File name: Pandora31s1_CharlesCityVA_20240627_L2Fit_fout2c7d20240321p1-8.txt File generation date: 20241204T072456.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 31 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora31_OF_v1d20240301.txt Instrument calibration file used: Pandora31s1_CF_v7d20240321.txt Level 1 file used: Pandora31s1_CharlesCityVA_20240627_L1_smca1c7d20240321p1-8.txt Full location name: Richmond VCU Short location name: CharlesCityVA Country of location: USA Location latitude [deg]: 37.3260 Location longitude [deg]: -77.2057 Location altitude [m]: 6 Local noon date: 20240627 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.0651 305.2060 305.3469 305.4877 305.6285 305.7694 305.9101 306.0509 306.1917 306.3324 306.4731 306.6138 306.7545 306.8952 307.0358 307.1765 307.3171 307.4577 307.5983 307.7388 307.8794 308.0199 308.1604 308.3009 308.4414 308.5819 308.7223 308.8628 309.0032 309.1436 309.2840 309.4243 309.5647 309.7050 309.8454 309.9857 310.1260 310.2662 310.4065 310.5467 310.6870 310.8272 310.9674 311.1076 311.2477 311.3879 311.5280 311.6682 311.8083 311.9484 312.0884 312.2285 312.3686 312.5086 312.6486 312.7886 312.9286 313.0686 313.2086 313.3485 313.4885 313.6284 313.7683 313.9082 314.0481 314.1879 314.3278 314.4676 314.6075 314.7473 314.8871 315.0269 315.1666 315.3064 315.4461 315.5859 315.7256 315.8653 316.0050 316.1447 316.2843 316.4240 316.5636 316.7032 316.8428 316.9824 317.1220 317.2616 317.4012 317.5407 317.6802 317.8198 317.9593 318.0988 318.2383 318.3777 318.5172 318.6566 318.7961 318.9355 319.0749 319.2143 319.3537 319.4930 319.6324 319.7717 319.9111 320.0504 320.1897 320.3290 320.4683 320.6075 320.7468 320.8860 321.0253 321.1645 321.3037 321.4429 321.5821 321.7212 321.8604 321.9996 322.1387 322.2778 322.4169 322.5560 322.6951 322.8342 322.9732 323.1123 323.2513 323.3904 323.5294 323.6684 323.8074 323.9463 324.0853 324.2243 324.3632 324.5021 324.6411 324.7800 324.9189 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240627T110427.6Z 8944.461431 231 1 29.90 2 77.55 70.07 47.50 202.04 0.00 1 0.00 1 0 25 2.344e-01 5.879e-03 2.145e-01 3.831e-03 6.185091e-01 2.076886e-03 6.838787e-03 -6.000000e+00 1.373589e-01 232.73 -2.00 3.44 -2.00 320.89 0.00e+00 -4.768014e-04 9.242463e-04 3.374637e-04 -6.000000e+00 6.216564e-03 289.91 -2.00 20.00 -2.00 320.20 0.00e+00 4.506 0.001 302.00 328.00 3 2.7041e+00 6.8995e-03 5.5613e-02 -6.0000e+00 3.4424e-01 4.1458e-03 9.2225e-03 3.2662e-02 -6.0000e+00 3.7193e-01 -1.6582e-02 8.7613e-03 1.6312e-02 -6.0000e+00 2.2099e-01 -3.1019e-03 4.2577e-03 4.6629e-03 -6.0000e+00 9.4152e-02 2.0231e-04 -1.0023e-04 1.0965e-04 5.2310e-05 -6.0000e+00 6.4006e-03 1.4452e-02 11 1 0 11 8 0 79.66 23.72 0.34 0.01445 0.01370 45 45 1 5 0 