File name: Pandora31s1_CharlesCityVA_20231209_L2Fit_fout2c2d20200727p1-8.txt File generation date: 20240113T144002.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vickie Connors Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora31_OF_v4d20190916.txt Instrument calibration file used: Pandora31s1_CF_v2d20200727.txt Level 1 file used: Pandora31s1_CharlesCityVA_20231209_L1_smca1c2d20200727p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20231209 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1347 305.2753 305.4159 305.5564 305.6970 305.8375 305.9780 306.1185 306.2590 306.3995 306.5400 306.6804 306.8209 306.9613 307.1018 307.2422 307.3826 307.5230 307.6633 307.8037 307.9441 308.0844 308.2248 308.3651 308.5054 308.6457 308.7860 308.9262 309.0665 309.2068 309.3470 309.4872 309.6274 309.7677 309.9078 310.0480 310.1882 310.3284 310.4685 310.6086 310.7488 310.8889 311.0290 311.1691 311.3092 311.4492 311.5893 311.7293 311.8694 312.0094 312.1494 312.2894 312.4294 312.5693 312.7093 312.8492 312.9892 313.1291 313.2690 313.4089 313.5488 313.6887 313.8286 313.9684 314.1083 314.2481 314.3879 314.5277 314.6675 314.8073 314.9471 315.0868 315.2266 315.3663 315.5061 315.6458 315.7855 315.9252 316.0649 316.2045 316.3442 316.4838 316.6235 316.7631 316.9027 317.0423 317.1819 317.3214 317.4610 317.6006 317.7401 317.8796 318.0191 318.1586 318.2981 318.4376 318.5771 318.7165 318.8560 318.9954 319.1348 319.2742 319.4136 319.5530 319.6924 319.8318 319.9711 320.1104 320.2498 320.3891 320.5284 320.6677 320.8070 320.9462 321.0855 321.2247 321.3639 321.5032 321.6424 321.7816 321.9207 322.0599 322.1991 322.3382 322.4774 322.6165 322.7556 322.8947 323.0338 323.1729 323.3119 323.4510 323.5900 323.7290 323.8681 324.0071 324.1460 324.2850 324.4240 324.5630 324.7019 324.8408 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231209T125343.5Z 8743.537310 167 1 51.29 2 83.64 125.15 54.90 158.23 0.00 1 0.00 1 0 25 6.278e-01 4.243e-02 2.922e-01 1.106e-02 7.597552e-01 6.783986e-03 7.154437e-03 -6.000000e+00 3.733694e-01 223.58 -2.00 3.44 -2.00 322.00 0.00e+00 -1.078506e-02 2.997539e-03 1.074972e-03 -6.000000e+00 2.086017e-02 280.84 -2.00 20.00 -2.00 321.61 0.00e+00 8.153 0.009 302.00 328.00 3 1.9342e+00 2.1488e-02 8.9674e-02 -6.0000e+00 9.3664e-01 7.5381e-01 3.1409e-02 3.9441e-02 -6.0000e+00 1.0359e+00 -9.7424e-01 3.5949e-02 2.3570e-02 -6.0000e+00 5.9653e-01 3.3778e-01 1.7495e-02 8.5747e-03 -6.0000e+00 2.6466e-01 1.2225e-05 3.2818e-03 3.6729e-04 8.9745e-05 -6.0000e+00 1.9830e-02 -3.3260e-03 1.6999e-04 12 8 8 10 0 0 55.39 23.01 0.98 -0.00333 0.02134 30 5 1 5 0 1709.380 25.90 20.00 23.01 15.41 34.2 947.48 900000 900000 900000 900000 -9427 900000 900000 900000 900000 900000 -112105 900000 291139 -78809 900000 900000 -42898 900000 900000 143007 -41581 900000 900000 900000 62919 900000 -125185 900000 20573 900000 -44656 900000 86649 168768 133855 900000 -35642 900000 900000 142415 269129 900000 900000 -30846 900000 162750 120332 29351 900000 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2035 3728 -3123 4687 -9 539 2527 -13129 488 152 -1920 -2943 -4928 -5114 -4453 1493 -478 576 -10055 4864 1850 1673 -4199 -5043 -49 6103 -846 -2435 -4086 -2805 -4293 1117 -901 1651 7313 -3535 6605 2309 3306 5160 5032 -6081 1503 -99 581 5270 5495 -340 -2784 1707 -9765 -2548 3464 343 5538 4244 -6364 4178 -2841 4667 -8236 SS 20231209T130416.2Z 8743.544632 170 1 51.05 2 81.95 126.91 54.23 161.19 0.00 1 0.00 1 0 17 3.089e-01 1.030e-02 1.672e-01 3.812e-03 7.054961e-01 2.175831e-03 7.278274e-03 -6.000000e+00 1.844162e-01 223.58 -2.00 3.44 -2.00 321.49 0.00e+00 5.655241e-04 9.130357e-04 8.103326e-04 -6.000000e+00 1.166128e-02 280.84 -2.00 20.00 -2.00 321.14 0.00e+00 6.681 0.005 302.00 328.00 3 1.7592e+00 6.6748e-03 7.5480e-02 -6.0000e+00 4.6457e-01 -1.9888e-02 1.0645e-02 3.7157e-02 -6.0000e+00 5.1524e-01 2.5464e-02 1.3626e-02 2.1548e-02 -6.0000e+00 2.8714e-01 -2.6572e-02 6.5345e-03 7.4437e-03 -6.0000e+00 1.3321e-01 6.6535e-05 3.8933e-04 1.1897e-04 8.4317e-05 -6.0000e+00 9.2692e-03 -1.9370e-03 1.2866e-04 12 8 8 10 0 0 86.46 23.02 0.49 -0.00194 0.00099 88 16 1 5 0 579.950 25.90 19.99 23.02 16.51 34.2 951.63 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -114147 900000 900000 -68389 9809 900000 900000 -91969 900000 85266 900000 -40343 900000 -130222 900000 -12862 49529 -46658 107203 -9531 -11173 41786 41118 17256 13554 177642 12532 11453 20279 15900 -10960 40340 15711 -2531 -2739 17945 33055 -1862 25504 -3913 -6204 -3469 2754 -4003 8947 -1895 4500 -10303 274 10401 -514 1571 1690 -3065 1322 -835 2581 -463 2311 -3844 6979 -2272 4137 -2531 -2585 810 -1813 3325 -158 482 -1350 -1750 418 -108 224 951 -3756 -285 1306 31 319 -576 -73 -287 876 595 587 -1915 1746 -88 293 -1703 -1749 181 1648 35 -298 -399 -483 -293 -243 -258 925 986 298 643 -37 -311 1027 174 -1020 351 50 65 806 781 -587 -408 -340 -740 -358 209 -368 652 327 -461 606 -375 577 -458 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -975 900000 900000 -642 51 900000 900000 -1466 900000 316 900000 -551 900000 -4708 900000 -159 382 -1076 694 -212 -261 606 634 394 367 1260 510 528 924 797 -736 1665 859 -173 -199 1139 2004 -183 2149 -491 -812 -471 371 -593 1240 -265 637 -1672 45 1795 -111 342 363 -705 312 -230 790 -159 792 -1364 2074 -670 1041 -661 -720 255 -701 1335 -75 247 -751 -1051 261 -71 150 624 -2460 -169 722 17 190 -399 -55 -252 866 628 607 -1879 1485 -72 244 -1559 -1691 183 1780 40 -389 -576 -691 -418 -354 -357 1233 1342 431 979 -55 -480 1500 248 -1423 467 65 83 1099 1218 -989 -753 -634 -1469 -757 472 -830 1488 760 -1068 1327 -820 1183 -937 SS 20231209T131437.4Z 8743.551822 173 1 50.97 2 80.32 128.67 53.66 164.15 0.00 1 0.00 1 0 25 2.456e-01 4.552e-03 1.496e-01 1.671e-03 6.181765e-01 8.739032e-04 6.640306e-03 -6.000000e+00 1.393196e-01 223.58 -2.00 3.44 -2.00 320.86 0.00e+00 1.376834e-03 3.198023e-04 5.219562e-04 -6.000000e+00 5.898436e-03 280.84 -2.00 20.00 -2.00 320.53 0.00e+00 5.676 0.003 302.00 328.00 3 1.2867e+00 2.5511e-03 6.4346e-02 -6.0000e+00 3.4646e-01 -2.6837e-02 3.4474e-03 3.1492e-02 -6.0000e+00 3.7999e-01 3.0791e-02 4.0516e-03 1.7172e-02 -6.0000e+00 2.2238e-01 -2.2820e-02 2.0526e-03 5.6204e-03 -6.0000e+00 9.3948e-02 2.9403e-04 9.3264e-07 4.9052e-05 6.4020e-05 -6.0000e+00 6.9024e-03 -2.4615e-03 1.2427e-04 10 0 0 10 0 0 66.14 23.01 0.36 -0.00246 -0.00245 231 41 1 5 0 220.580 25.90 20.00 23.01 17.12 34.2 954.45 900000 157107 900000 -77420 151240 -120707 900000 -30812 900000 -17776 -13009 -25931 -30259 -35308 15043 8613 -37388 5575 -13048 1675 -34160 26474 -15138 12748 -9835 20432 -34203 -22560 5298 -16022 -7899 -961 3900 -10249 -1349 -2610 -10916 1705 10171 -1865 -3550 4244 1222 342 2325 2830 -1830 -818 3923 5257 -1050 1604 2222 -1719 882 -876 852 -530 1562 914 -349 1233 2000 1118 -788 1688 -1016 850 -467 668 -319 358 -1284 1178 -88 258 -988 -1225 706 -1258 998 -1163 -756 -1590 -733 -124 -70 420 743 -99 84 878 111 1044 -183 588 623 608 -96 -42 -433 57 603 -234 -806 -1254 -306 -219 73 -210 -73 -101 14 -66 161 697 639 141 -110 -241 -247 205 -83 -348 76 135 578 543 488 -24 5 -299 -144 -224 -106 -247 209 97 -251 150 -64 246 -79 900000 256 900000 -355 246 -858 900000 -119 900000 -74 -61 -154 -242 -382 123 88 -681 73 -224 26 -784 341 -323 228 -240 390 -1134 -648 118 -501 -275 -37 163 -508 -59 -121 -637 107 727 -163 -351 416 130 37 255 318 -222 -102 495 716 -172 285 431 -377 200 -211 207 -129 364 215 -88 345 585 365 -268 545 -338 293 -185 300 -157 180 -640 537 -37 98 -363 -472 307 -661 553 -745 -522 -1178 -579 -97 -57 348 608 -78 66 643 80 789 -148 547 669 692 -117 -50 -479 60 598 -242 -903 -1396 -358 -276 102 -306 -116 -159 22 -103 239 994 930 217 -179 -384 -388 328 -129 -523 110 188 832 784 794 -42 10 -567 -286 -474 -228 -555 479 226 -582 333 -134 513 -164 SS 20231209T132313.7Z 8743.557798 178 1 50.88 2 79.00 130.17 53.27 166.65 0.00 1 0.00 1 0 25 9.789e-02 4.035e-03 6.009e-02 1.101e-03 5.608020e-01 5.593594e-04 6.187876e-03 -6.000000e+00 5.498931e-02 223.58 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