File name: Pandora31s1_CharlesCityVA_20231130_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20231201T062027.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20231130_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20231130 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231130T123656.6Z 8734.525655 278 1 50.53 2 84.99 122.17 61.94 284.09 0.00 1 0.00 1 0 33 7.233e-01 6.384e-02 3.277e-01 1.830e-02 9.596932e-01 1.235728e-02 8.448210e-03 -6.000000e+00 4.617712e-01 223.74 -2.00 3.44 -2.00 322.58 0.00e+00 7.622222e-04 5.792835e-03 1.599896e-03 -6.000000e+00 3.187825e-02 281.77 -2.00 20.00 -2.00 322.20 0.00e+00 9.811 0.016 302.00 328.00 3 5.2797e-01 4.1311e-02 1.0919e-01 -6.0000e+00 1.1392e+00 1.8650e+00 5.6407e-02 4.8166e-02 -6.0000e+00 1.2665e+00 -2.0103e+00 5.7360e-02 2.9200e-02 -6.0000e+00 7.3412e-01 6.4438e-01 2.8881e-02 1.1095e-02 -6.0000e+00 3.4171e-01 6.0205e-06 5.2835e-03 5.8317e-04 1.0944e-04 -6.0000e+00 2.3880e-02 3.7508e-03 1.5638e-04 12 8 8 10 0 0 -43.02 22.12 1.42 0.00375 0.04345 30 5 1 5 0 1684.030 25.17 20.01 22.12 8.21 33.6 915.33 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 196792 285576 900000 -38046 900000 900000 17910 900000 900000 900000 -3703 900000 900000 900000 900000 900000 -95377 900000 35703 900000 -2996 900000 176786 900000 103757 900000 -93 900000 900000 900000 900000 900000 900000 -46270 900000 900000 900000 134237 900000 900000 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1.4439e-04 1.2550e-04 -6.0000e+00 1.5446e-02 4.2166e-03 9.8574e-05 12 8 8 10 0 0 83.66 22.12 0.55 0.00422 0.00586 105 19 1 5 0 484.840 25.17 19.99 22.12 10.26 33.4 923.98 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -111680 900000 900000 900000 900000 900000 -152364 900000 900000 900000 -148494 900000 900000 900000 900000 900000 -230783 900000 -47170 900000 -41721 900000 7718 1346 -53536 900000 51072 900000 900000 46091 34926 297368 900000 -35104 900000 31213 21648 -1733 57479 127410 5268 51624 20322 8544 -95 10707 -2482 13055 -1906 13724 -12452 9867 16336 4635 -858 10065 -5153 5299 305 2460 555 3224 -6775 16276 -2701 8538 -2228 -2656 5086 -2600 7363 590 348 65 -3021 2408 -718 -2005 1252 -5905 1798 2409 -1377 1123 -1688 628 201 1646 -105 345 -2932 1505 115 -705 -2372 -2472 484 700 -302 -988 -440 247 -740 642 -313 662 1829 -206 590 161 183 1231 -299 -751 -201 -103 611 990 1201 -108 -33 -72 -1296 -431 238 -242 602 250 -851 550 -50 675 -596 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -506 900000 900000 900000 900000 900000 -863 900000 900000 900000 -1223 900000 900000 900000 900000 900000 -6534 900000 -253 900000 -344 900000 57 11 -750 900000 315 900000 900000 569 547 1347 900000 -1315 900000 656 535 -59 1207 1522 249 1764 982 516 -7 723 -197 872 -143 881 -1114 816 1498 548 -113 1208 -759 772 54 493 123 711 -1588 2789 -502 1296 -376 -498 1065 -719 2027 200 130 26 -1335 1066 -342 -982 584 -2813 745 959 -582 516 -942 409 144 1339 -93 298 -2410 1048 81 -511 -1737 -1913 390 620 -308 -1174 -547 325 -998 835 -396 814 2281 -276 821 227 248 1565 -372 -975 -252 -125 739 1321 1751 -183 -58 -140 -2719 -967 535 -569 1432 603 -2037 1301 -111 1385 -1221 SS 20231130T125837.1Z 8734.540708 284 1 50.86 2 81.42 125.75 65.98 286.68 0.00 1 0.00 1 0 25 3.646e-01 5.260e-03 1.967e-01 1.897e-03 7.743727e-01 1.038296e-03 8.052915e-03 -6.000000e+00 2.089266e-01 223.74 -2.00 3.44 -2.00 321.45 0.00e+00 2.395159e-03 4.324282e-04 8.491494e-04 -6.000000e+00 9.761525e-03 281.76 -2.00 20.00 -2.00 321.10 0.00e+00 6.320 0.004 302.00 328.00 3 6.9332e-01 3.1641e-03 7.4136e-02 -6.0000e+00 5.2246e-01 5.9703e-03 5.0456e-03 4.0441e-02 -6.0000e+00 5.7497e-01 1.0190e-02 6.4477e-03 2.3330e-02 -6.0000e+00 3.3291e-01 -1.4116e-02 3.0939e-03 7.9828e-03 -6.0000e+00 1.4435e-01 2.4309e-04 -2.5006e-04 5.3992e-05 9.2082e-05 -6.0000e+00 1.0659e-02 3.2110e-03 1.0178e-04 10 0 0 10 0 0 32.69 22.13 0.42 0.00321 0.00133 266 48 1 5 0 191.160 25.17 20.01 22.13 12.73 33.6 934.64 900000 900000 900000 900000 -96702 -166045 900000 900000 900000 900000 170380 -151458 900000 -125050 900000 -8173 -88609 -27088 -26276 -2872 -63342 93478 -65978 132150 -53213 57944 -88063 1076 -27952 -3902 -27873 22843 -10054 -17911 -4806 -17082 -11894 -9326 37469 -11407 -3233 1711 3722 -13404 5074 6247 785 1161 2582 9927 -4102 6576 2051 2893 51 26 -287 1606 1327 1360 -1723 341 4717 563 1660 2113 -423 1861 802 789 192 1518 -322 1437 -1253 1324 -1304 0 -345 -1471 332 -1104 -784 -1304 -785 -490 232 -322 796 -836 357 1085 158 547 1 311 516 603 -151 347 -733 409 341 -498 -1466 -1287 -83 -143 138 -175 -125 -164 54 93 267 576 618 249 -169 -393 -135 580 -299 -184 -252 189 709 714 437 83 -79 -91 -235 -365 -88 -185 299 35 -442 178 -64 445 -164 900000 900000 900000 900000 -179 -460 900000 900000 900000 900000 315 -895 900000 -1039 900000 -33 -933 -175 -184 -17 -702 224 -865 268 -757 289 -1744 10 -351 -46 -530 321 -228 -456 -105 -445 -343 -294 1017 -548 -161 88 197 -869 282 358 50 79 188 753 -412 672 244 376 7 4 -44 241 194 199 -278 56 868 122 370 467 -99 458 229 259 69 550 -115 467 -377 354 -350 0 -117 -608 146 -564 -435 -776 -498 -328 161 -229 552 -560 221 637 94 351 1 253 491 654 -164 368 -777 382 297 -448 -1428 -1319 -89 -157 169 -245 -183 -252 83 138 378 847 870 370 -266 -629 -209 853 -428 -271 -359 260 959 1049 695 151 -149 -183 -478 -795 -205 -449 697 82 -1036 415 -139 962 -351 SS 20231130T131324.6Z 8734.550979 289 1 50.92 2 79.08 128.30 68.71 288.46 0.00 1 0.00 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