File name: Pandora31s1_CharlesCityVA_20230815_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20230816T072817.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20230815_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20230815 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230815T111533.6Z 8627.469139 82 1 50.85 2 81.12 79.06 70.84 77.36 0.00 1 0.00 1 0 25 4.091e-01 4.671e-02 1.529e-01 8.949e-03 7.212613e-01 5.585217e-03 7.162238e-03 -6.000000e+00 2.591034e-01 231.58 -2.00 3.44 -2.00 321.53 0.00e+00 6.214122e-03 2.260158e-03 7.734741e-04 -6.000000e+00 1.728983e-02 292.13 -2.00 20.00 -2.00 321.17 0.00e+00 6.121 0.004 302.00 328.00 3 3.6062e+00 1.6872e-02 7.1581e-02 -6.0000e+00 6.6364e-01 5.9564e-01 2.3029e-02 3.7112e-02 -6.0000e+00 7.3865e-01 -7.4868e-01 2.5429e-02 1.9770e-02 -6.0000e+00 4.1758e-01 2.9322e-01 1.2400e-02 6.4362e-03 -6.0000e+00 1.8651e-01 1.3978e-05 1.9027e-03 2.9331e-04 7.6415e-05 -6.0000e+00 1.2949e-02 1.9981e-02 2.1326e-04 12 8 8 10 0 0 98.98 23.21 1.06 0.01998 0.03428 13 2 1 5 0 3910.620 25.17 20.00 23.21 33.43 35.5 1028.73 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 102986 900000 -108723 900000 900000 900000 -131947 900000 900000 900000 -51064 900000 900000 900000 37645 900000 -101529 900000 -49476 900000 900000 900000 96584 900000 900000 900000 150969 43368 900000 900000 900000 900000 900000 84357 900000 27170 -38343 460 900000 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3259 728 1248 -5461 93 1852 70 3391 -11070 225 1898 -209 -9551 -2365 -949 -5980 -2899 -2389 2097 -5841 7670 1526 1859 -1951 -7866 1151 5509 -786 1923 -6298 -6023 -4181 4962 -895 3069 4214 -3376 -118 1505 1428 4315 5416 -5242 5885 -1892 1933 7093 4933 73 -379 1820 -4387 -2489 5424 -3792 6814 2076 -5523 1357 -499 3197 -9554 SS 20230815T112736.9Z 8627.477511 87 1 51.08 2 78.76 80.82 68.57 78.97 0.00 1 0.00 1 0 25 2.711e-01 1.235e-02 1.037e-01 3.257e-03 6.151741e-01 1.792541e-03 6.541005e-03 -6.000000e+00 1.635511e-01 231.58 -2.00 3.44 -2.00 320.80 0.00e+00 2.280988e-03 6.293361e-04 4.731559e-04 -6.000000e+00 7.640558e-03 292.13 -2.00 20.00 -2.00 320.46 0.00e+00 4.950 0.002 302.00 328.00 3 3.2266e+00 5.2042e-03 5.8863e-02 -6.0000e+00 4.1700e-01 -4.4820e-03 6.8470e-03 3.2029e-02 -6.0000e+00 4.5829e-01 8.6232e-03 7.7866e-03 1.6816e-02 -6.0000e+00 2.6204e-01 -1.2684e-02 3.9448e-03 5.2236e-03 -6.0000e+00 1.1010e-01 8.0312e-05 -1.3286e-04 9.8010e-05 5.8121e-05 -6.0000e+00 7.8687e-03 2.2046e-02 9.1407e-05 12 8 8 10 0 0 96.96 23.20 0.52 0.02205 0.02105 46 8 1 5 0 1110.230 25.17 20.00 23.20 33.84 35.5 1030.70 900000 900000 900000 -104120 900000 900000 900000 900000 900000 900000 -116134 -2119 -118597 12989 900000 900000 -116919 900000 900000 22060 -64355 97829 55994 9801 -12301 44532 -61249 28059 -33416 46296 79549 30838 -10330 -10163 14148 2624 -8475 1306 19367 6042 5020 24757 9687 2870 16628 -7450 -22829 -4294 14943 15026 2345 15222 6891 -3753 2221 2174 668 969 1893 4376 -6295 545 2541 4843 856 3083 -4883 4582 -2670 1882 65 988 -3967 570 -1317 -513 -307 -747 1573 -1167 3917 -1024 -648 -1489 -1822 -554 344 749 1340 -1356 680 2731 -160 -875 -1047 1125 -447 -306 -402 577 -1208 1397 1109 -401 -707 -2682 136 61 63 125 -348 -655 -325 1107 -92 420 826 -137 -299 58 -61 -594 838 -824 