File name: Pandora31s1_CharlesCityVA_20231207_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20240113T153609.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20231207_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20231207 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231207T124349.1Z 8741.530429 225 1 49.98 2 84.98 123.53 40.80 179.98 0.00 1 0.00 1 0 33 7.679e-01 8.097e-02 3.123e-01 2.295e-02 9.435412e-01 1.565177e-02 7.563123e-03 -6.000000e+00 4.872258e-01 223.61 -2.00 3.44 -2.00 322.58 0.00e+00 -3.179175e-02 7.408045e-03 1.593540e-03 -6.000000e+00 3.112480e-02 281.05 -2.00 20.00 -2.00 322.18 0.00e+00 9.789 0.016 302.00 328.00 3 1.0511e+00 5.2725e-02 1.0768e-01 -6.0000e+00 1.2144e+00 1.8255e+00 6.6521e-02 4.4192e-02 -6.0000e+00 1.3457e+00 -1.9155e+00 6.3347e-02 2.6027e-02 -6.0000e+00 7.7516e-01 5.3989e-01 3.2744e-02 1.0005e-02 -6.0000e+00 3.4117e-01 4.1108e-06 9.8146e-03 7.3400e-04 9.0750e-05 -6.0000e+00 2.6174e-02 5.8307e-03 1.4611e-04 12 8 8 10 0 0 43.81 22.11 1.52 0.00583 0.07958 20 4 1 5 0 2498.260 25.17 20.00 22.11 9.14 33.7 920.15 900000 900000 216690 900000 900000 900000 900000 900000 900000 900000 218125 900000 900000 433 900000 900000 5872 900000 900000 900000 -22930 900000 900000 900000 900000 900000 -50228 900000 900000 900000 -58561 900000 296919 900000 9861 900000 28088 900000 900000 900000 900000 900000 900000 -46035 900000 900000 900000 88250 900000 900000 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5521 -4900 900000 5402 4482 -3216 -1867 5548 -1862 7481 10869 8592 9426 -3124 9463 -280 2835 9012 -29944 3907 5668 669 4961 679 -3598 -5608 6822 5878 5308 -13314 10651 3850 2840 -4580 -10344 5364 16613 585 -7554 -13679 1879 -10420 4740 -5804 9276 12541 -6478 9501 2880 1978 14839 6001 -14293 -2850 -1134 -1286 9464 14273 -3194 -6222 5639 -18432 -5609 6160 -860 9670 9322 -14123 11373 -5917 10627 -9931 SS 20231207T125602.7Z 8741.538920 228 1 51.04 2 82.97 125.53 40.94 184.57 0.00 1 0.00 1 0 25 4.529e-01 1.253e-02 2.616e-01 4.666e-03 8.846724e-01 2.864566e-03 8.719494e-03 -6.000000e+00 2.773684e-01 223.61 -2.00 3.44 -2.00 322.02 0.00e+00 -1.557882e-03 1.329419e-03 1.294741e-03 -6.000000e+00 1.992234e-02 281.05 -2.00 20.00 -2.00 321.66 0.00e+00 7.507 0.007 302.00 328.00 3 1.1509e+00 9.4152e-03 8.7590e-02 -6.0000e+00 7.0754e-01 2.9785e-02 1.8666e-02 4.8143e-02 -6.0000e+00 7.8577e-01 -6.3999e-03 2.4553e-02 2.9739e-02 -6.0000e+00 4.4145e-01 -1.7233e-02 1.1058e-02 1.0729e-02 -6.0000e+00 2.1600e-01 4.6747e-05 8.2671e-04 1.4361e-04 1.2185e-04 -6.0000e+00 1.4328e-02 5.4747e-03 1.2219e-04 12 8 8 10 0 0 61.79 22.12 0.45 0.00547 0.01169 88 16 1 5 0 579.900 25.17 20.00 22.12 11.17 33.7 929.04 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 66623 900000 900000 900000 -108664 900000 900000 900000 900000 900000 -215351 900000 -63950 900000 -81565 900000 43743 900000 122313 900000 -8354 65072 900000 38656 180282 157581 169663 -44465 900000 37274 29032 31954 49626 138718 -14046 58242 -3651 -4515 -655 14883 2793 22819 5992 20139 -16703 6908 22329 5997 -3032 6776 -1640 -2040 -761 5498 -1845 2118 -4563 13516 324 10846 -3073 -1926 3914 -3844 6252 1721 698 -681 -2481 -347 -1730 -902 3637 -7048 2311 1796 -767 845 -1421 -1083 -224 1308 -266 114 -2294 1964 1714 173 -1488 -2715 614 2120 279 -740 -661 -575 -658 -216 -396 1178 2052 -247 903 -93 -172 1161 -312 -918 -207 -91 336 1397 560 -53 -153 -479 -865 -328 171 -228 811 213 -472 366 -109 612 -728 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 301 900000 900000 900000 -604 900000 900000 900000 900000 900000 -6062 900000 -457 900000 -1020 900000 247 900000 553 900000 -104 490 900000 582 814 890 894 -1885 900000 814 732 854 1233 1619 -815 1882 -247 -344 -52 1076 235 1546 464 1351 -1736 653 2134 769 -415 918 -237 -325 -139 1088 -426 480 -1063 2421 59 1764 -533 -365 841 -1088 1901 630 283 -279 -1110 -161 -846 -443 1679 -3437 1033 781 -350 395 -800 -723 -175 1079 -237 99 -1874 1455 1181 125 -1167 -2275 534 1873 286 -884 -834 -771 -891 -285 -502 1534 2562 -332 1257 -132 -234 1481 -414 -1186 -257 -110 405 1846 822 -89 -273 -928 -1803 -694 386 -537 1928 515 -1125 817 -239 1251 -1491 SS 20231207T130640.7Z 8741.546304 231 1 50.99 2 81.27 127.32 41.22 188.53 0.00 1 0.00 1 0 17 2.219e-01 4.777e-03 1.965e-01 1.990e-03 7.580247e-01 1.091674e-03 7.963586e-03 -6.000000e+00 1.280611e-01 223.61 -2.00 3.44 -2.00 321.36 0.00e+00 2.329760e-03 4.435733e-04 7.944875e-04 -6.000000e+00 6.159871e-03 281.05 -2.00 20.00 -2.00 321.02 0.00e+00 6.227 0.004 302.00 328.00 3 9.1451e-01 3.2894e-03 7.2886e-02 -6.0000e+00 3.1940e-01 2.8568e-02 5.1193e-03 3.9442e-02 -6.0000e+00 3.5224e-01 1.4931e-02 6.5189e-03 2.2512e-02 -6.0000e+00 2.0253e-01 -1.9819e-02 3.1559e-03 7.6385e-03 -6.0000e+00 8.8415e-02 2.1223e-04 -2.2298e-04 5.6597e-05 9.0579e-05 -6.0000e+00 6.4695e-03 5.0869e-03 9.4722e-05 10 0 0 10 0 0 48.06 22.13 0.38 0.00509 0.00341 212 38 1 5 0 240.480 25.17 20.00 22.13 13.30 33.6 937.30 900000 900000 900000 900000 900000 -85793 900000 900000 900000 900000 -107564 72669 1887 -72619 900000 44329 -57582 -4583 10695 39089 -43363 68586 -19940 32052 -14008 82119 -75043 -34197 -10075 -23141 -27062 29490 -10711 -8170 -15760 -2249 -19729 3593 13211 -6300 -6644 5375 7996 -11686 7877 -2509 1138 -576 9744 6391 21 2806 1575 -1637 -288 1136 -831 2682 -1362 2193 -3377 1623 3560 1539 180 3418 -584 1272 61 684 324 211 -613 925 -235 560 149 -1167 958 -856 431 -675 -1186 -972 -1342 -366 -570 -202 496 -594 -39 734 153 846 50 381 967 22 177 27 -475 449 669 -214 -1199 -1028 -254 38 185 -211 -284 -112 -87 243 290 803 433 236 45 -492 -289 507 8 -555 -135 17 650 612 518 -53 -67 -248 -405 -208 -123 -158 266 98 -407 297 -129 403 -54 900000 900000 900000 900000 900000 -166 900000 900000 900000 900000 -396 141 4 -436 900000 129 -487 -28 62 182 -470 252 -197 211 -160 382 -1546 -510 -125 -355 -543 451 -258 -199 -402 -53 -646 115 479 -331 -392 304 465 -850 486 -179 82 -45 746 566 2 306 193 -228 -42 172 -132 404 -208 324 -564 294 734 364 45 817 -149 344 19 226 116 77 -220 328 -76 163 43 -365 346 -349 204 -368 -707 -616 -848 -243 -395 -142 341 -393 -26 459 96 572 36 327 898 24 200 31 -488 438 606 -202 -1139 -1027 -268 44 237 -288 -431 -178 -139 371 423 1134 628 361 73 -764 -462 768 11 -792 -186 23 847 866 843 -92 -129 -483 -837 -460 -275 -367 629 236 -967 665 -286 837 -110 SS 20231207T132110.3Z 8741.556370 236 1 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