File name: Pandora31s1_CharlesCityVA_20230817_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20230818T094236.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20230817_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20230817 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230817T130015.8Z 8629.541849 121 1 3.50 2 60.70 95.40 72.59 87.87 0.00 1 0.00 1 0 17 9.455e-03 5.626e-03 5.504e-03 2.389e-03 2.669200e-01 1.216947e-03 3.122334e-03 -6.000000e+00 5.452254e-03 231.46 -2.00 3.44 -2.00 316.59 0.00e+00 1.787906e-04 1.329404e-04 4.303873e-05 -6.000000e+00 2.174141e-04 292.05 -2.00 20.00 -2.00 316.25 0.00e+00 2.034 0.000 302.00 328.00 3 3.3800e+00 3.2031e-03 2.4525e-02 -6.0000e+00 1.3764e-02 2.0736e-03 3.5754e-03 1.3561e-02 -6.0000e+00 1.5000e-02 -4.7987e-04 2.0860e-03 6.6091e-03 -6.0000e+00 8.7933e-03 -2.4956e-03 9.7287e-04 1.8269e-03 -6.0000e+00 3.6037e-03 1.7286e-03 -2.2108e-04 6.8720e-05 2.1785e-05 -6.0000e+00 2.5983e-04 2.1715e-02 8.6048e-05 12 1 1 12 1 1 94.91 23.18 0.24 0.02171 0.02005 8 25 1 5 0 368.270 25.17 20.00 23.18 34.85 35.4 1035.48 -938 -1615 -3547 1483 -3581 -1477 -1532 2656 -1221 1071 -1810 486 -2368 1042 846 389 -1157 -183 1688 -291 499 1271 1744 -293 851 815 -484 112 251 579 1230 2324 -258 -647 -2094 -1302 -1781 -401 -674 -937 -813 -742 -785 -890 447 -1367 -222 -786 511 301 226 577 1274 763 868 813 315 331 529 1413 772 1339 497 271 -176 -409 -41 797 357 95 388 173 141 -202 -186 -99 -431 -167 -209 -256 -1016 -1615 -1270 -950 -998 -415 -203 -119 275 169 643 649 853 613 732 556 780 -224 -284 -103 -131 -304 194 -172 -871 -952 -806 -376 40 44 64 -124 -87 -135 146 578 371 285 36 -471 58 -217 -89 -72 335 570 1222 1111 550 653 275 17 63 41 -259 -153 182 -527 -372 -93 -127 -345 -83 -151 -274 -596 224 -525 -217 -250 468 -229 198 -345 99 -567 263 240 113 -352 -58 541 -98 167 424 608 -106 317 310 -179 40 86 204 444 900 -109 -266 -825 -532 -797 -202 -375 -568 -523 -494 -514 -584 300 -926 -145 -506 322 196 153 414 925 582 677 627 246 255 414 1110 622 1127 441 242 -156 -344 -33 660 309 89 379 173 138 -194 -169 -83 -345 -132 -176 -235 -989 -1675 -1345 -1033 -1137 -488 -249 -144 337 200 718 699 880 640 781 642 949 -287 -372 -133 -161 -356 227 -210 -1093 -1224 -1085 -515 57 65 96 -185 -126 -188 192 745 488 387 51 -679 83 -309 -125 -99 447 739 1559 1428 745 918 396 25 93 62 -410 -246 293 -871 -611 -151 -203 -534 -130 SS 20230817T132645.2Z 8629.560245 143 1 50.73 2 55.48 99.86 67.50 91.86 0.00 1 0.00 1 0 17 7.354e-03 4.864e-03 8.236e-04 2.920e-04 2.306068e-01 1.476134e-04 2.695019e-03 -6.000000e+00 4.241349e-03 231.45 -2.00 3.44 -2.00 317.20 0.00e+00 1.529468e-04 1.852899e-05 4.425055e-05 -6.000000e+00 1.690874e-04 292.04 -2.00 20.00 -2.00 316.84 0.00e+00 1.759 0.000 302.00 328.00 3 1.8313e+00 3.9158e-04 2.1227e-02 -6.0000e+00 1.0707e-02 -1.5011e-02 4.3784e-04 1.1762e-02 -6.0000e+00 1.1668e-02 4.1749e-03 2.6159e-04 5.7316e-03 -6.0000e+00 6.8400e-03 -3.3084e-03 1.2565e-04 1.5832e-03 -6.0000e+00 2.8037e-03 1.1373e-02 1.1449e-05 8.5671e-06 1.8434e-05 -6.0000e+00 2.0209e-04 2.1088e-02 1.0961e-04 11 1 0 11 16 0 99.62 23.20 0.23 0.02109 0.02117 977 175 1 5 0 51.860 25.17 20.00 23.20 35.37 35.5 1039.00 -1134 -1738 -2424 -3084 -2320 -918 -475 658 -453 -763 -907 -197 -324 317 -160 -360 18 88 389 265 202 627 614 263 406 -39 -278 -158 498 923 1185 1418 -60 -1175 -1486 -1147 -946 -309 -484 -838 -925 -827 -887 -638 -443 -672 -559 -593 -169 591 734 720 994 785 790 860 468 594 628 1031 1092 1301 1213 548 90 -2 -155 490 596 198 139 -27 -50 16 0 -11 -133 6 -189 -648 -886 -1463 -1514 -1155 -815 -566 -222 -50 -50 131 285 347 629 809 569 510 583 -36 -255 -181 -455 -365 202 -325 -677 -667 -564 -385 124 83 31 -50 6 -29 297 453 458 275 58 -373 -207 -93 28 261 450 543 1010 934 602 343 152 23 96 94 -112 -103 72 -196 -315 -128 -305 -297 -243 -151 -244 -331 -378 -259 -103 -59 91 -68 -115 -136 -32 -59 65 -37 -88 4 23 104 73 56 172 176 80 129 -13 -87 -45 135 256 350 450 -20 -390 -467 -375 -351 -135 -253 -453 -529 -489 -534 -383 -265 -398 -321 -331 -93 331 437 456 661 545 559 621 342 427 445 737 823 1058 1062 498 78 -1 -116 369 497 185 129 -26 -47 14 0 -9 -96 4 -146 -568 -799 -1443 -1572 -1263 -956 -706 -269 -62 -60 162 322 355 597 769 585 580 735 -46 -336 -229 -578 -430 232 -401 -839 -867 -767 -546 184 122 47 -76 8 -41 384 605 579 368 84 -570 -320 -141 41 364 595 735 1310 1247 801 485 225 35 147 152 -179 -171 124 -343 -548 -216 -499 -470 -409 SS 20230817T133059.7Z 8629.563191 146 1 50.87 2 54.65 100.61 66.68 92.51 0.00 1 0.00 1 0 17 6.869e-03 5.250e-03 3.925e-04 2.110e-04 2.260228e-01 1.079071e-04 2.652104e-03 -6.000000e+00 3.962093e-03 231.45 -2.00 3.44 -2.00 315.99 0.00e+00 1.809991e-04 1.021328e-05 2.937462e-05 -6.000000e+00 1.579303e-04 292.04 -2.00 20.00 -2.00 315.65 0.00e+00 1.723 0.000 302.00 328.00 3 1.7464e+00 2.8219e-04 2.0769e-02 -6.0000e+00 1.0003e-02 -1.5664e-02 3.1429e-04 1.1467e-02 -6.0000e+00 1.0900e-02 3.2435e-03 1.8069e-04 5.5871e-03 -6.0000e+00 6.3895e-03 -2.3207e-03 8.1289e-05 1.5414e-03 -6.0000e+00 2.6193e-03 1.2926e-02 1.0787e-04 6.1037e-06 1.9201e-05 -6.0000e+00 1.8876e-04 2.0793e-02 1.2600e-04 10 0 0 10 0 0 99.72 23.21 0.26 0.02079 0.02160 1180 212 1 5 0 42.880 25.17 20.00 23.21 35.89 35.6 1043.16 -917 -1171 -2023 -2612 -1662 -992 460 681 307 -575 -431 -280 -205 384 28 -43 2 363 448 576 438 928 606 451 331 67 -329 -66 569 914 1333 1360 212 -1120 -1175 -1223 -800 -353 -339 -838 -834 -820 -906 -609 -467 -626 -632 -554 -156 667 657 802 904 746 719 784 483 504 670 1021 1132 1241 1213 513 58 -31 -178 496 470 158 12 -20 -127 -77 -105 -70 -150 -40 -252 -659 -875 -1560 -1452 -1200 -857 -540 -174 -105 -33 90 319 440 574 830 605 568 539 12 -312 -165 -487 -328 156 -336 -729 -774 -595 -437 124 23 43 -64 -7 6 373 515 496 347 120 -267 -178 4 60 322 520 566 1057 954 628 347 163 -15 106 23 -105 -163 53 -249 -354 -213 -356 -304 -247 -206 -275 -463 -536 -336 -203 95 157 77 -145 -107 -75 -62 122 10 -16 1 135 172 227 173 365 250 196 150 31 -147 -27 221 361 560 614 102 -529 -523 -568 -394 -194 -209 -583 -582 -591 -666 -446 -340 -452 -443 -377 -110 454 476 616 693 597 587 652 406 418 547 841 935 1107 1111 487 53 -27 -154 429 428 155 12 -20 -128 -77 -96 -60 -124 -32 -213 -601 -849 -1656 -1552 -1353 -995 -640 -216 -132 -41 106 355 463 585 846 638 637 645 16 -405 -205 -586 -381 177 -409 -924 -991 -796 -587 175 33 62 -95 -10 8 473 650 637 454 164 -372 -251 6 83 441 674 724 1296 1203 818 481 227 -21 154 34 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