1199 -644 1312 1318 1002 -319 -160 -222 -414 -206 558 -694 527 195 -634 404 -245 573 -789 900000 900000 900000 -720 900000 900000 900000 900000 900000 900000 -1598 -12 -2626 102 900000 900000 -5073 900000 900000 318 -2158 712 668 200 -333 733 -2751 528 -1174 874 1307 945 -523 -516 556 123 -509 87 1319 538 493 2150 1010 326 1702 -979 -3554 -587 1801 1979 388 2460 1310 -845 496 505 160 229 436 997 -1688 153 787 1589 292 1007 -1726 1579 -1104 838 31 481 -1960 255 -550 -196 -114 -293 690 -605 2205 -663 -444 -1083 -1412 -447 286 628 1104 -1093 509 1913 -113 -660 -880 1044 -469 -351 -478 665 -1324 1388 1066 -406 -758 -3036 158 75 84 179 -532 -1022 -501 1627 -131 586 1172 -203 -464 91 -95 -906 1237 -1196 1667 -883 1760 1870 1555 -538 -285 -410 -794 -413 1164 -1498 1146 430 -1389 853 -501 1125 -1560 SS 20230815T113315.0Z 8627.481424 90 1 50.69 2 77.65 81.64 67.50 79.73 0.00 1 0.00 1 0 17 4.187e-01 5.819e-03 1.840e-01 1.636e-03 5.702284e-01 8.527273e-04 6.213131e-03 -6.000000e+00 2.418586e-01 231.58 -2.00 3.44 -2.00 320.34 0.00e+00 1.569284e-03 2.664451e-04 3.614626e-04 -6.000000e+00 9.869244e-03 292.13 -2.00 20.00 -2.00 320.00 0.00e+00 4.540 0.001 302.00 328.00 3 2.3935e+00 2.4238e-03 5.4141e-02 -6.0000e+00 6.1184e-01 -1.7353e-02 2.9941e-03 2.9532e-02 -6.0000e+00 6.6697e-01 1.0220e-02 3.1212e-03 1.5187e-02 -6.0000e+00 3.8997e-01 -1.1838e-02 1.6283e-03 4.5884e-03 -6.0000e+00 1.5969e-01 2.8788e-04 -2.8264e-04 4.7137e-05 4.9835e-05 -6.0000e+00 1.1508e-02 2.1447e-02 9.8458e-05 10 0 0 10 0 0 94.26 23.20 0.35 0.02145 0.01932 121 22 1 5 0 418.820 25.17 20.00 23.20 33.93 35.4 1030.96 21566 77036 85447 -95115 114643 33183 364081 -34195 900000 234480 -38673 -15983 -48033 -12895 32402 10678 -39890 16848 20710 13053 -29540 16027 2064 9566 -10898 19114 -24138 -1060 -12303 5053 15709 -1025 -1813 -6759 2585 -5601 -2948 -7458 4044 -2846 1038 2264 409 -822 884 -3682 -7746 -2627 390 3355 -841 2894 2038 209 705 1128 64 -505 1282 997 -921 627 2517 2451 1252 1366 -643 1515 69 592 -133 651 -1291 831 -1022 22 -106 -544 -371 -517 328 -1627 -1152 -1115 -842 -218 554 294 872 -60 518 811 534 665 227 763 254 -87 -508 441 -709 475 466 -497 -1129 -1157 -638 -384 63 -116 -22 -147 -40 190 259 410 393 233 -290 -435 -359 241 10 -137 431 142 961 848 550 146 217 -187 -194 -242 17 -263 448 -187 -213 -20 -173 196 -187 78 179 186 -1173 183 116 581 -308 900000 374 -466 -185 -975 -232 451 212 -1458 384 487 348 -1225 435 70 330 -496 674 -1191 -44 -584 229 759 -63 -125 -489 165 -412 -246 -796 471 -412 158 363 69 -144 155 -692 -1430 -477 72 655 -192 702 544 61 215 357 21 -163 398 314 -316 238 980 1036 535 562 -270 659 35 336 -76 378 -742 469 -532 10 -48 -258 -202 -309 224 -1266 -897 -923 -747 -205 538 292 847 -56 444 649 447 552 214 775 297 -108 -661 550 -825 525 493 -558 -1369 -1394 -811 -523 88 -171 -35 -240 -64 287 388 597 587 350 -465 -717 -584 376 17 -210 631 200 1325 1253 867 256 389 -354 -366 -486 34 -562 970 -414 -465 -42 -359 386 -367 SS 20230815T113830.9Z 8627.485080 93 1 50.76 2 76.62 82.41 66.50 80.44 0.00 1 0.00 1 0 25 6.905e-02 4.695e-03 3.801e-02 1.168e-03 5.340935e-01 6.011314e-04 5.883079e-03 -6.000000e+00 3.984146e-02 231.58 -2.00 3.44 -2.00 319.99 0.00e+00 9.950233e-04 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