File name: Pandora31s1_CharlesCityVA_20231104_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20231105T060747.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20231104_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20231104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231104T124636.6Z 8708.532368 282 1 49.34 2 78.14 120.07 30.22 253.80 0.00 1 0.00 1 0 17 5.517e-01 1.973e-02 1.943e-01 4.938e-03 5.789305e-01 2.649691e-03 6.244938e-03 -6.000000e+00 3.222849e-01 224.88 -2.00 3.44 -2.00 320.54 0.00e+00 -2.276517e-03 8.997480e-04 4.225942e-04 -6.000000e+00 1.640334e-02 284.57 -2.00 20.00 -2.00 320.21 0.00e+00 4.714 0.002 302.00 328.00 3 4.2830e+00 7.5685e-03 5.5116e-02 -6.0000e+00 8.0870e-01 1.9692e-02 9.7502e-03 2.9209e-02 -6.0000e+00 8.9250e-01 1.2765e-02 1.0797e-02 1.5641e-02 -6.0000e+00 5.1006e-01 -1.5492e-02 5.5676e-03 4.9852e-03 -6.0000e+00 2.2072e-01 3.6308e-05 5.5090e-04 1.4973e-04 5.5054e-05 -6.0000e+00 1.6211e-02 1.1295e-02 1.1490e-04 12 9 8 11 32 0 99.89 22.53 0.52 0.01130 0.01544 14 3 1 5 0 3523.120 25.47 20.01 22.53 13.74 33.7 933.10 900000 900000 900000 900000 -32803 900000 900000 900000 900000 900000 -117234 900000 9719 -81630 900000 290752 -74907 132539 900000 -32564 -20351 334921 24549 41050 29466 900000 -84822 120192 -26156 17946 -39717 122296 -15050 82159 -14619 128759 -17807 26675 240194 9487 9725 17109 3780 -19934 30251 25615 5395 -3541 36498 29542 -6854 27386 -3581 -5950 -4459 6056 -3951 17046 -669 11875 -11834 606 6891 5199 -6032 6424 -5528 1374 196 1717 393 1028 -3159 6986 -760 2443 -1397 -4907 4156 -3446 3421 2555 -331 663 -3157 627 -765 -76 720 -6261 -2096 1517 379 1690 -360 -1261 -237 1169 -859 1373 -2368 1253 1249 1191 -1471 -2131 -6 2238 -47 129 -827 -39 -950 1306 89 1992 -666 -463 -1456 613 1233 -706 1270 -1719 1086 684 189 1064 1857 -179 -203 -390 -1359 -208 153 -319 535 45 -26 844 -258 950 -1730 900000 900000 900000 900000 -171 900000 900000 900000 900000 900000 -2662 900000 96 -2370 900000 1396 -3059 808 900000 -1087 -616 1609 556 887 773 900000 -6798 1315 -1164 586 -2611 2000 -1009 2212 -952 2282 -1464 1758 2544 1043 1168 2027 524 -3481 3346 3004 776 -572 4240 3978 -1442 4606 -873 -1594 -1240 1596 -1163 4086 -184 2922 -3821 193 2317 1914 -2461 2273 -2182 537 87 841 208 552 -1712 3267 -349 1000 -571 -2153 1899 -1938 2050 1700 -240 502 -2621 530 -678 -68 630 -5548 -1691 1130 280 1295 -310 -1226 -255 1355 -1047 1608 -2680 1275 1224 1212 -1618 -2452 -7 2756 -63 188 -1281 -61 -1482 1932 127 2746 -952 -687 -2271 959 1901 -1077 1868 -2508 1506 924 253 1489 2814 -296 -355 -707 -2565 -406 312 -672 1137 98 -55 1738 -516 1819 -3359 SS 20231104T125532.4Z 8708.538569 288 1 50.90 2 76.62 121.63 31.91 255.84 0.00 1 0.00 1 0 25 6.792e-02 4.851e-03 3.652e-02 1.126e-03 5.391848e-01 5.681569e-04 6.045645e-03 -6.000000e+00 3.827263e-02 224.88 -2.00 3.44 -2.00 319.90 0.00e+00 5.760475e-04 1.606010e-04 2.960542e-04 -6.000000e+00 1.560656e-03 284.57 -2.00 20.00 -2.00 319.57 0.00e+00 4.215 0.001 302.00 328.00 3 2.1292e+00 1.5775e-03 4.9880e-02 -6.0000e+00 9.5160e-02 -1.3894e-02 1.8877e-03 2.7005e-02 -6.0000e+00 1.0416e-01 2.6170e-02 1.8380e-03 1.3953e-02 -6.0000e+00 6.1369e-02 -1.9399e-02 9.8155e-04 4.2480e-03 -6.0000e+00 2.5545e-02 5.2867e-04 -2.9472e-04 3.1861e-05 4.7672e-05 -6.0000e+00 1.8633e-03 1.1094e-02 1.0310e-04 10 0 0 10 0 0 99.91 22.53 0.23 0.01109 0.00888 174 31 1 5 0 292.470 25.47 20.01 22.53 14.45 33.8 936.37 14102 -31425 31636 -11709 -33505 -16117 -16282 2344 26400 10520 -20440 -13333 -8570 -9320 4438 4488 -12372 -4663 -4347 -3948 -6007 7239 -3108 -2331 -1078 4141 -13648 -2935 -4800 -925 -2173 4082 -1881 -2672 -2614 -2004 -3758 -2030 4894 -1690 -1842 -450 -181 -3144 830 -672 -787 -1396 533 1204 -367 1757 703 328 161 970 -329 914 360 1518 -159 965 2063 957 322 736 46 734 590 483 6 86 -250 403 15 304 -300 -374 -300 -729 -336 -1286 -1430 -1135 -870 -396 -117 149 337 171 670 912 767 1047 576 524 734 205 -180 -16 -406 -6 297 -490 -1201 -1109 -712 -280 59 99 -26 -64 101 213 465 444 481 -58 -280 -689 -519 -12 -44 -64 325 489 901 879 482 210 110 10 4 -138 -149 -223 145 -152 -419 50 -82 106 -1 92 -358 196 -104 -351 -150 -172 24 237 118 -333 -240 -184 -230 116 134 -481 -184 -182 -173 -273 296 -153 -125 -62 235 -917 -170 -286 -59 -165 337 -184 -266 -250 -200 -407 -263 726 -312 -374 -96 -40 -722 186 -156 -185 -340 123 298 -103 532 234 118 61 378 -132 358 138 580 -66 409 973 495 168 367 23 380 324 302 4 60 -169 254 8 168 -159 -205 -175 -501 -248 -1075 -1213 -1019 -836 -381 -117 152 338 172 622 789 682 920 571 563 855 256 -236 -20 -503 -7 332 -576 -1452 -1410 -909 -381 83 153 -41 -105 163 324 694 641 708 -91 -443 -1129 -840 -19 -70 -97 470 712 1277 1261 773 357 194 19 7 -271 -299 -449 299 -317 -870 104 -159 204 -2 SS 20231104T130524.9Z 8708.545427 291 1 29.67 2 74.96 123.40 33.80 257.94 0.00 1 0.00 1 0 25 4.196e-02 4.687e-03 1.219e-02 7.323e-04 4.913487e-01 3.669661e-04 5.587707e-03 -6.000000e+00 2.364089e-02 224.88 -2.00 3.44 -2.00 319.40 0.00e+00 3.780058e-04 8.959512e-05 2.235284e-04 -6.000000e+00 9.641390e-04 284.57 -2.00 20.00 -2.00 319.08 0.00e+00 3.780 0.001 302.00 328.00 3 1.2697e+00 1.0012e-03 4.4922e-02 -6.0000e+00 5.8779e-02 -1.4921e-02 1.1626e-03 2.4486e-02 -6.0000e+00 6.4343e-02 1.6295e-02 1.0068e-03 1.2478e-02 -6.0000e+00 3.7908e-02 -1.3477e-02 5.4452e-04 3.7279e-03 -6.0000e+00 1.5778e-02 1.9948e-03 -4.0734e-04 2.0816e-05 4.0943e-05 -6.0000e+00 1.1511e-03 1.0991e-02 7.1110e-05 12 1 1 12 1 1 99.86 22.54 0.27 0.01099 0.00793 298 92 1 5 0 99.200 25.47 20.00 22.54 15.73 33.9 943.00 -17399 -10212 -13613 -6665 -18607 -12707 -13760 -8304 -10665 -13234 -16145 -14279 -6298 -7881 124 -3428 -1424 -3714 -172 -2192 -301 118 -1444 -535 -2886 -706 -3962 -1761 -2787 145 -1169 2420 -399 -1057 -2458 -2727 -1832 -1271 251 -1268 -932 -1018 -447 -1149 89 -1016 -775 -157 -44 1118 278 825 846 744 592 964 327 616 521 801 800 1337 1680 800 405 444 268 589 573 284 352 128 -89 112 -6 30 -272 61 -398 -735 -677 -1370 -1459 -1150 -838 -584 -286 32 218 304 711 790 960 906 692 477 549 43 -267 -20 -445 -221 193 -452 -976 -834 -593 -432 50 5 35 -95 168 197 425 501 360 -31 -241 -583 -471 -159 -108 155 287 466 1004 987 414 386 171 44 108 -3 -239 -155 66 -144 -372 -61 -130 -101 32 -275 -165 -231 -107 -318 -214 -265 -159 -233 -313 -414 -419 -210 -328 6 -184 -82 -236 -11 -153 -21 8 -111 -45 -265 -66 -378 -157 -250 14 -120 274 -52 -138 -311 -362 -278 -233 55 -303 -242 -280 -126 -331 26 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