664.310 26.32 20.00 23.72 32.69 4.9 1011.69 900000 -98895 33448 -39208 -97640 900000 -88794 1381 -150920 -44162 -81954 55640 -48280 32997 -38888 -23914 -12228 -27943 -12782 -19665 -16458 -10083 18755 -6644 4188 -19344 -6609 -1720 -2103 -14648 -6441 6721 -10098 -6155 -16458 -2743 -6146 -4044 -1004 -409 3142 -3454 5731 -7257 1301 -2063 -1649 -3359 3347 -2036 2535 1060 2148 5383 -385 3356 -398 3 -1732 1981 -1401 1630 1192 1486 1893 1416 2101 992 1571 1295 1180 817 1420 -115 169 -343 -1323 -1181 -587 -570 -1335 -343 -2075 -654 -1588 675 -334 465 630 923 1097 90 766 -220 820 -417 914 262 169 -523 -3 -1276 -642 -372 -975 -763 -955 -643 -415 2 130 345 -113 215 261 351 -78 174 243 -500 263 -23 -416 109 509 73 899 908 417 453 -77 32 -179 168 -449 -7 35 45 -158 36 -46 -62 -202 900000 -705 125 -160 -663 900000 -633 5 -2716 -300 -863 208 -525 222 -607 -382 -195 -579 -247 -434 -363 -212 318 -162 101 -630 -193 -46 -56 -477 -230 249 -511 -318 -905 -133 -348 -249 -75 -36 304 -384 610 -899 150 -251 -204 -436 425 -293 391 186 409 1084 -87 771 -98 1 -421 459 -348 433 361 463 611 446 703 321 561 536 539 391 670 -52 70 -128 -505 -456 -232 -266 -732 -212 -1429 -471 -1240 551 -269 382 517 782 864 67 542 -162 662 -364 907 298 210 -651 -3 -1359 -625 -364 -1036 -856 -1131 -812 -569 3 204 568 -186 340 390 501 -112 261 387 -836 436 -37 -648 164 727 108 1272 1325 636 774 -145 59 -353 349 -1005 -16 80 104 -366 87 -103 -132 -416 SS 20240627T111350.6Z 8944.467946 234 1 29.94 2 75.79 71.35 48.19 204.98 0.00 1 0.00 1 0 17 1.491e-01 4.344e-03 4.012e-02 1.395e-03 5.507143e-01 7.378169e-04 6.169448e-03 -6.000000e+00 8.686001e-02 232.73 -2.00 3.44 -2.00 320.37 0.00e+00 1.224256e-03 2.770348e-04 6.179976e-04 -6.000000e+00 3.876766e-03 289.91 -2.00 20.00 -2.00 319.62 0.00e+00 3.985 0.001 302.00 328.00 3 1.5229e+00 2.2866e-03 4.9293e-02 -6.0000e+00 2.1792e-01 -2.7232e-03 2.8795e-03 2.8915e-02 -6.0000e+00 2.3531e-01 -1.8119e-02 2.5446e-03 1.4433e-02 -6.0000e+00 1.4021e-01 -3.0450e-03 1.2819e-03 4.3066e-03 -6.0000e+00 5.9524e-02 1.1639e-03 -1.1012e-04 3.9804e-05 4.8037e-05 -6.0000e+00 4.0424e-03 1.4096e-02 10 0 0 10 0 0 78.83 23.73 0.23 0.01410 0.01327 174 174 1 5 0 172.020 26.32 20.00 23.73 32.76 5.0 1013.20 -64979 -49633 -37295 -44916 -69766 -49908 -37336 -54797 -38166 -39341 -30526 -40933 -30262 -26283 -18037 -12210 -6839 -11429 -691 -2907 -3536 -9625 -2876 -5553 -8012 -4822 -10796 -2053 -5559 -3381 -5244 1346 160 -1085 -1860 -5659 -2862 -1783 138 -1717 126 -475 513 -396 222 541 -590 -510 -1092 425 684 1911 709 1230 22 1451 272 1100 -239 863 659 1100 2220 1710 838 859 467 244 1068 855 1113 317 136 182 -417 -692 -1285 -925 -456 -465 -647 -1001 -1457 -1221 -634 -343 341 296 401 476 650 613 527 375 280 231 477 412 -45 -155 -510 -803 -620 -527 -896 -805 -829 -628 -197 122 277 113 99 161 189 285 387 236 134 -274 6 68 -72 215 345 131 497 556 241 407 -15 139 -114 -155 -250 -121 -3 66 -214 -11 -28 -116 20 -661 -501 -356 -446 -812 -485 -355 -705 -473 -534 -398 -659 -541 -559 -432 -322 -189 -361 -21 -96 -122 -353 -105 -227 -360 -223 -534 -91 -250 -159 -290 81 11 -80 -132 -420 -230 -169 16 -233 19 -75 84 -67 38 94 -105 -93 -206 84 148 452 184 342 6 440 86 344 -74 263 209 378 843 716 364 360 192 103 488 443 628 187 80 102 -219 -331 -580 -417 -223 -262 -415 -717 -1127 -988 -542 -310 319 283 385 443 570 506 418 302 245 225 518 494 -57 -198 -623 -912 -662 -569 -1028 -967 -1036 -825 -273 182 441 187 163 256 288 419 567 358 214 -453 10 111 -114 333 515 190 701 799 374 682 -27 258 -219 -309 -521 -261 -7 148 -480 -23 -59 -236 41 SS 20240627T112408.9Z 8944.475103 237 1 31.73 2 73.85 72.74 49.04 208.11 0.00 1 0.00 1 0 25 1.810e-01 7.852e-03 1.600e-01 6.339e-03 4.860919e-01 3.323248e-03 5.509974e-03 -6.000000e+00 1.053954e-01 232.73 -2.00 3.44 -2.00 320.01 0.00e+00 9.095130e-04 1.088215e-03 3.989653e-04 -6.000000e+00 4.704126e-03 289.91 -2.00 20.00 -2.00 319.22 0.00e+00 3.533 0.001 302.00 328.00 3 4.7566e+00 9.9144e-03 4.3632e-02 -6.0000e+00 2.6442e-01 6.4266e-02 1.2062e-02 2.5430e-02 -6.0000e+00 2.8552e-01 -2.7721e-02 9.9208e-03 1.2488e-02 -6.0000e+00 1.7013e-01 4.7830e-03 5.1011e-03 3.5980e-03 -6.0000e+00 7.2225e-02 7.2592e-05 -1.5326e-04 1.8435e-04 4.0185e-05 -6.0000e+00 4.9052e-03 1.4318e-02 11 8 0 10 0 0 98.34 23.75 0.17 0.01432 0.01317 9 9 1 5 0 3524.810 26.41 20.00 23.75 33.74 5.0 1015.11 -55531 -38410 20889 -61683 -73528 119223 -50470 77275 -5909 14638 1593 -6163 -22659 -11063 1146 17563 -7826 64396 25248 -7534 713 -7765 -3525 3992 9806 -897 -16224 420 2688 17124 -9048 -12769 -2139 4133 2744 -1261 8463 4770 -7388 8021 -4168 799 28 -3699 898 -1455 4525 -4623 -2373 -4061 2544 875 2124 191 -1410 1752 -900 2185 -2102 1380 1971 2476 4210 1542 1725 -298 1157 -2504 2689 910 531 -351 370 -177 808 -1565 1020 -755 -2872 1319 -2454 -1099 -1052 -122 -1595 1003 -553 928 1253 -255 630 -822 -46 -706 -15 -569 1009 190 295 86 -372 -1297 -625 -586 -1673 -251 -655 -76 254 1104 404 342 378 219 56 490 209 -1033 -224 -440 -283 -557 449 243 -221 1276 167 255 -199 309 390 445 -343 -233 -75 -87 366 62 -111 145 1 -154 -531 -1040 -693 229 -1382 -1687 737 -1020 552 -101 221 28 -127 -652 -346 38 573 -352 1600 960 -408 37 -434 -199 227 567 -60 -1268 27 164 957 -732 -1222 -207 395 253 -121 823 567 -1194 1316 -849 164 6 -842 197 -331 979 -1102 -565 -1031 662 253 654 64 -504 629 -339 799 -781 493 726 985 1828 748 852 -144 532 -1205 1341 522 333 -230 240 -110 464 -831 493 -367 -1539 781 -1700 -837 -859 -104 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