 1.517 0.000 302.00 328.00 3 6.1810e+00 2.5647e-03 1.8750e-02 -6.0000e+00 2.4517e-02 1.4844e-02 2.8563e-03 1.0786e-02 -6.0000e+00 2.6686e-02 1.1893e-02 1.6402e-03 5.2402e-03 -6.0000e+00 1.5631e-02 -8.1558e-03 7.3953e-04 1.4432e-03 -6.0000e+00 6.4010e-03 1.8723e-04 4.6065e-04 5.4867e-05 1.7237e-05 -6.0000e+00 4.5952e-04 1.5015e-02 1.9587e-04 11 9 0 11 32 0 99.91 23.30 0.30 0.01501 0.01848 14 3 1 5 0 3572.200 25.39 20.00 23.30 35.31 35.3 1045.37 -783 164 -366 -3828 310 716 5899 2243 6539 5070 -5154 -3108 -4717 -1072 1477 1841 -6210 2324 3465 978 -4018 2440 750 -289 -605 2244 -2245 956 -2219 1644 2864 1377 -990 -1290 -1866 -99 -2561 -1222 724 -621 -447 555 -631 -431 268 -780 -3233 -1320 798 2388 -290 2680 755 -45 834 281 275 256 859 958 -238 1453 1701 1376 576 773 -1394 592 -328 516 -873 636 -863 1160 -543 -9 -1084 -1250 -572 -1681 -122 -1254 -825 -800 -918 -95 7 709 668 -498 392 338 33 -576 -510 388 130 124 77 842 -1098 511 344 -120 -782 -1141 -16 -172 152 224 56 -416 -213 101 -413 508 440 299 179 233 -15 605 168 -679 494 248 530 759 727 -276 -35 -225 409 -225 613 -365 569 -315 -597 133 -416 120 -575 -169 36 -80 -779 56 131 1127 490 1472 1160 -1274 -800 -1364 -334 492 639 -2351 846 1284 379 -1620 935 301 -122 -265 975 -981 383 -874 635 1152 592 -454 -578 -801 -43 -1253 -674 447 -421 -316 398 -463 -315 195 -567 -2341 -924 543 1634 -211 1990 589 -37 678 233 229 211 699 785 -204 1292 1584 1310 533 672 -1181 497 -296 498 -888 652 -883 1136 -508 -8 -893 -1016 -487 -1560 -120 -1310 -888 -891 -1072 -114 9 889 831 -603 448 364 33 -592 -548 441 158 159 101 1066 -1345 593 394 -143 -983 -1479 -22 -234 213 324 83 -613 -303 136 -533 635 555 390 245 329 -22 851 233 -919 644 313 654 948 945 -374 -48 -316 577 -328 921 -564 891 -501 -951 208 -639 180 -864 SS 20230719T134620.0Z 8600.573843 173 1 50.69 2 47.86 95.00 66.15 82.36 0.00 1 0.00 1 0 17 1.453e-02 7.754e-03 3.063e-03 1.675e-03 2.132134e-01 8.621627e-04 2.457570e-03 -6.000000e+00 8.417061e-03 232.47 -2.00 3.44 -2.00 315.88 0.00e+00 3.117396e-04 7.967746e-05 2.822214e-05 -6.000000e+00 3.338921e-04 291.56 -2.00 20.00 -2.00 315.55 0.00e+00 1.488 0.000 302.00 328.00 3 6.0208e+00 2.2597e-03 1.8491e-02 -6.0000e+00 2.1304e-02 1.8753e-02 2.5157e-03 1.0743e-02 -6.0000e+00 2.3189e-02 5.6475e-03 1.4393e-03 5.2182e-03 -6.0000e+00 1.3582e-02 -6.6534e-03 6.4222e-04 1.4347e-03 -6.0000e+00 5.5619e-03 2.2659e-04 4.4553e-04 4.8208e-05 1.7437e-05 -6.0000e+00 3.9933e-04 1.4734e-02 1.5880e-04 11 9 0 11 8 0 99.53 23.31 0.43 0.01473 0.01808 13 2 1 5 0 3897.970 25.39 20.00 23.31 35.32 35.3 1045.97 -1182 -109 -2239 -4350 -2891 1017 3935 2513 3880 5189 -4213 -667 -3406 -1064 2092 1976 -4680 1326 3512 -34 -2804 1646 801 -825 -513 2123 -2873 910 -1777 2200 2312 1848 -490 122 -1057 758 -1922 -775 505 -1015 -780 60 -659 -1132 376 -1319 -2466 -2013 492 1597 -143 2340 1264 126 776 794 -419 1276 563 1603 -308 1799 1982 1067 166 602 -713 616 -85 653 -716 438 -584 881 -169 -538 -612 -1154 -540 -1107 -291 -1406 -1306 -941 -1092 -375 297 475 223 -457 165 228 636 -832 -453 274 591 -95 31 708 -872 210 85 -90 -836 -974 -365 107 99 142 84 -291 -272 273 -124 320 269 255 363 27 65 485 661 -433 669 188 575 1165 441 61 221 -158 -494 11 284 -309 498 -24 -651 144 -298 198 -1005 -277 -26 -535 -962 -586 202 828 590 961 1275 -1107 -180 -1041 -353 736 726 -1849 515 1375 -14 -1179 669 338 -367 -235 966 -1319 382 -732 889 980 829 -233 56 -471 343 -973 -441 321 -707 -564 44 -494 -850 279 -983 -1814 -1448 343 1124 -106 1775 999 103 641 663 -354 1059 465 1326 -267 1614 1858 1026 156 529 -608 523 -77 634 -731 452 -599 868 -159 -472 -508 -948 -465 -1031 -288 -1475 -1413 -1049 -1276 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